Spin-lattice relaxation in gadolinium-doped calcium tungstate

The spin-lattice relaxation of the S-state ion Gd³⁺ in a calcium tungstate host lattice has been examined at 37.5 GHz over the temperature range 1.5 to 30 K. The gadolinium concentrations in the doped single crystals used were about 50 ppm. Single exponential recovery was observed and the spin-lattice relaxation time (T ₁) varied from about 14 msec at 1.5 K to 0.03 msec at 30 K, measured with =90° and =8°. It was found that T ₁ varied with temperature (T) as T ₁ T ^–1 below 8 K and as T ₁ T ^–3 between 8 and 30 K. The experimental data was fitted by the expressions T ₁ ^–1 =35 T+0.5 T ³ and T ₁ ^–1 =35T+0.1 T ^3.6 for crystals of nominal gadolinium concentrations 0.005 wt % and 0.05 wt % respectively. The difference between the observed dependence and the T ^–5 variation predicted in the Raman region for an S-state ion in a perfect lattice is attributed to defects. Measurements in the -plane at 4.2 K showed that T ₁ was anisotropic with a maximum value at =25° about three times greater than the minimum value obtained at =55°. The angular positions at which these features occur show a remarkable coincidence with the acoustic axes of symmetry of the crystal, which have recently been determined by ultrasonic methods.     

Two-dimensional pressure-temperature phase diagram and latent heats of neon adsorbed on exfoliated graphite

A two-dimensional pressure-temperature phase diagram was constructed for neon adsorbed on exfoliated graphite using the heat capacity data obtained in our laboratory for this system. The two-dimensional pressures at the triple and critical points were found to be _t=64×10^–6 N/m and _c=128×10^–6 N/m, respectively. From Clapeyron's equation and assuming an ideal behavior for the two-dimensional gas phase, the latent heat of sublimation was calculated as a function of temperature. The latent heat of vaporization was also calculated at the triple point and consequently the latent heat of fusion was found. The following values were obtained at the triple point:l _s/k=86 K,l _v/k=24 K, andl _f/k=62 K.     

Schottky barrier height enhancement on n-In0.53Ga0.47As by (NH4)2S x surface treatment

(NH₄)₂S _x Surface treatment was found to increase the barrier height (_Bn) for Au/In_0.53Ga_0.47As Schottky junctions from 0.26 eV to 0.58 eV at 300 K as determined from Richardson plots. The ideality factorn thus decreased from 2.7 to 1.6 and the reverse saturation current densityJ ₀ from 9.4 Acm^–2 to 3.4×10^–5A cm^–2. The values of the effective Richardson constant were also evaluated. The chemical state of In_0.53Ga_0.47As surfaces before and after (NH₄)₂S _x modification, examined by X-ray photoelectron spectroscopy (XPS), indicated bond formation of S with In, Ga and As.     

Influence of Y2O3 distribution on the rate of tetragonal to monoclinic phase transformation of yttria-stabilized zirconia during hydrothermal aging

Tetragonal to monoclinic phase transformation of yttria-stabilized zirconia, namely plasma-sprayed coatings and sintered bodies containing 4–8 mass % Y₂O₃ during hydrothermal aging was investigated with respect to Y₂O₃ distribution using 1 m area from electron probe microanalysis (EPMA) and 20 nm area from transmission electron microscopy (TEM) analysis. Phase transformation at 473 K was prevented only in plasma-sprayed coatings having more than 6.7 mass % Y₂O₃ in 20 nm microscopic area. Furthermore, it was confirmed influence of Y₂O₃ distribution on the rate constants of this phase transformation was observed at 368 K.     

Kinetics and thermodynamics of intracrystalline Fe-Ga distribution in Y3(Fe,Ga)5O12

Garnets of composition Y₃Fe_5–x Ga _x O₁₂, withx=0–5, were synthesized from oxides. Samples with various Ga content were annealed at temperatures between 700–1290° C; the heating duration varied between 90 s and 1350 h. Cation distribution was measured by Mössbauer spectroscopy at room temperature. The standard free energy change for the exchange reaction Fe³⁺ (tet)+ Ga³⁺ (oct)Fe³⁺ (oct)+Ga³⁺ (tet) is about 20 kJ mol^–1, and decreases slightly with increasing Fe content. The specific rate constants for the ordering process were determined according to the Mueller model for order-disorder kinetics. The activation energies for the ordering process between 200–250 kJ mol^–1 were calculated from the temperature dependence of the specific rate constants.     

