Operation of solid oxide fuel cells with alternative hydrogen carriers

Future electricity production will use fossil-free sources with zero CO₂ emission or closed carbon cycle technologies based on renewable sources. While hydrogen is considered a key energy source, its production at present time relies heavily on fossil fuels. Furthermore, distribution and storage are not well established and require substantial investments. This is a strong motivation to identify alternative, safe, high power density hydrogen carriers, where existing logistics and infrastructure can be utilized. In this contribution, ammonia and biogas are considered for high-efficient electricity production in solid oxide fuel cells (SOFCs). It is demonstrated that the properties and operating conditions of SOFC allow for direct use of these fuels, with fuel pretreatment inside the SOFC anode. The high efficient electricity production using pure ammonia or real biogas was successfully proven on state-of-the-art SOFCs. Even without optimization of operating parameters, electrical efficiencies of 40–50% and high and stable power output were demonstrated.     

Micro-cogeneration based on solid oxide fuel cells: Market opportunities in the agriculture/livestock sector

Bio-waste embeds an extraordinary renewable potential, and it becomes a source of energy savings when transformed into a valuable resource, like biogas. Cogeneration (CHP) from biogas employing high-temperature Solid Oxide Fuel Cells (SOFCs) scores a high sustainability level, thanks to improved environmental and energy performances. The synergy between the niche market of small/micro biogas producers and SOFCs might act as a springboard to open market opportunities for both SOFC commercialization and business upgrade of small farms. However, local regulations, waste management, renewable energy subsidies and, above all, availability of eligible sites, determine real chances for on-the-ground implementation.Through a detailed analysis of the application scenario, this research aims at investigating opportunities for the experimentation of SOFC–CHP in small biogas plants and identifying the possible bottlenecks for future deployment. When it becomes relevant, energy conversion of livestock (especially cattle and swine) and agriculture waste requires SOFC modules from 10 kW_e to 35 kW_e. This is in line with the current status of SOFC suppliers. Moreover, considering the fuel cell market roll-out, the average levelized cost of electricity is expected to decrease from 0.387 €/kWh to 0.115 €/kWh, when electricity is produced from livestock waste available on-site.     

Integration of a municipal solid waste gasification plant with solid oxide fuel cell and gas turbine

An interesting source of producing energy with low pollutants emission and reduced environmental impact are the biomasses; particularly using Municipal Solid Waste (MSW) as fuel, can be a competitive solution not only to produce energy with negligible costs but also to decrease the storage in landfills. A Municipal Solid Waste Gasification Plant Integrated with Solid Oxide Fuel Cell (SOFC) and Gas Turbine (GT) has been studied and the plant is called IGSG (Integrated Gasification SOFC and GT). Gasification plant is fed by MSW to produce syngas by which the anode side of an SOFC is fed wherein it reacts with air and produces electricity. The exhausted gases out of the SOFC enter a burner for further fuel combusting and finally the off-gases are sent to a gas turbine to produce additional electricity. Different plant configurations have been studied and the best one found to be a regenerative gas turbine. Under optimized condition, the thermodynamic efficiency of 52% is achieved. Variations of the most critical parameters have been studied and analyzed to evaluate plant features and find out an optimized configuration.     

Technical, economic and environmental analysis of energy production from municipal solid waste

Four technologies are investigated which produce energy from municipal solid waste (MSW): incineration, gasification, generation of biogas and utilisation in a combined heat and power (CHP) plant, generation of biogas and conversion to transport fuel.Typically the residual component of MSW (non-recyclable, non-organic) is incinerated producing electricity at an efficiency of about 20% and thermal product at an efficiency of about 55%. This is problematic in an Irish context where utilisation of thermal products is not the norm. Gasification produces electricity at an efficiency of about 34%; this would suggest that gasification of the residual component of MSW is more advantageous than incineration where a market for thermal product does not exist. Gasification produces more electricity than incineration, requires a smaller gate fee than incineration and when thermal product is not utilised generates less greenhouse gas per kWh than incineration. Gasification of MSW (a non-homogenous fuel) is, however, not proven at commercial scale.Biogas may be generated by digesting the organic fraction of MSW (OFMSW). The produced biogas may be utilised for CHP production or for transport fuel production as CH₄-enriched biogas. When used to produce transport fuel some of the biogas is used in a small CHP unit to meet electricity demand on site. This generates a surplus thermal product.Both biogas technologies require significantly less investment costs than the thermal conversion technologies (incineration and gasification) and have smaller gate fees. Of the four technologies investigated transport fuel production requires the least gate fee. A shortfall of the transport fuel production technology is that only 50% of biogas is available for scrubbing to CH₄-enriched biogas.     

