Development of multimetal binding model and application to binary metal biosorption onto peat biomass

Biosorption of Cr(3+), Cu(2+) and Cd(2+) from binary metal solutions onto peat in the batch systems was investigated at pH 4. The order of maximum uptake was Cr>or=Cu>Cd and maximum uptake levels of ca. 0.4 mmol/g were observed for chromium and copper while cadmium was taken up to a maximum of ca. 0.2 mmol/g. Co-ion competition resulted in up to 70 percent decrease of primary metal uptake. A novel approach to multicomponent sorption modelling involving regression to the total metal taken up was adopted. Two extended Langmuir-type models were found to exhibit good fit to the experimental data. Using the simpler model of these, three-dimensional sorption surfaces were generated which describe the metal uptake as a function of equilibrium concentrations of both metals. These methods allow prediction of metal uptakes over a continuum of concentrations of both metals in binary systems.     

Limitations of heavy metal removal from waste water by means of algae

It has been suggested by several authors that heavy metals might be removed from aqueous systems by phytoplanktonic algae, whose high capacity for accumulating dissolved metals has previously been described. This paper shows—by comparing results obtained on accumulation factors and growth rates in different models—that metal removal by means of algae is not feasible in practice. It was found that under optimum conditions in a static system the reduction of a given initial metal concentration by 50% requires approx. 14 days, while in a dynamic model a retention time of approx. 19 days is needed to achieve the same reduction. Finally, measurements of nitrogenase activity inhibition caused by various concentrations of mercury and cadmium demonstrate that nitrogen-fixing blue-green algae can be used for biological sewage treatment only at very low heavy metal concentrations in the medium.     

Heavy metal biosorption by gellan gum gel beads

The Ni(2+) accumulation in batch mode from diluted solutions by gel beads of gellan gum (GG), alginate, kappa-carrageenan, agar, agarose, silica gel, polyacrylamide and two mixtures of GG+agar was investigated. All polymeric materials studied accumulated Ni(2+), but gel beads of GG were stable, easily obtainable and showed the highest Ni(2+) accumulation. The pH of the Ni(2+) solution was not critical for Ni(2+) accumulation. Accumulation of metals Cu(2+), Co(2+), Ni(2+), Pb(2+), Cd(2+) and Zn(2+) by GG gel beads reached the equilibrium after 24h. The removal of Pb(2+) and Cu(2+) from the aqueous solution was very efficient, with maximum metal uptake (q(max)) of 0.85 and 0.75 mmol/g dw GG, respectively. The general q(max) sequence was Pb>Cu>Ni approximately Zn=Co>Cd. In an equimolar metal mixture sorption experiment a clear reduction in accumulation was observed, except for Pb(2+) (30%). Heavy metals were desorbed with 100mM sodium citrate.     

Continuous-flow metal biosorption in a regenerable Sargassum column

Metal biosorption behavior of raw seaweed S. filipendula in ten consecutive sorption-desorption cycles has been investigated in a packed-bed flow-through column during a continuous removal of copper from a 35mg/L aqueous solution at pH 5. The elutant used was a 1% (w/v) CaCl2/HCl-solution at pH 3. The sorption and desorption was carried out for an average of 85 and 15h, respectively, representing more than 41 days of continuous use of the biosorbent. The weight loss of biomass after this time was 21.6%. The Cu-biosorption capacity of the biomass, based on the initial dry weight, remained relatively constant at approximately 38 mg Cu/g. Loss of sorption performance was indicated by a shortening breakthrough time and a broadening mass-transfer zone. The column service time, considered up to 1 mg Cu/L in the effluent, decreased continuously from 25.4 h for the first to 12.7 h for the last cycle. The critical bed length, representing the mass-transfer zone, increased almost linearly from 28 to 34cm. "Life-factors" for S. filipendula were found to be 0.0008h(-1) for the breakthrough time and 0.008cm/h for the critical bed length, using an exponential decay and linear fitting functions, respectively. Regeneration with CaCl2/HCl at pH 3 provided elution efficiencies up to 100%. Maximum concentration factors were determined to be in the range 16-44, a decreasing tendency was observed with an increasing exposure time.     

