IN-713C characteristic properties optimized through different heat treatments

The strength of a nickel-based superalloy hardened through precipitation is related to the volume fraction, particle size and distribution of the precipitated phase, . These parameters may vary as a result of heat treatment, or high-temperatures service. The information obtained, describing the influence of time and temperature on the precipitated phase, , is of special importance owing to its technological application at high temperatures. Dissolution or precipitation kinetics are such that the volume-fraction balance of the phase is quickly established at an ageing temperature given by successive changes due only to the particle growth. The results of the present study describe heat-treatment effects on size and distribution of the phase, and precipitated carbides ageing of a nickel-based superalloy (IN-713C). These on ageing studies at a certain temperature show that the kinetic growth of particles by controlled diffusion follows that r t ^1/3 law.     

Oxidation of an Al2O3-γAlON ceramic composite

The oxidation of dispersed aluminium oxynitride particles in an alumina matrix has been studied. The kinetics law of this reaction is linear and the activation energy is 420±40 kJ mol^–1 (100±10 kcal mo^–1). A-alumina layer is formed and leads to-alumina above 1200° C. The-alumina formation produces surface compressive stresses, and thus the mechanical properties ( _f, HV) are improved. We have proved that the formation of-alumina in the Al₂O₃-AION composite can lead to the best properties for this ceramic. A-alumina layer has a very interesting effect on the wear resistance of this material.     

Microstructure and mechanical properties of rapidly quenched L20 and L20+L12 alloys in Ni-Al-Fe and Ni-Al-Co systems

Ductile L2₀-type wires and+L1₂-type duplex wires with high strengths and large elongation in the Ni-Al-Fe and Ni-Al-Co ternary systems have been manufactured directly from the liquid state by an in-rotating-water spinning method. The wire diameter was in the range 80 to 180m and the average grain size was 2 to 4m for the wires and 0.2 to 1.0m for the+ wires. _y, _f and _p of the wires were found to be about 360 to 760 MPa, 560 to 960 MPa, and 0.2 to 5.5%, respectively, for the Ni-Al-Fe system, those of the+ wires were about 395 to 660 MPa, 670 to 1285 MPa, and 3.5 to 17%, respectively, for the Ni-Al-Fe system, and about 260 to 365 MPa, 600 to 870 MPa, and 4.0 to 7.0%, respectively, for the Ni-Al-Co system. Cold-drawing caused a significant increase in _y and _f and the values attained were about 1850 and 2500 MPa, respectively, for Ni-20Al-30Fe and Ni-25Al-30Co wires drawn to about 90% reduction in area. The high strengths, large elongation and good cold-workability of the melt-quenched and+ compound wires have been inferred to be due to the structural change into a low-degree ordered state containing a high density of phase boundaries, suppression of grain-boundary segregation and refinement of grain size.     

EXAFS study of a hot-pressed α′-sialon ceramic containing erbium as the modifying cation

The general composition for an-sialon isM _x(Si, Al)₁₂(O, N)₁₆, (the value ofx lies between 0 and 2), where M is a modifying cation such as Li⁺, Ca²⁺, Y³⁺ or a number of the lanthanide cations (Ln³⁺). This paper reports extended X-ray absorption fine structure (EXAFS) spectroscopy measurements of a hot-pressed erbium containing-sialon, using the synchrotron radiation source at Daresbury, UK. This technique provides short-range structural information within this engineering ceramic. The results suggest that the erbium modifying cation shows a preference for being located in one particular site within the ceramic network.     

The dielectric behaviour of single-crystal MgO,Fe/MgO and Cr/MgO

The dielectric constants and loss factors,, for pure single-crystal MgO and for Fe-and Cr-doped crystals have been measured at frequencies, , from 500 Hz to 500 kHz at room temperature. For pure MgO at 1 kHz the values of and the loss tangent, tan , (9.62 and 2.16×10^–3, respectively) agree well with the data of Von Hippel; the conductivity, , varies as ⁿ withn=0.98±0.02. In Fe-doped crystals increases with Fe-concentration (at any given frequency); for a crystal doped with 12800 ppm Fe, was about four times the value for pure MgO. At all concentrations the variation of log with log was linear andn=0.98±0.02. A decrease in with increasing Fe-concentration was also observed. A similar, although less pronounced, behaviour was found in Cr-doped crystals. The effects are discussed in terms of hopping mechanisms.     

