Surface characteristics of a porous-surfaced Ti-6Al-4V implant fabricated by electro-discharge-compaction

Electro-discharge-compaction (EDC) is a unique method for producing porous-surfaced metallic implants. The objective of the present studies was to examine the surface characteristics of the Ti-6Al-4V implants formed by EDC. Porous-surfaced Ti-6Al-4V implants were produced by employing EDC using 480 F capacitance and 1.5 kJ input energy. X-ray photoelectron spectroscopy was used to study the surface characteristics of the implant materials. C, O, and Ti were the main constituents, with smaller amounts of Al and V. EDC Ti-6Al-4V also contained N. Titanium was present mainly in the forms of mixed oxides and small amounts of nitride and carbide were observed. Al was present in the form of aluminum oxide, while V in the implant surface did not contribute to the formation of the surface oxide film. The surface of conventionally prepared Ti-6Al-4V primarily consists of TiO₂, whereas, the surface of the EDC-fabricated Ti-6Al-4V consists of complex Ti and Al oxides as well as small amounts of titanium carbide and nitride components. However, preliminary studies indicated that the implant was biocompatible and supports rapid osseointegration.     

Laser surface modification of Ti-6Al-4V alloy

Hardening of Ti-6Al-4V alloy with laser surface melting (LSM) and laser surface alloying (LSA) techniques was attempted. Both LSM and LSA were carried out in a nitrogeneous atmosphere. Niobium, molybdenum and zirconium were used as alloying elements in the LSA. A hardness increase was observed for both LSM and LSA. Maximum hardness was obtained for LSM and zirconium alloy addition. In LSM, hardness increased almost three-fold in comparison to the substrate, which has a Vickers hardness of 350, by the formation of TiN in the region of 100 m melt depth. Hardness then decreased slowly and reached a minimum of 580 VHN at the maximum melt depth of 750 m. However, hardness for the zirconium alloy addition was uniform throughout the melted zone. Ageing treatments were performed for all specimens at 450C and different ageing times. Hardness measurements and X-ray diffraction were utilized to delineate the features associated with the hardening of the melted zone.     

Laser surface melting of Ti-6Al-4V alloy

Surface hardening of Ti-6Al-4V alloy with laser surface melting (LSM) in a nitrogen atmosphere has been studied. In LSM, hardness increased almost three-fold in comparison to that of the substrate, the latter having a Vickers hardness of 350, by the formation of TiN in the range of 100m of melt depth. Hardness, then, decreased slowly and reached a minimum of 580 VHN at a maximum melt depth of 750m. -Ti was formed in the heat-affected zone (HAZ) with a VHN of 450. Ageing treatments were performed for all specimens at 450 °C and different ageing times (1–20h). Short ageing treatments increased the hardness in the melted zone as well as in the HAZ (1–3h). Long ageing treatments (7–20h) resulted in uniform hardness distribution in the melted zone.     

Biaxial deformation of Ti-6Al-4V and Ti-6Al-4V/TiC composites by transformation-mismatch superplasticity

Gas-pressure bulge forming of unreinforced Ti-6Al-4V and TiC-reinforced Ti-6Al-4V was performed while cycling the temperature around the allotropic transformation range of the alloy (880–1020 °C). The resulting domes exhibited very large strains to fracture without cavitation, demonstrating for the first time the use of transformation-mismatch superplasticity under a biaxial state of stress for both an alloy and a composite. Furthermore, much faster deformation rates were observed upon thermal cycling than for control experiments performed under the same gas pressure at a constant temperature of 1000°C, indicating that efficient superplastic forming of complex shapes can be achieved by transformation-mismatch superplasticity, especially for composites which are difficult to shape with other techniques. However, the deformation rate of the cycled composite was lower than for the alloy, most probably because the composite exhibits lower primary and secondary isothermal creep rates. For both cycled materials, the spatial distribution of principal strains is similar to that observed in domes deformed by isothermal microstructural superplasticity and the forming times can be predicted with existing models for materials with uniaxial strain rate sensitivity of unity. Thus, biaxial transformation-mismatch superplasticity can be modeled within the well-known frame of biaxial microstructural superplasticity, which allows accurate predictions of forming time and strain spatial distribution once the uniaxial constitutive equation of the material is known.     