Equilibrium and kinetic modelling of Cd(II) biosorption by algae Gelidium and agar extraction algal waste

In this study an industrial algal waste from agar extraction has been used as an inexpensive and effective biosorbent for cadmium (II) removal from aqueous solutions. This biosorbent was compared with the algae Gelidium itself, which is the raw material for agar extraction. Equilibrium data follow both Langmuir and Redlich-Peterson models. The parameters of Langmuir equilibrium model are q(max)=18.0 mgg(-1), b=0.19 mgl(-1) and q(max)=9.7 mgg(-1), b=0.16 mgl(-1), respectively for Gelidium and the algal waste. Kinetic experiments were conducted at initial Cd(II) concentrations in the range 6-91 mgl(-1). Data were fitted to pseudo-first- and second-order Lagergren models. For an initial Cd(II) concentration of 91 mgl(-1) the parameters of the pseudo-first-order Lagergren model are k(1,ads)=0.17 and 0.87 min(-1); q(eq)=16.3 and 8.7 mgg(-1), respectively, for Gelidium and algal waste. Kinetic constants vary with the initial metal concentration. The adsorptive behaviour of biosorbent particles was modelled using a batch reactor mass transfer kinetic model. The model successfully predicts Cd(II) concentration profiles and provides significant insights on the biosorbents performance. The homogeneous diffusivity, D(h), is in the range 0.5-2.2 x10(-8) and 2.1-10.4 x10(-8)cm(2)s(-1), respectively, for Gelidium and algal waste.     

A preliminary model for predicting heavy metal contaminant loading from an urban catchment

The toxicity of heavy metals to biota in urban catchments has been regarded as a very important non-point source pollution issue. Numerous studies on heavy metal pollution in urban receiving waters have found that metal transport by surface runoff is closely correlated to the partitioning of the metal forms between dissolved and particulate phases, where sediment plays an important role in the transport process. Sediment cycling on urban streets, metal binding form, and rainfall character in the catchment area are considered to be the key factors for metal transport. A preliminary model is developed based on these considerations. Starting from classical build-up and wash-off processes for the suspended sediment (SS) on the urban impervious surface, the model links the transport of suspended sediment to the transport of metal species. Monitoring data from a small highway catchment were used in the model development. A total of 47 rain events over 1 year were monitored intensively at short time intervals (5-10 min) for hydrological data, rainfall intensity, and stormwater quality. In developing the model, lead was used for the metal load prediction, as it has been a common fuel additive for urban transportation. Agreement between model results and monitoring data indicates that the model can be used in predicting metal load from impervious urban areas, such as streets and roadways, on a long-term basis.     

A simplified equilibrium model for sorption of heavy metal ions from aqueous solutions on chitosan

The amounts of sorption of Cu2 , Ni2+, and Zn2+ from water on cross-linked chitosan were measured. Experiments were performed as a function of initial pH (2-5), total metal concentration (0.77-17 mol/m3), and metal concentration ratio (0.25-4) at 25 degrees C in single- and binary-metal systems. The sorption was so highly pH dependent that the isotherm could not be described by one specific equation. A simplified equilibrium model was thus proposed considering competitive sorption of proton and metal ions. The number of active sites on chitosan bound with one metal ion was adjustable and model parameters could be graphically determined. Given initial metal concentrations and solution pH, the proposed model could predict the amounts of sorption of proton and metals as well as the equilibrium pH. In general, application of the model parameters calculated in single-metal systems to the prediction of sorption in binary-metal systems was not satisfactory due to a remarkable effect of competitive sorption.     