BCS temperature-dependent superconducting energy gap in domain boundaries of melt-textured YBa2Cu3O7

Attenuation and velocity measurements in low magnetic fields in the superconducting state of a melt-textured sample of YBa₂Cu₃O₇ are reported. Changes in both attenuation and relative velocitydv/v are observed at the penetration fieldH _c1 of its domain boundaries. The change indv/v atH _c1 appears to be proportional to the repulsive force between vortices. The change in atH _c1 may be produced by a relaxation process involving superconducting quasiparticles in the vicinity of the normal core of the vortices. Analysis of the relaxation time associated with this process yields a temperature-dependent energy gap which follows the BCS dependence. The relaxation time associated with the process is about 10^–11 sec.     

Some expectation on the mechanism of cross-flow instability in a swept wing flow

Summary Three-dimensional boundary layer transition on axisymmetric rotating bodies is the subject of a comprehensive experimental study. Based on this study, hypotheses are made on the mechanism of cross-flow instability for swept wing flow. These new results are combined with past explanations to provide a rough sketch for the entire flow field over the swept wing. From this new viewpoint there appears the mechanism of traveling waves, being induced by a stationary disturbance. Some uncertainties appearing in recent papers concerning this flow field are discussed. Among these uncertainties for which an explanation is provided, is the discrepancy of frequencies between the hot wire signal and the visualized flow pattern.Nomenclature x direction along a potential flow stream line - y direction normal to a potential flow stream line - z direction normal to bothx andy directions - U mean velocity inx-direction - V mean velocity iny-direction - x direction along a disturbance - y direction normal tox direction - u, v, w fluctuating velocity components inx, y, z directions - U velocity inx-direction with wall fixed coordinate - U _e velocity of outer edge of boundary-layer - U uniform flow velocity normal to leading edge - V uniform flow velocity parallel to leading edge - Q upstream velocity - N rotation speed of an axisymmetric body - P arbitrary point on a disk surface - r radius to a pointP - R ₀ radius of a disk or a cylinder - U _p phase velocity of ring like vortices - T position where wall streaks appear in the case of oil flow visualization - Re _c,t critical and transitional Reynolds numbers - angle of the spiral disturbance - boundary-layer thickness - angular velocity - sweep angle of a body - wave length of disturbance - kinematic viscosity of a fluid With 11 Figures     

Singular Band Behavior of the Extended Emery Model for the Superconducting Cuprates

Mean field slave-boson approximation is performed on the extended Emery model for the CuO₂ conducting plane. The model is parameterized by Cu–O charge transfer energy _pd , copper–oxygen overlap t ₀, oxygen–oxygen overlap t', and Coulomb interaction U on the copper site taken as infinite. Special emphasis is placed on the role of t in the renormalization trends of the effective band parameters _pf and t, replacing _pd and t ₀, at small doping . It is shown that small, negative t expands the range of stability of the metallic phase, changing, in the second order of the perturbation theory, the nature of the metal–insulator transition point. In the nonperturbative limit, t modifies strongly the renormalization of _pf , making it saturate at the value of 4t. Finite doping suppresses the insulating state approximately symmetrically with respect to its sign. The regime _pf 4t fits very well the ARPES spectra of Y123, Bi2212, and LSCO and also explans, in the latter case, the evolution of the FS with doping accompanied by the spectral weight-transfer from the oxygen to the resonant band.     

Band-theoretical calculation for the anomalous resistivity of Ni near the Curie temperature

The anomalous resistivity of nickel near the Curie temperature T _c is investigated using the itinerant model of the magnetic electron. The 3d-band wave functions are used to calculate the form factor. The temperature derivative of resistivity diverges positively when T approaches T _c from below and negatively when it approaches from above. The calculation of the correlation function shows that both short-range and long-range orders exist. The critical exponents = 1/2 and = 0 are equal to the Ornstein—Zernike values in the paramagnetic region, but in the ferromagnetic region in addition to these values ₁ = 1/2 and ₁ = 0 there is simultaneously a second set of values ₂ = and ₂ = –1.     