Thermo-economic optimization of an indirectly coupled solid oxide fuel cell/gas turbine hybrid power plant

Power generation using gas turbine (GT) power plants operating on the Brayton cycle suffers from low efficiencies, resulting in poor fuel to power conversion. A solid oxide fuel cell (SOFC) is proposed for integration into a 10-MW GT power plant, operating at 30% efficiency, in order to improve system efficiencies and economics. The SOFC system is indirectly coupled to the GT, in order to minimize the disruption to the GT operation. A thermo-economic model is developed to simulate the hybrid power plant and to optimize its performance using the method of Lagrange Multipliers. It predicts an optimized power output of 18.9 MW at 48.5% efficiency, and a breakeven per-unit energy cost of USD 4.54 ¢ kW h⁻¹ for the hybrid system based on futuristic mass generation SOFC costs.     

Upgrading biogas produced at dairy farms into renewable natural gas by methanation

Renewable natural gas can be produced from raw biogas, a product of the anaerobic decomposition of organic material, by upgrading its CO₂ content (25‐50%) via thermocatalytic hydrogenation (CO₂ methanation). The H₂ needed for this reaction can be generated by water electrolysis powered by carbon emission‐free energy sources such as renewable or nuclear power, or using surplus electricity. Herein, after briefly outlining some aspects of biogas production at dairy farms and highlighting recent developments in the design of methanation systems, a case study on the renewable natural gas generation is presented. The performance of a system for renewable natural gas generation from a 2000‐head dairy farm livestock manure is evaluated and assessed for its economic potential. The project is predicted to generate revenue through the sale of energy and carbon credits with the payback period of 5 years, with a subsidized energy price.     

An analysis of power generation from municipal solid waste (MSW) incineration plants in Taiwan

Heavily (about 99%) depending on imported energy, Taiwan, a country in the subtropics, has limited natural resources. In this regard, biomass energy from (MSW) municipal solid waste incineration plants thus became attractive during the 1990s. The objective of this paper is to present a comprehensive analysis of MSW-to-energy in Taiwan. This paper gave a concise summary of current status of domestic energy consumption &; power generation, MSW generation &; MSW incineration treatment, and electricity generation from MSW incineration plants since 2000. Based on the electricity generation in 2008 (i.e., 2967 GWh), the environmental benefit of mitigating CO₂ emissions and the economic benefit of selling electricity were preliminarily calculated to be around 1.9 × 10⁶ tons and US$ 1.5 × 10⁸, respectively. However, since the heat content of incinerated MSW and the methodologies were used on the recommendation of the (IPCC) Intergovernmental Panel on Climate Change, the net emissions of CO₂ equivalent from methane (CH₄) &; nitrous oxide (N₂O) have been estimated to be at around 76,000 and 88,000 tons/year compared to coal and oil, respectively.     

Thermo-economic modeling of an indirectly coupled solid oxide fuel cell/gas turbine hybrid power plant

Power generation using gas turbine (GT) power plants operating on the Brayton cycle suffers from low efficiencies, resulting in poor fuel to power conversion. A solid oxide fuel cell (SOFC) is proposed for integration into a 10 MW gas turbine power plant, operating at 30% efficiency, in order to improve system efficiencies and economics. The SOFC system is indirectly coupled to the gas turbine power plant, paying careful attention to minimize the disruption to the GT operation. A thermo-economic model is developed for the hybrid power plant, and predicts an optimized power output of 20.6 MW at 49.9% efficiency. The model also predicts a break-even per-unit energy cost of USD 4.65 ¢ kWh⁻¹ for the hybrid system based on futuristic mass generation SOFC costs. This shows that SOFCs may be indirectly integrated into existing GT power systems to improve their thermodynamic and economic performance.     