重金属迁移转化规律研究

通过对阜阳污水处理厂的进水、曝气沉砂池、出水分析检测,研究CASS工艺对城市污水中重金属的去除效果,得出了重金属的迁移转化规律,为进一步提高CASS工艺的污水处理效果提供了科学依据。     

The efficiency of heavy metal removal by a conventional activated sludge treatment plant

The total and dissolved concentration of cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel and zinc at various points in a conventional activated sludge treatment plant have been measured. The analysis of raw sewage samples collected hourly over a 3-day period showed that metal input to the sewage treatment plant was not a continuous process but consisted of slugs of metal lasting for a discrete time. The efficiency of heavy metal removal by this model treatment plant was determined by monitoring the influent and effluent metal levels over a 4-week period.     

Binding of Cu(II) to algae in a metal buffer

The interactions of Cu(II) with algal surfaces and exudates were studied in metal-NTA buffers by a combination of several analytical techniques. Suspensions of living algae in the presence of NTA were titrated at constant pH with Cu(II). The various Cu species were determined as follows: a copper ion selective electrode was used reliably in the pCu range 9–12; differential pulse polarography was used to measure separately Cu(II)-NTA complexes and labile Cu(II) species and to evaluate the complexation of copper by ligands in solution; copper bound to the algal surfaces was extracted by acid treatment and measured by AAS. Thus, we determined both the binding of Cu to the algal surfaces and to exudates excreted by the algae. The results were interpreted in terms of conditional equilibrium constants valid at a given pH; the conditional constants, both for the binding to the surfaces and with the exudates increase in the pH range 5.0–6.5. Simple equilibrium models using the experimentally determined binding capacities and equilibrium constants were able to simulate the results and to evaluate the speciation of copper. Under the experimental conditions used, the binding of Cu(II) to algal exudates has a more significant effect on copper speciation than the binding to the algal surfaces. These extracellular ligands may play an important role in decreasing the concentration of free copper ion and thus mitigating the potential toxic effects in organisms.     

Toxicity assessment of heavy metal mixtures by Lemna minor L

The discharge of untreated electroplating wastewaters directly into the environment is a certain source of heavy metals in surface waters. Even though heavy metal discharge is regulated by environmental laws many small-scale electroplating facilities do not apply adequate protective measures. Electroplating wastewaters contain large amounts of various heavy metals (the composition depending on the facility) and the pH value often bellow 2. Such pollution diminishes the biodiversity of aquatic ecosystems and also endangers human health. The aim of our study was to observe/measure the toxic effects induced by a mixture of seven heavy metals on a bioindicator species Lemna minor L. Since artificial laboratory metal mixtures cannot entirely predict behaviour of metal mixtures nor provide us with informations relating to the specific conditions in the realistic environment we have used an actual electroplating wastewater sample discharged from a small electroplating facility. In order to obtain three more samples with the same composition of heavy metals but at different concentrations, the original electroplating wastewater sample has undergone a purification process. The purification process used was developed by Orescanin et al. [Orescanin V, Mikeli? L, Luli? S, Nad K, Rubci? M, Pavlovi? G. Purification of electroplating wastewaters utilizing waste by-product ferrous sulphate and wood fly ash. J Environ Sci Health A 2004; 39 (9): 2437-2446.] in order to remove the heavy metals and adjust the pH value to acceptable values for discharge into the environment. Studies involving plants and multielemental waters are very rare because of the difficulty in explaining interactions of the combined toxicities. Regardless of the complexity in interpretation, Lemna bioassay can be efficiently used to assess combined effects of multimetal samples. Such realistic samples should not be avoided because they can provide us with a wide range of information which can help explain many different interactions of metals on plant growth and metabolism. In this study we have primarily evaluated classical toxicity endpoints (relative growth rate, Nfronds/Ncolonies ratio, dry to fresh weight ratio and frond area) and measured guaiacol peroxidase (GPX) activity as early indicator of oxidative stress. Also, we have measured metal accumulation in plants treated with waste ash water sample with EDXRF analysis and have used toxic unit (TU) approach to predict which metal will contribute the most to the general toxicity of the tested samples.     