Fatigue behavior of Ti-6Al-4V cellular structures fabricated by additive manufacturing technique

Porous titanium and its alloys have been considered as promising replacement for dense implants, as they possess low elastic modulus comparable to that of compact human bones and are capable of providing space for in-growth of bony tissues to achieve a better fixation. Recently, the additive manufacturing (AM) method has been successfully applied to the fabrication of Ti-6Al-4V cellular meshes and foams. Comparing to traditional fabrication methods, the AM method offers advantages of accurate control of complex cell shapes and internal pore architectures, thus attracting extensive attention. Considering the long-term safety in the human body, the metallic cellular structures should possess high fatigue strength. In this paper, the recent progress on the fatigue properties of Ti-6Al-4V cellular structures fabricated by the AM technique is reviewed. The various design factors including cell shapes, surface properties, post treatments and graded porosity distribution affecting the fatigue properties of additive manufactured Ti-6Al-4V cellular structures were introduced and future development trends were also discussed.     

Effect of mean stress on fretting fatigue of Ti-6Al-4V on Ti-6Al-4V

Fretting fatigue tests of Ti‐6Al‐4V on Ti‐6Al‐4V have been conducted to determine the influence of stress amplitude and mean stress on life. The stress ratio was varied from R=−1 to 0.8. Both flat and cylindrical contacts were studied using a bridge‐type fretting fatigue test apparatus operating either in the partial slip or mixed fretting regimes. The fretting fatigue lives were correlated to a Walker equivalent stress relation. The influence of mean stress on fretting fatigue crack initiation, characterized by the value of the Walker exponent, is smaller compared with plain fatigue. The fretting fatigue knockdown factor based on the Walker equivalent stress is 4. Formation of fretting cracks is primarily associated with the tangential force amplitude at the contact interface. A simple fretting fatigue crack initiation metric that is based on the strength of the singular stress field at the edge of contact is evaluated. The metric has the advantage in that it is neither dependent on the coefficient of friction nor the location of the stick/slip boundary, both of which are often difficult to define with certainty a priori.     

Fatigue Behavior of Ti-6Al-4V

Low-cycle-fatigue texts in vacuum and air were performed. Under cyclic loading the Ti-6Al-4V showed both cyclic hardening and cyclic softening depending on heat treatment, stress amplitude, and microstructure. Plastic deformation of the β-phase in the unaged condition due to stress induced martensitic transformation caused cyclic hardening. Cyclic softening was observed if the α-phase hardened by coherent Ti₃Al particles was plastically deformed. Equiaxed microstructures exhibited a stronger cyclic softening than lamellar structures. This behavior could be explained by the pronounced texture of the equiaxed microstructures, whereas the lamellar structures were texture-free. The fatigue life was influenced by the cyclic softening process mainly in the low-cycle-fatigue regime. The fatigue life at normalized stress amplitude (σ_a/σ_y) was shorter for microstructures with strong cyclic softening as compared to microstructures with lower cyclic softening.     

Surface modification of Ti-4Al-2V alloy by nitrogen implantation

Ti-4Al-2V is a new type of alpha titanium alloy that suitable for the application in high-temperature and high-pressure water/steam environment. Ti-4Al-2V can be used in marine engineering, nuclear power industry. In this paper the surface characterization of the Ti-4Al-2V implanted with 75 keV nitrogen with fluences of 3 × 10¹⁷ and 8 × 10¹⁷ N⁺/cm² is investigated by glancing-incidence XRD, XPS and microhardness. The results show that new phase TiN are formed after N implantation in the surface region. The nitrogen implantation increases the surface hardness up to 340 and 260% for fluence of 8 × 10¹⁷ and 3 × 10¹⁷ N⁺/cm², respectively. The enhancement of hardness is related to the formation of TiN and irradiation induced hardness.     

Microstructure and properties of Ti-6Al-4V fabricated by low-power pulsed laser directed energy deposition