The effects of pressurization on the microstructure and mechanical properties of magnesium oxide

Changes in microstructure in single crystals of MgO, containing elastic discontinuities, which result from pressurization treatments in the range 0.2 to 2 GN m^–2 have been studied using an etch-pitting technique. Complex dislocation arrays have been observed around cubical and spherical cavities and precipitates. The observations are discussed in terms of stress and strain criteria. Production of {100} and {110} cracks at high pressure is also described. Following a 1 GN m^–2 pressurization the flow stress was observed to decrease by < 10% and this has been related to the induced dislocation density. In polycrystalline MgO the fracture strength was unaltered by pressurization but the critical temperature difference of thermal shock,T _C, was increased by 55K. This has similarly been attributed to the movement of pressurization-induced dislocations.     

Universality and the scaling laws in the superfluid phase transition of3He-4He mixtures

From the second-sound velocityU ₂ near the superfluid transition point, the superfluid densities in³He-⁴He mixtures, _s (X) and _s (), were deduced along the paths of constant³He concentrationX and of constant chemical potential difference of³He and⁴He. The following critical exponents of _s are determined: (a) =XX for _s (X) in the(X, T) plane,(b) X for _s (X) in the(, T) plane, and(c) for _s () in the(, T) plane. It is found that and _X change by about 4–6% relative to with increasing³He concentration up toX=0.4 and by 8–10% up toX=0.53. It seems that, belowX=0.53, universality hold for . Values of have been found to be in good agreement with the critical exponent of _s in pure⁴He under constant pressure. The values of and _X forX0.53 are also found to be consistent with the scaling relations in the (,T) plane of³He-⁴He mixture.Work performed in part while at the Electrotechnical Laboratory.     

Mechanical relaxation of 4 wt% Y2O3-ZrO2 tetragonal single crystals

The mechanical relaxation was examined by a resonance piezoelectric method for a 3.5 wt % Y₂O₃-ZrO₂ polycrystal and 4 wt% Y₂O₃-ZrO₂ tetragonal single crystals with orientations in the 100 and 111 directions. The relaxation was observed for the 111-oriented crystal, but not for the 100-crystal. The results indicated that the relaxation was active only for the elastic compliance, S₄₄, and inactive for (s ₁₁–s ₁₂). The amplitude of the anelastic relaxation measured for the polycrystalline and the 111-crystal body was 4.2 × 10^–12 m²N^–1 and 6.7×10^–12 m² N^–1, respectively. An observed broad relaxation peak suggested that complex processes exist even in single crystals.     

The tensile properties of pultruded GRP tested under superposed hydrostatic pressure

The failure mechanisms in waisted tensile specimens of pultruded 60% volume fraction glass fibre-epoxide were investigated at atmospheric and superposed hydrostatic pressures extending to 350 MN m^–2. The maximum principal stress at fracture decreased from 1.7 GN m^–2 at atmospheric pressure to 1.3 GN m^–2 at 250 MN m^–2 superposed pressure and remained approximately constant at higher pressures, as had been observed with carbon fibre reinforced plastic (CFRP) and a nickel-matrix carbon fibre composite. In the high-pressure region the failure surfaces were fairly flat, consistent with the fracture process being solely controlled by fibre strength. Pre-failure damage, in particular debonding, was initiated at 0.95 GN m^–2 at atmospheric pressure and this stress rose to 1.2 GN m^–2 at 300 MN m^–2 superposed pressure, i.e. by about 9% per 100 MN m^–2. Unlike the pressure dependence in CFRP, this contrasts with the pressure dependence of the resin tensile strength, about 25% per 100 MN m^–2, but can be associated with that of the fibre bundle/resin debonding stress, about 12% per 100 MN m^–2 superposed pressure. Consistent with this interpretation, glass fibres of the failure surfaces were resin-free, again in contrast to CFRP.     

Magnetic properties of (Dy1−xGdx)3Ga5O12 garnet single crystals

Magnetic properties of Dy_1–x Gd _x )₃Ga₅O₁₂ (DGGG) garnet single crystals were calculated using the Weiss molecular field theory and also measured using the vibrating sample magnetometer in the temperature range 4.2–40 K in the effective magnetic field from 0–7 T. The magnetic properties of DGGG single crystals are distributed between those of Dy₃Ga₅O₁₂ (DGG) and Gd₃Ga₅O₁₂ (GGG) single crystals, but are considerably closer to those of DGG. Based on the magnetic properties, the magnetic entropy change, S_M, was evaluated in the temperature range below 15 K. DGGG single crystals are a prospective material for magnetic refrigeration below 15 K.     