Alucobond铝塑复合板在金属屋面的应用

使用金属材料作为屋面是一种历史悠久建筑屋面形式,已经有两千多年的历史,随着人类文明和科学技术的不断发展,铝舍金及其复合材料逐步取代其他金属材料而被应用于建筑金属屋面。本文以“法国欧装雅公司办公楼项目”为例,向大家展示铝塑复合板屋面的设计和施工特点,为发展迅猛的中国金属屋面市场提供借鉴。     

Column biosorption of lanthanum and europium by Sargassum

Batch and column biosorption of La(3+) (lanthanum) and Eu(3+) (europium) was studied using protonated Sargassum polycystum biomass. The ion exchange sorption mechanism was confirmed by the proportional release of protons and by the total normality of the solution, which remained constant during the process. Equilibrium isotherms were determined for the binary systems, La/H and Eu/H for a total normality of 3 meq g(-1), which produced separation factors of 2.7 and 4.7, respectively, demonstrating a higher affinity of the biomass towards europium. Column runs with a single metal feed were used to estimate the intra-particle mass transfer coefficients for La and Eu (6.0 x 10(-4) and 3.7 x 10(-4) min(-1), respectively). Modeling batch and column binary systems with proton as the common ion was able to predict reasonably well the behavior of a ternary system containing protons. The software FEMLAB was used for solving the set of coupled partial differential equations. Moreover, a series of consecutive sorption/desorption runs demonstrated that the metal could be recovered and the biomass reused in multiple cycles by using 0.1N HCl with no apparent loss in the biosorbent metal uptake capacity.     

Residual heavy metal removal by an algae-intermittent sand filtration system

A laboratory scale study was undertaken to determine the feasibility of using algae growing in wastewater lagoons to absorb residual heavy metals for subsequent complete removal by intermittent sand filtration of the metal laden algae. In semi-continuous cultures the mixed algal flora native to wastewater lagoons absorbed 70–90% of the cadmium and copper from the wastewater media. Chromium absorption was less by ratio (20% was absorbed), but the mass of chromium removed was much greater as high levels of chromium were added. Only one alga (Oscillatoria sp.) which was extremely resistant to chromium grew in the chromium exposed cultures. Nearly total removal of the cadmium and copper was achieved by the algae-intermittent sand filter system. The net chromium removal agreed with the accumulation analyses.The technical feasibility of removing certain heavy metals from wastewater with such a system was established. However, in depth laboratory and field studies must be conducted to maximize system efficiency, demonstrate tactical limitations, and establish design specifications.     

Kinetics of heavy metal bioleaching from sewage sludge—II. Mathematical model

A conceptual model of the overall process of metal bioleaching from sewage sludge has been developed on the basis of experimental observations. Sludge pH was identified as the parameter which controls bacterial growth and thus the overall process. Quantitative relationships among the various process parameters were incorporated in the conceptual model, giving a mathematical model for the process. Bacterial growth, sulfate concentration and pH profiles simulated using the model were found to match experimental observations. The degree of solubilization of each metal was found to depend on the sludge pH and the type of the sludge and is given as a set of solubilization curves.     

火灾烟气毒性评价新的"RRC"动态模型及工程应用

就火灾中的死亡人数而言，最主要的威胁来自于火灾中的烟气。目前已经有很多种模型来描述火灾中的烟气毒性危害，如CO随机模型、FED、FEC和N气体模型。所有这些模型都不能反应真实火灾中烟气浓度的时空变化。根据真实火灾中的烟气危害度，选取人员的呼吸率、人员在火灾中的逃生路径、特定建筑中的烟气浓度场分布等三个对于人员致死具有决定性的因素，初步建立一个新的“RRC”动态模型来描述火灾中的烟气毒性危害，并通过算例展示了模型的工程应用。