Thin-wall structures of Ti-6Al-4V were fabricated by low-power pulsed laser directed energy deposition. During deposition, consistent with prior reports, columnar grains were observed which grew from the bottom toward the top of melt pool tail. This resulted in a microstructure mainly composed of long and thin prior epitaxial β columnar grains (average width ≈200 μm). A periodic pattern in epitaxial growth of grains was observed, which was shown to depend upon laser traverse direction. Utilizing this, a novel means was proposed to determine accurately the fusion boundary of each deposited layer by inspection of the periodic wave patterns. As a result it was applied to investigate the influence of thermal cycling on microstructure evolution. Results showed that acicular martensite, α' phase, and a small amount of Widmanstätten, α laths, gradually converted to elongated acicular α and a large fraction of Widmanstätten α laths under layer-wise thermal cycling. Tensile tests showed that the yield strength, ultimate tensile strength and elongation of Ti-6Al-4V thin wall in the build direction were 9.1%, 17.3% and 42% higher respectively than those typically observed in forged solids of the same alloy. It also showed the yield strength and ultimate tensile strength of the transverse tensile samples both were ˜13.3% higher than those from the build direction due to the strengthening effect of a large number of vertical β grain boundaries, but the elongation was 69.7% lower than that of the build direction due to the uneven grain deformation of β grains.     

基于气体捕捉法的泡沫Ti-6Al-4V等温发泡规律研究

为了确定气体捕捉法制备泡沫Ti-6Al-4V等温发泡过程中孔隙率和微观孔洞的变化规律,在不同发泡温度及发泡时间下制备了泡沫Ti-6Al-4V.运用阿基米德原理对泡沫Ti-6Al-4V的孔隙率进行测量,通过OM和SEM对其微观特征进行观察.研究表明:泡沫Ti-6Al-4V的孔隙率及孔径均随等温发泡温度升高而增加;但当发泡温度大于950℃时,孔隙率和孔径均减小,且孔洞形态由球形变成多边形,这是由于基体内生成大尺寸β相造成的.增加发泡时间能以促进孔洞长大的方式提高泡沫Ti-6Al-4V的孔隙率,球形孔洞数量随着发泡时间的增加逐渐增多.经950℃/10 h发泡得到了孔隙率34.2%、孔径平均值156μm、孔洞为球形且分布弥散的泡沫Ti-6Al-4V.     

Thermomechanical Behavior of Ti-6Al-4V Alloy

Ti-6Al-4V, among the Ti alloys, is the most widely used. In the present work, the behavior of Ti-6Ak-4V alloy has beeninvestigated by the uniaxial hot isothermal compression tests and a series of dilatometric experiments were also carried out todetermine the transformation temperatures at different cooling rates. Specimens for hot compression tests were homogenizedat 1050℃ for 10 min and then quickly cooled to different straining temperatures from 1050 to 850℃. Cooling rates were chosenfast enough to prevent high temperature transformation during cooling. Compression tests were conducted at temperaturesfrom 1050 to 850℃ in steps of 50℃ at constant true strain rates of 10~(-3) or 10~(-2) s~(-1). The apparent activation energy forcompression in two-phase region was calculated 420 kJ·mol~(-1). Partial globularization of cr phase was observed in the specimendeformed at low strain rates and at temperatures near the transformation zone and annealed after deformation.     

Ti-6Al-4V合金表面超声振动滚压强化研究

采用超声振动滚压加工技术对Ti-6Al-4V合金表面进行处理,探究该项技术对Ti-6Al-4V合金表面质量的影响。通过对该工艺加工前后的Ti-6Al-4V合金进行表面粗糙度参数、XRD图谱、截面微观形貌、表层残余应力及显微硬度的对比分析,结果表明:经该工艺处理后的合金表面各项粗糙度参数皆有明显降低;加工后的合金表面XRD图谱的衍射峰减弱且宽化,衍射角向高角度方向偏移;加工后的合金表层β相组织相较加工前明显细化,且随着深度增加β相组织逐渐增大;在距离表面约50μm位置的残余应力值最大可达到-967 MPa;加工后的合金表面显微硬度可达到421HV,且在0~140μm的深度范围内,显微硬度随着深度的增加逐渐减小至与基体硬度一致。经超声振动滚压加工后的Ti-6Al-4V合金表面质量显著提高,有利于提高其零部件的使用性能。     

Optimal machining conditions for turning Ti-6Al-4V using response surface methodology

Machining titanium is one of ever-increasing magnitude problems due to its characteristics such as low thermal conductivity, modulus of elasticity and work
hardening. The efficient titanium alloy machining involves a proper selection of process parameters to minimize the tangential force (F_z) and surface roughness (R_a). In the present work, the performance of PVD/TiAlN coated carbide inserts was investigated using response surface methodology (RSM) for turning Ti-6Al-4V. The effects of process parameters such as speed (v), feed (f), depth of cut (d) and back rake angle (γ_y) on F_z and R_a were investigated.
The experimental plan used for four factors and three levels was designed based on face centered, central composite design (CCD). The experimental results indicated that F_z increased with the increase in d, f and decreased with the increase in v and γ_y, whereas Ra decreased with the increase in v and γ_y, and increased with d and v. The goodness of fit of the regression equations and model fits (R ²) for F_z and R_a were found to be 0.968 and 0.970, which demonstrated that it was an effective model. A confirmation test was also conducted in order to verify the correctness of the model.     

