Al-Ti-C晶粒细化剂对工业纯铝的晶粒细化

采用自制的Al-Ti-C晶粒细化剂，检验了Al-Ti-C晶粒细化剂对工业纯铝的晶粒细化能力，研究了Al-Ti-C的含碳量、添加量、保温时间、浇注温度等对工业纯铝晶粒细化效果的影响。结果表明，对于工业纯铝添加质量分数为0.2％的Al-5.14Ti-0.3C晶粒细化剂，在725℃的铸造温度下保温2.5min，所得的铸锭晶粒细化效果最好。     

Al-Ti-B合金昌粒细化剂及细化机理的发展与现状

晶粒细化是提高材料强度和塑性,改善铸件质量的重要途径之一,其成功的关键在于形成高效、稳定、价廉的细化剂产品。在介绍Al-Ti-B合金晶粒细化剂的应用现状及生产方法的基础上,分析了晶粒细化剂的细化机理,明确了目前尚存在的问题,指出了今后的发展方向。     

铝-钛-硼晶粒细化剂的进展

介绍了铝 -钛 -硼晶粒细化剂的发展情况。     

Al-Ti-B合金晶粒细化剂及细化机理的发展与现状

晶粒细化是提高材料强度和塑性,改善铸件质量的重要途径之一,其成功的关键在于形成高效、稳定、价廉的细化剂产品.在介绍Al-Ti-B合金晶粒细化剂的应用现状及生产方法的基础上,分析了晶粒细化剂的细化机理,明确了目前尚存在的问题,指出了今后的发展方向.     

自蔓延高温合成Al-TiC晶粒细化剂及其晶粒细化效果

采用自蔓延高温合成 (SHS)技术直接合成了Al 80 %TiC和Al 5 0 %TiC晶粒细化剂。研究了这两种细化剂的相组成、结构及对工业纯铝的晶粒细化效果 ,并与商用Al 5Ti 1B细化剂进行了对比。结果表明 :合成的细化剂由TiC和α (Al)两相组成 ,TiC粒子的尺寸和分布对细化剂的晶粒细化效果有显著影响。Al 80 %TiC细化剂中TiC粒子尺寸较大 (2～ 5 μm)且呈聚集成团分布 ,其晶粒细化效果较差。合成的Al 5 0 %TiC细化剂的晶粒细化效果略优于Al 5Ti 1B细化剂。加入 0 .1%的该细化剂就能使凝固试样的结构由粗大的柱状晶转变成细小的等轴晶 (平均晶粒尺寸 12 0 μm) ,且这种晶粒细化效果可保持 90min。SEM和TEM分析显示 ,Al 5 0 %TiC细化剂中原位合成的TiC粒子具有亚微米尺寸 (0 .4～ 0 .9μm) ,且在高温铝液中具有较强的稳定性 ,从而赋予该细化剂良好的晶粒细化效果和强的抗晶粒细化衰退能力     

Al—Ti—C铝合金晶粒细化剂的研究进展

对新型铝合金晶粒细化剂Al-Ti-C的研究进展,制备方法,细化机理进行了述评。Al-Ti-C晶粒细化剂中的异持形核核心TiC有助于Al3Ti形核,而α－Al又包在Al3Ti外面,形核几率大相同添加量的Al-Ti-B,细化效果更好,异质形核核心TiC有助于Al3Ti形核,而α－Al3Ti外面,形核几率大于相同添加量的Al-Ti-B,细化效果更好。     

Al-Ti-B-RE细化剂对铝晶粒细化效果初探

对新型细化剂Al-Ti-B-RE的细化效果进行了探讨。结果表明:该中间合金是一种高效、长效的晶粒细化剂,当加入量为0.04%～0.10%,铝熔体在800℃静置30min的细化效果最显著,其效果优于进口Al-Ti-B细化剂。     

Al-Ti-B-RE细化剂对铝晶粒细化效果初探

对新型细化剂Al-Ti-B-RE的细化效果进行了探讨。结果表明：该中间合金是一种高效、长效的晶粒细化剂，当加入量为0．04％～0．10％，铝熔体在800℃静置30min的细化效果最显著，其效果优于进口Al-Ti-B细化剂。     