Thermal transport properties of helium near the superfluid transition. II. Dilute3He-4He mixtures in the superfluid phase

Measurements of the average thermal conductivity _exp hQ/T and of the thermal relaxation time to reach steady-state equilibrium conditions are reported in the superfluid phase for dilute mixtures of³He in⁴He. Hereh is the cell height,Q is the heat flux, andT is the temperature difference across the fluid layer. The measurements were made over the impurity range 2×10^–9<X(³He)<3×10^–2 and with heat fluxes 0.3<Q<160 µW/cm². Assuming the boundary resistanceR _b , measured forX<10^–5, to be independent ofX over the whole range ofX, a calculation is given for _exp. ForQ smaller than a well-defined critical heat fluxQ _c (X) X ^0.9, _exp is independent of Q and can be identified with the local conductivity _eff, which is found to be independent of the reduced temperature = (T–T)/T for –10^–2. Its extrapolated value at T is found to depart forX10^–3 from the prediction X ^–1 , tending instead to a weaker divergence X ^–a witha0.08. A finite conductivity asX tends to zero is not excluded by the data, however. ForQ >Q _c (X), a nonlinear regime is entered. ForX10^–6, the measurements with the available temperature resolution are limited to the nonlinear conditions, but can be extrapolated into the linear regime forX2×10^–7. The results for _exp(Q),Q _c (X), and _eff(XX) are found to be internally consistent, as shown by comparison with a theory by Behringer based on Khalatnikov's transport equations. Furthermore, the observed relaxation times (X) in the linear regime are found to be consistent forX>10^–5 with the hydrodynamic calculations using the measured _eff(X). ForX<10^–5, a faster relaxation mechanism than predicted seems to dominate. The transport properties in the nonlinear regimes are presented and unexplained observations are discussed.     

The reversion of martensite to austenite in certain stainless steels

An investigation has been made of the reversion of martensite () to austenite () in two stainless steels (i) Fe-16 wt% Cr-12 wt% Ni (of low interstitial content) (ii) Fe-15 wt% Cr-8 1/2 wt% Ni-2 wt% Mo-0.09 wt% C. The alloys were refrigerated to produce 12 to 15% martensite () and then heated for short times at various temperatures ranging from below A _s to above A _f. With rapid heating the reversion of to occurs largely by a shear mechanism. In the Fe-16Cr-12Ni alloy individual grains of transform to grains of reversed of similar size and shape. In the carbon-containing alloy there is evidence of break-up of the grains on reversion. An increase in the strength results from reversion and this is attributable mainly to the high dislocation density of the reversed .     

Negatively isotone optimal policies for random walk type Markov decision processes

Summary This paper considers a random walk type Markov decision process in which the state spaceI is an integer subset of IR ^m , and the action spaceK is independent ofi I. The natural order, overI, and a quasi order,, overK, is assumed, together with aconditional convexity assumption on the returns {r _i ^k }, and certain other assumptions about these rewards and the transition probabilities in relationship to the orders and.A negatively isotone policy is one for whichi i(i))(i) (i.e.(i) (i) or(i) i)). It is shown that, under specified conditions, a negatively isotone optimal policy exists. Some consideration is given to computational implications in particular relationship to Howard's policy space method.

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Zusammenfassung Wir betrachten einen Markovschen Entscheidungsprozeß vom random walk Typ. Der ZustandsraumI sei eine Teilmenge des IR^m, wobeii I ganzzahlige Komponenten habe. Die MengeK der zulässigen Aktionen ini I sei unabhängig voni I. Sei die natürliche Ordnung aufI und sei eine Quasiordnung aufK. Die Erträge {r _i ^k }seienbedingt konvex, darüberhinaus seien weitere Voraussetzungen über diese Erträge und die Übergangswahrscheinlichkeiten in Bezug auf die Ordnungen und erfüllt. Eine Politik heißt negativ isoton, falls ausi i folgti(i) (d. h.(i) (i) oder(i)(i)). Wir zeigen, daß unter gewissen Voraussetzungen einenegativ isotone optimale Politik existiert: Auch diskutieren wir einige Folgerungen für die Numerik, insbesondere hinsichtlich Howards Politikiteration.

