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本文研究了复合电沉积法制备的α-Al2O3/Cu复合材料的性能和磨损特征,测定了Al2O3粒径在0.5~5μm,含量在4~16%时Al2O3/Cu复合镀层的硬度和磨损率,用扫描电镜对磨损形貌进行了分析,并对其磨损机制进行了探讨。结果表明,镀层中硬度随Al2O3含量增加呈线性增长,且含大颗粒Al2O3镀层的硬度略高于小颗粒镀层,Al2O3颗粒含量和粒径大小对磨损率和磨损机制有显著影响。 相似文献
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通过热力学计算,选择Ni_2O_3粉末作原材料,采用反应挤压铸造方法实现了Al与Ni2O3直接压铸反应合成Al3Ni-Al2O3-Al原位复合材料。研究了压铸工艺参数和预制块中纯Al粉的含量对反应合成复合材料过程的影响,并对反应机理做了较深入的分析。结果表明,Ni2O3与Al的反应是为高放热反应,反应是爆发式的,通过调整预制块中Al粉的体积分数控制了反应的剧烈程度,并能获得不同组成和基体含量的复合材料。对反应机理的分析表明,在Al足量的情况下,Ni2O3与Al反应合成复合材料分为两个过程,一是反应过程,即Ni2O3+Al→Al2O3+[Ni];二是凝固过程,即反应后多余的Al与反应生成的[Ni]在随后冷却中的凝固过程,最终形成Al3Ni+α-Al2O3+Al复合材料。 相似文献
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ZnO-MgO-Al2O3陶瓷是一种复合烧结体,其主晶相为ZnO与ZnAl2O4,且均以晶粒存在。MgO能调节电阻温度系数,使之由负变为正。Al2O3能调节电阻率。慢的降温速度能提高线性及耐浪涌能量,降低电阻温度系数。 相似文献
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本文主要介绍了Ni-Al/Al2O3、Ti-Al/Al2O3和Fe-Al/Al2O3三种复合材料的最新研究进展情况,对它们的最新研究动态进行了综述。着重介绍了Fe-Al/Al2O3的研究进展,并认为Fe-Al/Al2O3是一种应用前景非常广阔的新型材料,添加合金元素是进一步提高其性能的重要途径。 相似文献
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利用高分辩透射电子显微镜研究挤压铸造法制备的亚微米 Al 2O 3颗粒增强 Al 基复合材料的界面微观结构。结果表明 : Al基体的 (200) 和 (111) 面优先沿 Al 2O 3颗粒表面生长 , 在复合材料界面处 Al 基体与 Al 2O 3颗粒具有 Al (200) ∥Al 2O 3 (101 2) 、Al [011 ] ∥Al 2O 3 [0221 ] 的晶体学位向关系并形成半共格界面 , 且界面存在 Al (111) / / Al 2O 3 ( 1120) 的共格关系。界面干净无任何反应物。接近界面的 Al 基体中出现了柏氏矢量为 b= 1/ 3 [ 111 ] 弗兰克不全刃位错 , 该刃位错引起界面附近基体中明显的晶格应变场 , 位错周围晶格变形场的范围约为 20~30 层原子面宽度 , 而在 Al 2O 3颗粒靠近界面的区域中未观察到位错等缺陷。并从晶体学角度对界面的形成机制进行了分析。 相似文献
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采用一种具有芯-壳结构的复合纳米纤维增强铝合金复合材料,可以在提高抗拉强度的同时增加塑性。通过真空热压烧结技术制备了Al2O3@Y3Al5O12复合纳米短纤维增强2024铝合金复合材料。研究了纤维添加质量分数对复合材料致密度、硬度、抗拉强度及延伸率的影响;并探究了芯-壳结构在复合材料增韧中的作用。结果表明:Al2O3@Y3Al5O12纳米短纤维具有良好的分散性,在超声分散及机械搅拌混粉后均匀吸附在铝合金颗粒表面,无分层及团聚现象;经热压烧结后,Al2O3@Y3Al5O12纳米短纤维以短纤维形态均匀分散在铝合金基体内,少量添加Al2O3@Y3Al5O12纳米短纤维起到了桥联和孔洞填充作用,使复合材料致密度和硬度提高;添加质量分数为1wt%时,抗拉强度和延伸率取得最大值,由铝合金的249.3 MPa、2.9%增加到299.1 MPa、4.3%。Al2O3@Y3Al5O12纳米短纤维的添加可以细化晶粒,阻碍裂纹扩展,且在拔出/断过程中Al2O3@Y3Al5O12纳米短纤维芯-壳结构的塑性变形起到了增强增韧作用。 相似文献
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The microstructural characteristic of 1070Al matrix composites reinforced by 0.15 μm Al2O3 particles whose volume fraction was 40% was investigated by TEM and HREM. The results showed that the interface between the matrix and reinforcements was clean and bonded well, without any interfacial reaction products. There were some preferential crystallographic orientation relationships between Al matrix and Al2O3 particle because of the lattice imperfection on the surface of Al2O3 particles. 相似文献
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The microstructural characteristic of 1070Al matrix composites reinforced by 0.15μm Al2O3 particles whose volume fraction was 40% was investigated by TEM and HREM.The results showed that the interface between the matrix and reinforcements was clean and bonded well,without any interfacial reaction products.There were some preferential crystallographic orientation relationships between Al matrix and Al2O3 particle because of the lattice imperfection on the surface of Al2O3 particles. 相似文献