铝合金晶粒细化剂的研究进展

晶粒细化剂是铝合金生产中常用的添加剂之一,能显著提高铝合金的力学性能和机械加工性能,对铝合金的生产具有十分重要的意义。本文阐述了铝合金晶粒细化剂的发展历史和研究现状,并简单介绍了晶粒细化剂的细化机理和目前工业生产中常用的晶粒细化剂。     

铝—钛—硼高效晶粒细化剂

提高铝及铝合金强度的途径之一是细化晶粒.根据金属结晶学理论可知,要使铝及铝合金在铸造过程中形成细小的等轴晶,必须增加其由最初液态转入固态时的形核率.因此,除尽量创造自发形核的结晶动力学条件外,还需人为地加入大量外来晶核.铝一钦-硼中间合金就是人们为细化晶粒而在铸造过程中加入的一种变质剂.后经多年探索实践,发展成为当今的铝-钛-硼高效晶粒细化剂.生产实践表明,铝-钛-硼晶粒细化剂的细化效果十分显著,使用该产品后,可使铸锭的晶粒度由原来的4级提高到1级.     

化合物型铝钛硼细化剂成分分析的X射线衍射法

通过试验，提出了一套用Ｘ射线衍射法测定铝合金晶粒细化剂成分的分析方法，替代了原化学方法，避免了化学分析的缺点，直接对细化剂的各组成物相进行了定量分析，审其它试验方法无法达到的，该方法是一种较是粒细化剂分析方法。     

晶粒细化剂对Al-Mg-Si铝合金组织和性能的影响

研究了进口Al-Ti-B和自制Al-Ti-B-RE晶粒细化剂对Al-Mg-Si铝合金组织和综合力学性能的影响.结果表明,加入2种中间合金都能显著细化Al-Mg-Si铝合金的晶粒尺寸,对力学性能和布氏硬度也都有不同程度的提高.Al-Mg-Si铝合金的晶粒尺寸随着自制中间合金加入量的增加逐渐减小,当加入量为0.2％时,合金铸态组织性能和综合力学性能最好.     

The grain refinement of 6063 aluminum using Al-5Ti-1B and Al-3Ti-0.15C grain refiners

The Al-Ti-B grain refiners containing boride nucleant particles are used to promote a uniform microstructure throughout aluminum ingots and to suppress the growth of columnar grains. In addition, for the last eight years a new generation of Al-Ti-C grain refiners has been used commercially in a wide range of alloy systems. This paper will compare the potency of the commercially available Al-5Ti-1B grain refiner with that of the Al-3Ti-0.15C grain refiner for the 6063 cast alloy. For more information, contact Gabriela Popescu, University Politehnica of Bucharest, Material Science and Engineering Faculty, Splaiuil Independentei 313, Bucharest, 77206 Romania. gabriella81us@yahoo.com.     

A novel fading-resistant Al-3Ti-3B grain refiner for Al-Si alloys

Al-Ti-B refiners with excess-Ti perform adequately for wrought aluminum alloys but inefficiently in the case of foundry alloys. The high content of silicon in the latter, which forms silicides with Ti and severely impairs the refining potency of the nuclei, is known to be responsible for the poor performance. Hence, new grain refiners, such as Al-3B and Al-3Ti-3B master alloys with excess-B have been developed with well documented advantages for Al-Si alloys. It is very desirable to involve TiAl₃ particles in the Al-3Ti-3B master alloy to maximize its grain refining efficiency. However, fading phenomenon is a key drawback for application of the TiAl₃-containing refiners in aluminum foundry. In the present work, new Al-3Ti-3B grain refiners, containing TiB₂, AlB₁₂ and TiAl₃ particles were developed with an aim to prolong the acting time after inoculation. The results showed that inoculation of Al-7Si alloy with thus meliorated Al-3Ti-3B grain refiner has produced a fine grain structure which was approximately maintained up to 30 min.     