     

Precipitation in Ni-Co-Al alloys

Discontinuous precipitation of the phase in Ni-Co-Al alloys has been studied in the temperature range 673 to 973 K using optical microscopy and transmission electron microscopy. Discontinuous precipitation was observed to occur in all the alloys to some degree, the extent of the precipitation decreasing with decreasing cobalt content of the alloy. Only in high cobalt alloys (greater than 38 at%) did the discontinuous transformation go to completion. The discontinuous transformation product consisted of fine straight coherent lamellae with a specific cube-cube orientation relationship to the matrix at low ageing temperatures and short times. At higher temperatures and longer times, continuous and discontinuous coarsening processes produced a coarse, less regular structure with a plate spacing ten times that of the regular structure. The overall kinetics of the discontinuous transformation were affected by the prior continuous precipitation of particles ahead of the discontinuous reaction fronts. The coarsening of these continuous particles as a function of time stopped the transformation in low cobalt alloys and continuously slowed the rate of transformation in high cobalt alloys resulting in Avrami exponents,n, less than 1. Reversion experiments and experiments on prestrained specimens yielded Avrami exponents ofn=1 lending support to the above suggestion. The major effect of cobalt in these alloys was to increase their propensity to transform discontinuously. This effect was largely due to the decrease in the rate of continuous precipitation and coarsening as a result of the increased partitioning of cobalt between and in high cobalt alloys.     

Phase decomposition in extruded Zn-Al based alloy

Ageing characteristics of an extruded eutectoid Zn-Al based alloy were investigated using X-ray diffraction and scanning electron microscopy techniques. The extruded alloy consisted of Al rich phase and Zn rich _E and phases. The original cast eutectoid Zn-Al alloy was extruded at 250 °C. Both supersaturated _s and _s phase decomposed during extrusion and appeared as fine and coarse lamellar structures. The _E and phases particles formed in the original interdendritic region. It was found that two Zn rich phases _E and decomposed sequentially during ageing at 170, 140 °C. The decomposition of the _E phase occurred as a discontinuous precipitation in the early stage of ageing and the decomposition of the phase took place in a four phase transformation: + T + in the prolonged ageing. Two typical morphologies of the decomposition of the Zn rich phases _E and were distinctive in back-scattered scanning electron microscopy.     

Electronic and two-magnon light scattering in oxide superconducting crystals

From investigations of two-magnon Raman scattering (RS) under high pressures up to 430 kbar in Eu₂CuO₄ and YBa₂Cu₃O_6.2 crystals, it was shown that the dependence of the superexchange integralJ on the distance between Cu and O atoms in CuO₂ planesa is anomalously weak (Ja^–n, n=3±0.5). The large value ofJ indicates strong initial overlapping of Cu and O wave functions in high-T _c , materials. It was found that an increase in free carrier concentration results in a rapid increase of magnon damping and the disappearance of the two-magnon peak from RS spectra. A detailed study of electron Raman scattering has been carried out in superconducting and insulating YBa₂Cu₃O_6–x , single crystals. The spectral redistribution at frequencies<600 cm^–1 in different polarizations indicate that the superconducting gap is strongly anisotropic. In the normal (metallic) phase the behavior of the imaginary part of the response functionR() in the polarization (xx) corresponds to the model of a marginal Fermi liquid, and in the polarization (xx), this behavior is independent of the temperature. In insulating crystals,R() is independent of temperature toT200 K in both polarizations.     