Analysis of small-scale biogas utilization systems on Ontario cattle farms

The production of biogas through the anaerobic digestion of cattle manure and its subsequent use in the generation of electricity on larger farms in Ontario is currently economically attractive. This is a result of the Ontario Feed-In Tariff (FIT) program, which provides incentivized rates for the production of electricity from biogas. Although larger farms can take advantage of the higher rates for electricity, there are substantially more smaller farms for which individually designed and engineered biogas systems would be prohibitively expensive. By employing the concept of modular biogas plants, this analysis evaluates the economics of small-scale biogas utilization systems. Dairy farms with at least 33 animals and beef farms with at least 78 animals can operate economically attractive biogas systems. This analysis shows that approximately 9000 additional Ontario cattle farms would be able to take advantage of the FIT program, which would add 120 MW_e of renewable energy capacity to the Ontario electrical grid.     

Distributed power generation via gasification of biomass and municipal solid waste: A review

The access to electricity has increased worldwide, growing from 60 million additional consumers per year in 2000–2012 to 100 million per year in 2012–2016. Despite this growth, approximately 675 million people will still lack access to electricity in 2030, indicating that electricity demand will continue to increase. Unfortunately, traditional large fossil power technologies based on coal, oil and natural gas lead to a major concern in tackling worldwide carbon dioxide emissions, and nuclear power remains unpopular due to public safety concerns. Distributed power generation utilizing CO₂-neutral sources, such as gasification of biomass and municipal solid wastes (MSW), can play an important role in meeting the world energy demand in a sustainable way. This review focuses on the recent technology developments on seven power generation technologies (i.e. internal combustion engine, gas turbine, micro gas turbine, steam turbine, Stirling engine, organic rankine cycle generator, and fuel cell) suitable for distributed power applications with capability of independent operation using syngas derived from gasification of biomass and MSW. Technology selection guidelines is discussed based on criteria, including hardware modification required, size inflexibility, sensitivity to syngas contaminants, operational uncertainty, efficiency, lifetime, fast ramp up/down capability, controls and capital cost. Major challenges facing further development and commercialization of these power generation technologies are discussed.     

Design of hybrid power-to-power systems for continuous clean PV-based energy supply

The increasing penetration of intermittent renewable sources, fostering power sector decarbonization, calls for the adoption of energy storage systems as an essential mean to improve local electricity exploitation, reducing the impact of distributed power generation on the electric grid. This work compares the use of hydrogen-based Power-to-Power systems, battery systems and hybrid hydrogen-battery systems to supply a constant 1 MW_el load with electricity locally generated by a photovoltaic plant. A techno-economic optimization model is set up that optimizes the size and annual operation of the system components (photovoltaic field, electrolyzer, hydrogen storage tanks, fuel cell and batteries) with the objective of minimizing the annual average cost of electricity, while guaranteeing an imposed share of local renewable self-generation. Results show that, with the present values of investment costs and grid electricity prices, the installation of an energy storage system is not economically attractive by itself, whereas the installation of PV panels is beneficial in terms of costs, so that the baseline optimal solution consists of a 4.2 MW_p solar field capable to self-generate 33% of the load annually. For imposed shares of self-generation above 40%, decoupling generation and consumption becomes necessary. The use of batteries is slightly less expensive than the use of hydrogen storage systems up to a 92% self-generation rate. Above this threshold, seasonal storage becomes predominant and hybrid storage becomes cheaper than batteries. The sale of excess electricity is always important to support the plant economics, and a sale price reduction sensibly impacts the results. Hydrogen storage becomes more competitive when the need for medium and long terms energy shift increases, e.g. in case of having a cap on the available PV capacity.     

Thermally driven cooling coupled with municipal solid waste-fired power plant: Application of combined heat,cooling and power in tropical urban areas

Energy recovery from flue gases in thermal treatment plants is an integral part of municipal solid waste (MSW) management for many industrialized nations. Often cogeneration can be employed for both enhancing the plant profitability and increasing the overall energy yield. However, it is normally difficult to justify traditional cogeneration in tropical locations since there is little need for the heat produced. The main objective of this article is to investigate the opportunities and potentials for various types of absorption technologies driven by MSW power plants for providing both electricity and cooling. Results show that cogeneration coupling with thermally driven cooling is sustainably and economically attractive for both electricity and cooling production. The thermally driven cooling provides significant potential to replace electrically driven cooling: such systems are capable of providing cooling output and simultaneously increasing electricity yield (41%). The systems are also capable of reducing the fuel consumption per unit of cooling in comparison with conventional cooling technology: a reduction of more than 1 MW_fuel/MW_cooling can be met in a small unit. MSW power plant coupled with thermally driven cooling can further reduce CO₂ emissions per unit of cooling of around 60% as compared to conventional compression chiller and has short payback period (less than 5 years).     