The performance of Al–Ti–C grain refiners in twin-roll casting of aluminium foilstock

The master alloys based on the Al–Ti–B system have been used extensively for refining the grain structure of aluminum alloys. The quality-related problems linked with the TiB₂ particles, however, have generated an interest in the Al–Ti–C grain refiners as an acceptable replacement for Al–Ti–B master alloys. TiC particles are smaller than the TiB₂ particles and are less prone to agglomeration. Al–3Ti–0.15C grain refiners have been in use for some time in several alloy systems. Much of the work reported on this alloy, however, has been from DC casting while performance data in strip casting is not available. In the present work, a commercial Al–3Ti–0.15C grain refiner was employed in the twin-roll casting of AA8111 foilstock. Its grain refining efficiency was compared with that of the Al–5Ti–0.2B master alloy, the standard grain refiner in aluminium industry for the manufacture of aluminium foil products.     

添加Al-TiB中间合金对铝合金组织、磨损和压缩变形行为的影响(英文)

在7178铝合金中添加不同比例的Al-10%TiB中间合金,考察TiB对铝合金的晶粒细化、磨损和压缩变形行为的影响。组织观察表明,TiB颗粒起着晶粒细化剂的作用,导致生成球状枝晶。当Al-TiB中间合金的添加量超过20%时,合金的耐磨性和强度随着中间合金添加量的增加而降低,即使其枝晶组织变得更细而接近于球状组织。     

中间合金对铝合金细化处理的现状分析与初探

分析讨论了中间合金对铝合金晶粒细化处理的研究与应用现状及其细化机理;并对新型细化剂AITiBRE中国合金的细化效果进行初探,结果表明该中间合金是一种高效、长效的晶粒细化剂,对压力罐用铝材具有显著的细化作用,其效果优于进口的A15TilB细化剂。     

细化变质处理对铸造Al-7.5Si-4Cu合金力学性能和组织的影响(英文)

研究了单一和复合Al-5Ti-B、RE和Al-10Sr细化变质剂对砂型铸造Al-7.5Si-4Cu合金力学性能、显微组织、细化变质效果及其金属间化合物变化的影响。结果表明:与单一细化变质处理以及铸态相比,经过添加质量分数为0.8%的Al-5Ti-B、0.1%的RE和0.1%的Al-10Sr细化变质剂复合细化变质处理后铸造Al-7.5Si-4Cu合金的力学性能和显微组织都得到了显著改善。对于单一细化变质处理,加入0.8%的Al-5Ti-B中间合金后,合金的抗拉强度和布氏硬度得到大幅度提高,并且细化了α(Al)相。加入0.1%的RE中间合金后,合金的伸长率得到了最大程度的提高。这是因为RE的加入使铝合金熔液而得到净化,同时改变了金属间化合物的形状。而加入0.1%的Al-10Sr变质剂后,合金的屈服强度得到改善,但其他性能的改善有限。Al-10Sr变质剂对共晶硅具有较强的变质作用,但使得铝合金熔体含气量增加并形成严重的柱状晶组织。利用硅相的平均面积和长宽比描述细化变质效果得到的结论与力学性能和组织分析的结果相同。     

铝合金用中间合金细化剂

综述了中间合金细化剂对铝合金晶粒细化处理的研究与应用现状。对具有代表性的细化机理进行了分析和讨论。     

Preparation of Ni-W-10Y_2O_3 refiner and refinement mechanism in a superalloy

A novel grain refiner composed of nickel,tungsten and yttria was prepared by the powder metallurgy way. The microstructure of the refiner alloy was studied by optical microscope(OM),scanning electron microscope(SEM) and energy dispersive spec-troscopy(EDS). The refinement process was simplized. It was shown that the alloy grains could be refined by addition of the refiners apparently even at high pouring temperature. The average grain size of the refiner free alloy was 4 mm,and 0.4 mm for the refined alloy. The fine-grain superalloy has excellent mechanical properties at intermediate temperature. The refinement mechanism was discussed.