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The interaction between Zn-Al eutectic alloy and Al2O3p/6061Al composites in the vacuum furnace was investigated. Great attention has been paid to the elements diffusion, the microstructure and formation of the interface between Zn-Al eutectic alloy and Al2O3p/6061Al composites. Experimental results show that Zn-Al eutectic alloy has a good wetting ability to Al2O3p/6061 Al composites and the wetting angle decreases with increasing the temperature in vacuum. After the interaction,an interaction layer forms between Zn-Al alloy and Al2Oap/6061 Al composites. The phases in the interaction layer mainly consist of α-Al(Zn), Al2O3 and CuZns resulted from the diffusion of elements from the Zn-Al alloy. Several porosities distribute in the region near the interface of the Zn-Al alloy/interaction layer. The amount of shrinkage voids in the interacting layer is relevant to the penetration of Zn element into Al2O3p/6061Al composites which is a function of temperature. So it is necessary to lower heating temperature in order to limit the Zn penetration. 相似文献
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Jiuchun YAN Zhiwu XU Shixiong LU Shiqin YANGState Key Laboratory of Advanced Welding Production Technology Harbin Institute of Technology Harbin China 《材料科学技术学报》2004,20(4):401-404
The interaction between Zn-AI eutectic alloy and Al203p/6061AI composites in the vacuum furnace was investigated. Great attention has been paid to the elements diffusion, the microstructure and formation of the interface between Zn-AI eutectic alloy and Al2O3p/6061AI composites. Experimental results show that Zn-AI eutectic alloy has a good wetting ability to Al2O3p/6061 Al composites and the wetting angle decreases with increasing the temperature in vacuum. After the interaction, an interaction layer forms between Zn-AI alloy and Al2O3p/6061 Al composites. The phases in the interaction layer mainly consist of α-AI(Zn), Al2O3 and CuZn5 resulted from the diffusion of elements from the Zn-AI alloy. Several porosities distribute in the region near the interface of the Zn-AI alloy/interaction layer. The amount of shrinkage voids in the interacting layer is relevant to the penetration of Zn element into Al2O3p/6061Al composites which is a function of temperature. So it is necessary to lower heating temperat 相似文献
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以γ-AlOOH和TiO_2为原料,添加不同质量分数SiC晶须(SiCw),采用无压反应烧结法制备多孔(Al_6Si_2O_(13)+TiC)/Al_2TiO_5复合材料,分析了SiCw质量分数对(Al_6Si_2O_(13)+TiC)/Al_2TiO_5复合材料孔隙率和抗压强度的影响,讨论了SiCw的强化机制。结果表明:不添加SiCw时,产物主要为Al_2TiO_5和少量Al_2O_3,还有少量未反应的TiO_2;加入SiCw之后,还形成了Al_6Si_2O_(13)和TiC相,TiC和Al_6Si_2O_(13)分别以规则颗粒状和晶须形态存在于Al_2TiO_5基体中。TiC颗粒与Al_6Si_2O_(13)晶须通过细化显微组织、裂纹偏转和晶须桥连机制,起到协同强化作用。SiCw的添加使孔隙率和抗压强度同时大幅度提高,随着SiCw质量分数的增加,(Al_6Si_2O_(13)+TiC)/Al_2TiO_5复合材料孔隙率降低,抗压强度提高的速率减小,当SiCw的质量分数为7.2%时,抗压强度最高,达到301.81 MPa。 相似文献
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回顾了国内外在定向金属氧化法制备Al/Al2O3陶瓷基复合材料方面的研究成果,详细讨论了合金成分、外敷剂、温度和气氛以及预形体对其反应机理和显微结构的影响,指出了今后定向金属氧化法制备Al/Al2O3陶瓷材料的研究重点和发展方向. 相似文献
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Jianguo YANG Hongyuan FANG Xin WANState Key Laboratory of Advanced Welding Production Technology Harbin Institute of Technology Harbin China 《材料科学技术学报》2005,21(5):782-784
1.IntroductionTo improve the mechanical properties and relieve mis-matches between the filler metals and base materials,the particulates of superalloys,ceramic or carbon fiberswere added into the conventional brazing filler metal toform composite filler material.The method has beenused in aero-engine component repairing[1,2],fine castcomponent joining[3],wide clearance butt jointing[4],ce-ramic brazing[5,6]and electronic package[7].However,the method was used mostly in metal brazing.The mi-cro… 相似文献