Prediction of thermal diffusion in binary mixtures of nonelectrolyte liquids by the use of nonequilibrium thermodynamics

A derivation based on nonequilibrium thermodynamic leads to this expression for the thermal diffusion factor, _T=M ₂(h ₂ ^xs -h ₁ ^xs )/RT ₂, where M ₂ is the molecular weight of the lighter of the two components, h ₁ ^xs is the partial excess enthalpy of component i, J/g, R is 8.314 J · K ^–1 · mol ^–1, T is temperature in K, and ₂ is the thermodynamic correction factor (1 + d ln ₂/d ln X ₂), where ₂ is an activity coefficient and X ₂ is the mole fraction. The correctness of this theoretical prediction is verified for the liquid system ethanol-water at 298 K.Paper submitted to the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A.     

Nonlinear electrical properties of ZnO varistors fast-fired by using millimeter-wave sintering process

Fast firing of Bi₂O₃-based ZnO varistor materials, which includes zero minutes soaking at 1100°C with 120°C/min heating and 145°C/min cooling rate, was made possible using millimeter-wave sintering (mS) technique. The overall sintering time of the process is less than 18 minutes, and the varistor characteristics obtained are = 38, J _L = 5.55 × 10^–6 A/cm² and V _bk = 600 V/mm, whereas the intrinsic parameters of the materials are _b = 2.84 eV, N _d = 1.85 × 10²⁴ m^–3 and N _s = 7.02 × 10¹¹ cm^–2. By contrast, conventional sintering (cS) process needs higher sintering temperature (1200°C), longer soaking time (60 min) and slower ramping rate (30°C/min) to obtain ZnO materials with the same marvelous nonlinear properties as those prepared by mS-process. Moreover, millimeter-wave sintering (24 GHz, mS) process enhances the densification kinetics and grain growth behavior more efficiently than the microwave sintering (2.45 GHz, S) process, resulting in better varistor characteristics for ZnO materials. However, sintering by millimeter-wave for too long period induces overfiring of the samples, which results in a density reversion phenomenon. Such a phenomenon leads to the decrease in surface state (N _s) and the potential barrier height (_b), which are presumed to be the mechanism leading to the degradation of ZnO materials' nonlinear properties.     

Transverse (interlaminar) cracking under tensile loading in pultruded CFRP

The examination of microstructure of tensile specimens of pultruded 60% V _f carbon fibre-reinforced epoxide of up to 6 mm unreduced diameter shows that transverse cracking precedes the tensile failure of groups of fibres. In material whose strength is 2 GN m^–2, the process can commence in waisted specimens at stresses as low as 1 GN m^–2; in those of unreduced section it was not detected below 1.5 GN m^–2. This failure initiation stage can be associated with the decrease in the slope of the load-extension curve. With increasing load the inter-tow cracks were observed to grow and some surface fibre bundles detached. It is suggested that misaligned fibres in these surface bundles were straightened out and contributed to the load-carrying capacity of the rod. Only following detachment of numerous bundles (for the specimens with unreduced section) or growth of interlaminar cracks into the specimen shoulders (for those with a reduced gauge diameter) did tensile failure of fibre bundles lead to catastrophic fracture. It is to this last propagation stage that statistical models of failure of bundles at different cross-sections should refer.     

Computation of particle settling speed and orientation distribution in suspensions of prolate spheroids

A numerical technique for the dynamical simulation of three-dimensional rigid particles in a Newtonian fluid is presented. The key idea is to satisfy the no-slip boundary condition on the particle surface by a localized force-density distribution in an otherwise force-free suspending fluid. The technique is used to model the sedimentation of prolate spheroids of aspect ratio b/a=5 at Reynolds number 03. For a periodic lattice of single spheroids, the ideas of Hasimoto are extended to obtain an estimate for the finite-size correction to the sedimentation velocity. For a system of several spheroids in periodic arrangement, a maximum of the settling speed is found at the effective volume fraction (b/a)²04, where is the solid-volume fraction. The occurence of a maximum of the settling speed is partially explained by the competition of two effects: (i) a change in the orientation distribution of the prolate spheroids whose major axes shift from a mostly horizontal orientation (corresponding to small sedimentation speeds) at small to a more uniform orientation at larger , and (ii) a monotonic decrease of the the settling speed with increasing solid-volume fraction similar to that predicted by the Richardson–Zaki law (1–)⁵⁵ for suspensions of spheres.     

Effect of Normal-State Pseudogap on Physical Quantities in Hubbard Model for Underdoped High-T c Cuprates

We develop the strong-coupling theory of coexisting charge-density-wave (CDW) and superconductivityd-wave gaps within the framework of the FLEX (fluctuation exchange) approximation for the two-dimensional Hubbard model. For nested sections of the Fermi surface these equations reduce to the previous FLEX equations for superconductivity where the squared energy gap _s ² in the denominator of the Green's function is replaced by ( _s ² + _c ² ) (here _s is the superconductivity and _c the CDW gap). We solve these equations by taking for _c a phenomenologicald-wave gap. The resulting neutron scattering intensity, spin-lattice relaxation rate 1/T₁ , Knight shift, resistivity, and photoemission intensity are in qualitative agreement with the data on underdoped high-T_c cuprates. TheT_c for superconductivity decreases and the crossover temperature T_* for 1/T₁Tincreases with increasing gap amplitude of _c which is in qualitative agreement with the phase diagram for underdoped cuprates.     