固体氧化物燃料电池与燃气轮机联合发电系统模拟研究

固体氧化物燃料电池(SOFC)是一种高效低污染的新型能源。建立了以天然气为燃料的固体氧化物燃料电池和燃气轮机(GT)联合发电系统的计算模型,并对具体系统进行计算。结果表明：SOFC与GT组戍的联合发电系统,发电效率可达68％(LHV);加上利用的余热,整个系统的能量利用率可以超过80％。文中还分析了SOFC的工作压力、电流密度等参数对系统性能的影响,提高工作压力,可以增加电池发电量,提高系统的发电效率;而电流密度的增大将使SOFC及整个系统的发电量降低。     

Methane generation in landfills

Methane gas is a by-product of landfilling municipal solid wastes (MSW). Most of the global MSW is dumped in non-regulated landfills and the generated methane is emitted to the atmosphere. Some of the modern regulated landfills attempt to capture and utilize landfill biogas, a renewable energy source, to generate electricity or heat. As of 2001, there were about one thousand landfills collecting landfill biogas worldwide. The landfills that capture biogas in the US collect about 2.6 million tonnes of methane annually, 70% of which is used to generate heat and/or electricity. The landfill gas situation in the US was used to estimate the potential for additional collection and utilization of landfill gas in the US and worldwide. Theoretical and experimental studies indicate that complete anaerobic biodegradation of MSW generates about 200 Nm³ of methane per dry tonne of contained biomass. However, the reported rate of generation of methane in industrial anaerobic digestion reactors ranges from 40 to 80 Nm³ per tonne of organic wastes. Several US landfills report capturing as much as 100 Nm³ of methane per ton of MSW landfilled in a given year. These findings led to a conservative estimate of methane generation of about 50 Nm³ of methane per ton of MSW landfilled. Therefore, for the estimated global landfilling of 1.5 billion tones annually, the corresponding rate of methane generation at landfills is 75 billion Nm³. Less than 10% of this potential is captured and utilized at this time.     

Multi-objective optimization of biogas systems producing hydrogen and electricity with solid oxide fuel cells

The design of solid oxide fuel cells (SOFC) using biogas for distributed power generation is a promising alternative to reduce greenhouse gas emissions in the energy and waste management sectors. Furthermore, the high efficiency of SOFCs in conjunction with the possibility to produce hydrogen may be a financially attractive option for biogas plants. However, the influence of design variables in the optimization of revenues and efficiency has seldom been studied for these novel cogeneration systems. Thus, in order to fulfill this knowledge gap, a multi-objective optimization problem using the NSGA-II algorithm is proposed to evaluate optimal solutions for systems producing hydrogen and electricity from biogas. Moreover, a mixed-integer linear optimization routine is used to ensure an efficient heat recovery system with minimal number of heat exchanger units. The results indicate that hydrogen production with a fuel cell downstream is able to achieve high exergy efficiencies (65–66%) and a drastic improvement in net present value (1346%) compared with sole power generation. Despite the additional equipment, the investment costs are estimated to be quite similar (12% increase) to conventional steam reforming systems and the levelized cost of hydrogen is very competitive (2.27 USD/kgH₂).     

Joint electricity and carbon market for Northeast Asia energy interconnection

Decarbonization of the electricity sector is crucial to mitigate the impacts of climate change and global warming over the coming decades. The key challenges for achieving this goal are carbon emission trading and electricity sector regulation, which are also the major components of the carbon and electricity markets, respectively. In this paper, a joint electricity and carbon market model is proposed to investigate the relationships between electricity price, carbon price, and electricity generation capacity, thereby identifying pathways toward a renewable energy transition under the transactional energy interconnection framework. The proposed model is a dynamically iterative optimization model consisting of upper- level and lower-level models. The upper-level model optimizes power generation and obtains the electricity price, which drives the lower-level model to update the carbon price and electricity generation capacity. The proposed model is verified using the Northeast Asia power grid. The results show that increasing carbon price will result in increased electricity price, along with further increases in renewable energy generation capacity in the following period. This increase in renewable energy generation will reduce reliance on carbon-emitting energy sources, and hence the carbon price will decline. Moreover, the interconnection among zones in the Northeast Asia power grid will enable reasonable allocation of zonal power generation. Carbon capture and storage (CCS) will be an effective technology to reduce the carbon emissions and further realize the emission reduction targets in 2030-2050. It eases the stress of realizing the energy transition because of the less urgency to install additional renewable energy capacity.     