High frequency dielectric properties of MgO,Fe/MgO and Cr/MgO

The study of the dielectric constant and loss in pure single-crystal MgO and in Fe- and Cr-doped crystals, the low frequency results of which have been reported [1], has now been extended to cover frequencies from 500 Hz to 9 GHz. Measurements were made on the same specimens, at room temperature, using bridge, cavity, slotted-line and cavity-resonator techniques. Over the whole frequency range, a good fit is obtained to the Universal Laws of dielectric response: _ac ⁿ and (–) ^n–1 with n=0.98±0.02 for both pure and doped MgO. At any point in this frequency range the addition of iron or chromium increases and decreases , the changes being more pronounced with iron. These effects are discussed in terms of hopping mechanisms.     

AC electrical conductivity of electron beam evaporated Cu-GeO2 thin cermet films

AC electrical properties of 410 nm think 30 at.wt% Cu-70 at.wt% GeO₂ thin films are reported for the frequency range 10⁴ to 10⁶ Hz and temperature range 150 to 425 K. The loss tangent (tan ) and the dielectric loss (/₀) are found to show striking minima around a cut-off frequency 10⁵ Hz. In the lower frequency range (10⁵ Hz), ₁() ^s T ⁿ is obeyed with s (0 to 0.51) increasing as a function of temperature and n (0.10 to 0.14) showing a very weak temperature dependence. In the higher frequency region (10⁵ Hz), ₁() and /₀ increase sharply leading to the quadratic behavior of ₁() with s equal to 2. These processes are discussed by analyzing an equivalent circuit which shows that at lower frequencies, the effects of series resistance in leads and contacts can be neglected, while at higher frequencies such effect give rise to spurious ² dependance for the conductance. A weakly activated AC conductivity and a frequency exponent s that increases with increasing temperature suggest that the low frequency behavior originates from carrier migration by tunneling process.     

1000 to 1300 K slow plastic compression properties of Al-deficient NiAl

Nickel aluminides containing 37, 38.5 and 40 at % Al have been fabricated by XD^tm synthesis and hot pressing. Such materials were compression tested in air under constant velocity conditions between 1000 and 1300 K. Examination of the microstructures of hot pressed and compression tested aluminides indicated that the structure consisted of two phases, and NiAl, for essentially all conditions, where was usually found on the NiAl grain boundaries. The stress-strain behaviour of all three intermetallics was similar where flow at a nominally constant stress occurred after about two plastic per cent deformation. Furthermore the 1000 to 1300 K flow stress-strain rate properties are nearly identical for these materials, and they are much lower than those for XD^tm processed Ni-50Al [1]. The overall deformation of the two phase nickel aluminides appears to be controlled by dislocation climb in NiAl rather than processes in .     

Complex microstructural changes in as-cast eutectoid Zn-Al alloy

Phase transformations and microstructural changes of an as-cast eutectoid Zn-Al alloy (ZnAl₂₂Cu₂) were investigated during isothermal holding. The typical dendritic structures consisted of _s phase as a core with the edge of decomposed _s phase and decomposed _s in the interdendritic regions. A series of complex phase transformations was observed. Both decompositions of _s and _s were determined at an early stage of ageing and a four-phase transformation, _f+T+, was observed at the boundaries of _f phase and the phase, instead of clearly observed at the boundaries of phase, in a solution-treated Zn-Al alloy during prolonged ageing.     

The Ni3Al-Ni3Cr-Ni3Mo section of the Ni-Cr-Al-Mo system

An investigation is reported of the constitution of the 75 at % nickel section of the Ni-Cr-Al-Mo system in the temperature range 1523 to 1073 K. Alloys in the region 10 to 20 at % Al were annealed at 1523, 1273, and 1073 K, respectively, and subjected to electron microprobe analysis, X-ray diffraction, and microscopical and hardness examination. Constitutional data are presented as partial isothermal sections and as vertical sections. At 1523 K the section consists only of fields containing ,+ and , the last mentioned phase being predominant. With decreasing temperature the and + fields increase in extent. Also, the NiMo and Ni₃Mo phases were encountered in the ternary Ni-Al-Mo alloy studied. The quaternary + alloys showed small lattice mismatch values, i.e. up to 0.25%. Raft like morphologies of were found in the quaternary alloys, resulting from directional coarsening. Observations of as-cast structures are also reported.