Physical properties of pulsed current copper electrodeposits

Square-wave unipolar pulse electroplating and bipolar pulse reverse electroplating of copper using an acid copper electrolyte of the type used for printed circuit board production has been studied. The effects of pulse-plated coatings on cathode efficiency and on the coatings properties, such as surface roughness, microhardness, stress-strain characteristics and elongation, are reported. The results show that microhardness, tensile strength and elongation are directly affected by the pulse technique used.Nomenclature A Cross-sectional area (m²) - CE Relative cathode efficiency - i Current density (A dm^–2) - i _m,i _p Mean, peak current density (A dm^–2) - M _a Actual deposit mass (g) - M _t Theoretical mass (g) - R _a Average roughness - R _tm Mean roughness - t Coating thickness (m) - t _off Off-time (ms) - t _on On-time (ms) - duty cycle (%) - density (g m^–3)     

Site occupation in gadolinium-doped calcium tungstate

The electron spin resonance spectrum of the S-state ion Gd³⁺ in a calcium tungstate host lattice has been examined at 37.5 GHz over the temperature range 290 K to 4.2 K. Low concentration Czochralski-grown single crystals having gadolinium concentrations of about 100 ppm were used to ensure substitution by Gd³⁺ in calcium sites; the crystals were vacancy compensated. Although the general features of the 290 K spectrum agreed well with that reported previously by Hempstead and Bowers, extra lines were observed very close to the main M=1 transitions. Examination in the-plane showed that the extra lines were most pronounced near=55° and that their intensites relative to those of the main transitions increased as the temperature was reduced. The extra lines are explained in terms of the ordering of oxygen vacancies.     

Heat capacity and thermodynamic functions of zinc metaarsenate in the range 298.15–673 K

The isobaric heat capacity of Zn(AsO₃)₂ is measured by a calorimetric method in the range 298.15–673 K. From the data obtained the temperature dependences of the functions C_kp/0(T), S⁰(T), H⁰(T)–H⁰(298.15), and ^** are calculated.Chemical Metallurgy Institute, Academy of Sciences of Kazakhstan, Karaganda. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 68, No. 4, pp. 647–650, July–August, 1995.     

Effects of mode mix upon fracture behavior of a solder joint

Results of fracture experiments of brass/solder/brass sandwich CTS (Compact Tension-Shear) specimens are presented together with observations of the crack propagation behavior and the fractographs. The fracture behaviors of the interface crack are analyzed by the finite element method with a modified boundary layer formulation. Several fracture mechanisms and the corresponding criteria are examined. And the crack growth behavior and fracture toughness are predicted. As the results various crack growth procedures such as the crack jump to another interface on the opposite side, the nucleation of a new crack far from the initial crack front, and the asymmetric relation of fracture toughness versus mode mix J _c– can be successfully explained. The fractographs, the crack growth behaviors, and stress-strain distribution along the interface are inter-related.     

Sinterability of magnesium silicon nitride powder with yttrium oxide addition coated using the homogeneous precipitation method

The sinterability of magnesium silicon nitride (MgSiN₂) powder with yttrium oxide (Y₂O₃) addition was examined using the hot-pressing technique (31 MPa and N₂ atmosphere) at 1550°C for 90 min; the MgSiN₂ powder had been coated with 0–4 mass% of Y₂O₃ addition by a (urea-based) homogeneous precipitation method. Relative densities of the hot-pressed MgSiN₂ compacts (ceramics) with and without Y₂O₃ addition were 99.6% apart for the MgSiN₂ceramic with 4 mass% Y₂O₃ addition (98.4%). The thermal conductivities of the MgSiN₂ ceramics with 0–1 mass% Y₂O₃ addition were in the range of 20–21 W · m^–1 · K^–1 whilst the Vickers hardness was 19.7 GPa for the pure MgSiN₂ ceramic and decreased slightly with Y₂O₃ addition. Average fracture toughness values were in the range of 1.2–1.6 MPa · m^1/2 with significant trend being noted with regards to the ceramic containing 0.5 mass% of Y₂O₃. It was concluded that the use of homogeneous precipitation processing resulted in significant advantages regarding the densification, homogeneous microstructure, and fracture toughness despite the amount of Y₂O₃ addition being as low as 0.5 mass%.