Biohythane as an energy feedstock for solid oxide fuel cells

Biogas (60%-CH₄, 40%- CO₂) is a potential source of renewable energy when used as energy feedstock for solid oxide fuel cells (SOFC), but releases biogenic CO₂ emissions. Hybrid SOFC performance can be affected by fuel composition and reformer performance. Biohythane (58%-CH₄, 35%-CO₂ and 7% H₂) can be a better alternative providing balance between energy and biogenic emissions. Biohythane performance is studied for a 120 kW SOFC stack using ASPEN process model and compared with other feed stocks. This work is the first to study and report on the application of biohythane in SOFC systems. Biohythane was found to produce less biogenic CO₂ emissions and 6% less CO at the reformer than biogas. Comparisons show that biohythane provides better efficiencies in hybrid SOFC systems. Sensitivity studies recommends operation of stack with biohythane at Steam to Carbon Ratio (STCR) = 2.0, i = 200 mA cm⁻² and U_F = 0.85 respectively.     

考虑源荷不确定性的分时电价动态修正机制研究

针对新型电力系统中可再生能源出力及负荷需求的不确定性造成源荷协调困难,导致难以制定合理的分时电价的问题,该文提出一种考虑源荷不确定性的分时电价动态修正机制。首先,根据可再生能源出力的波动性以及不确定性,建立新能源并网功率与并网电量偏差量化模型;其次,根据需求侧负荷的变化特征,结合可再生能源出力不确定性,通过多种不确定性因素影响条件的误差计算方法,建立电价概率密度模型。然后,根据负荷上报的用电量以及预报电价,建立考虑源荷不确定性的电力市场分时电价动态修正与优化模型,并采用粒子群算法进行模型求解。最后,通过实际运行数据仿真验证该文所提方法的有效性。     

Thermo-economic modeling of a solid oxide fuel cell/gas turbine power plant with semi-direct coupling and anode recycling

Power generation using gas turbine (GT) power plants operating on the Brayton cycle suffers from low efficiencies, resulting in poor fuel to power conversion. A solid oxide fuel cell (SOFC) is proposed for integration into a 10 MW gas turbine power plant, operating at 30% efficiency in order to improve system efficiencies and economics. The SOFC system is semi-directly coupled to the gas turbine power plant, with careful attention paid to minimize the disruption to the GT operation. A thermo-economic model is developed for the hybrid power plant, and predicts an optimized power output of 21.6 MW at 49.2% efficiency. The model also predicts a breakeven per-unit energy cost of USD 4.70 ¢/kWh for the hybrid system based on futuristic mass generation SOFC costs. Results show that SOFCs can be semi-directly integrated into existing GT power systems to improve their thermodynamic and economic performance.     

A critical review on global trends in biogas scenario with its up-gradation techniques for fuel cell and future perspectives

Renewable biogas production technology is an excellent method for eradication of greenhouse gas emission and thereby reducing global warming. This review discusses extensively on global biomass potential, energy need and method of satisfying the energy demand through sustainable techniques. One of the best alternative technological developments for the conversion of waste into useful energy is anaerobic digestion to produce biogas. It is recognized as one among leading green energy to manage the environmental and meet the current energy tasks to tackle globally. Generally, biogas can be utilized for cooking, heat and electricity generation. In order to extend the scope of application, traces of carbon dioxide, hydrogen sulphide has to be removed by several upgrading technologies to produce high purity methane (90%). This study discusses on biogas up-gradation using physical and chemical absorption, membrane separation, cryogenic separation, hybrid technology etc. Among the various up-gradation techniques, hybrid technology yields methane purity of 97%. In addition, this work reviews about benefits and problems in anaerobic integrated Solid Oxide Fuel Cell (SOFC) with latest real-world achievement in SOFC. Several SOFC systems with dynamic model development were reviewed based on efficiency of power generation. SOFC generates 45% more electricity than generator with heat engine. This review extends the scope for further research in biogas upgradation and global warming mitigation potential with carbon credits.