Microstructural Features of Friction-Welded Ti-6Al-4V Joint

1. IntroductionTi-6Al--4V is presently the most widely used Tialloyt especially in aerospace and marine industries.The fabrication of many structural components madeof Ti--6Al-4V alloy often requires welding. The highheat input and fast cooling rate during welding frequently lead to local microstructure changes which,in turn, change the local mechanical behavior in thewelded joint and, thereby, the overall performanceof the l'velded component[1'2]. In Ti-6Al-4V jointswelded with the laser …     

Superplastic deformation of strongly textured Ti-6Al-4V

Changes in microstructure and texture during superplastic deformation of strongly textured Ti-6Al-4V bar have been determined in order to establish the cause of stress and strain anisotropy. The effect of strain on the microstructure of the alloy was to cause a progressive break-up, due to grain-boundary sliding, of an initially directional microstructure containing contiguous-phase. The texture of the-phase, however, changed very little with superplastic strain but that of the-phase was randomized. Shape changes predicted by permitted deformation modes in the-phase did not correlate with the observed shape changes, whereas the observed anisotropy could be explained by the break-up of the contiguous-phase. A model to account for this anisotropy is described briefly, together with a typical microstructure which should exhibit isotropic superplastic deformation.     

Ti-6Al-4V组织相变研究进展

钛合金因具有密度小、延展性好、疲劳性优异和断裂性能以及比强度高等优点而被广泛应用于航空航天等领域。综述了近年来国内外学者在Ti-6Al-4V固态相变理论和实验研究方面的进展情况,总结了其由β相区在不同冷却速率下所得到的相变组织,得到了hcp-α向bcc-β转变时具有伯格斯取向关系,介绍了包括马氏体相变、块型转变以及扩散相变的转变温度,当冷却速率达到525℃/s时发生马氏体相变,β相将转变为α￠相,当冷却速率为20~410℃/s时发生竞争扩散型相变β→α_m,低于20℃/s发生扩散控制相变,原始β晶粒中出现不规则的αGB、初生α集束和魏氏α组织。最后探究了新技术在Ti-6Al-4V微观相变组织中的应用。     

Creep failure mechanisms of a Ti-6Al-4V thick plate

The creep failure operating mechanisms of a 17-mm thick plate of a Ti–6Al–4V alloy in various heat treating conditions have been investigated. Specimens in the as-received, mill-annealed, condition (50  min maintenance at 720 °C and air cooled as the final step of the thermomechanical process) showed the lowest creep resistance and their metallographic analysis revealed that the temperature-activated dislocation climb was the mechanism responsible for the failure and that observed holes were generated by plastic deformation, rather than by creep cavitation. Conversely, maximum times to failure were recorded in beta-annealed specimens (1030 °C for 30  min, air cooled and aged for 2  h at 730 °C). The fracture surfaces of these broken specimens exhibited an intergranular morphology that was attributed to grain boundary sliding along the former beta grains. Finally, alpha–beta field-annealed samples (940 °C 4  h, and furnace cooled to 700 °C) possessed intermediate lives between those of mill-annealed and beta-annealed specimens and the failure operating mechanism was diffusional creep by the nucleation and coalescence of the creep cavities generated at the alpha–beta interfaces and the triple points.     

Ti及Ti-6Al-4V的水基凝胶注模成形研究

将凝胶注模工艺应用于金属Ti及Ti-6Al-4V合金粉末的坯体成形,研究了高固相含量的Ti粉和Ti-6Al-4V合金粉末的料浆的制备.结果表明,用凝胶注模工艺制备出了固相含量为54ψ%的钛合金粉末料浆和形状复杂的坯体;粉末的颗粒形状是影响料浆固相含量的重要因素,球形粉末配制成的浆料固相含量最高,近球形次之,片状最低;分散剂柠檬酸铵也可以显著提高浆料的固相含量.