Erosion–corrosion assessment of materials for use in the resources industry

The erosion–corrosion properties of a range of ferrous-based materials that are currently being used or have potential for use in the resources industry have been assessed using a slurry pot erosion–corrosion (SPEC) test rig that has the capability of establishing the separate components of erosion, corrosion and synergy.Testing was performed, at 30 °C, in an aqueous slurry containing 35 wt% AFS 50–70 silica sand and a 3.5 wt% NaCl solution. Erosive action was supplied through high-speed rotation of a rubber-lined impeller.Erosion–corrosion performance of materials evaluated was related to composition/microstructure and hardness. Test data correlated with available service experience.The results showed that the cast Cr white irons with (i) a structure that was essentially a duplex stainless steel containing a distribution of hard carbides and (ii) a near eutectic Cr white iron exhibited the highest erosion–corrosion resistance of the materials tested. The evaluation of the Cr white irons also highlighted the influence of Cr and C levels on the E–C properties of these materials.E–C assessment of selected carbon steels confirmed that the erosion-only rates and synergistic levels showed a general decline with increasing carbon content and hardness. As expected, a low C steel pipe product displayed very mediocre erosion–corrosion behaviour as a consequence of its very low intrinsic corrosion resistance and inferior wear properties. This reflected service experience, however, such products are still being used, due to the comparatively low initial cost.A TiC particle-reinforced AISI 316 stainless steel exhibited an almost 45% improvement in the E–C resistance, when compared with an AISI 316L stainless steel.     

Erosion, corrosion and erosion–corrosion of EB PVD thermal barrier coatings

Electron beam (EB) physical vapour deposited (PVD) thermal barrier coatings (TBCs) have been used in gas turbine engines for a number of years. The primary mode of failure is attributed to oxidation of the bond coat and growth of the thermally grown oxide (TGO), the alumina scale that forms on the bond coat and to which the ceramic top coat adheres. Once the TGO reaches a critical thickness, the TBC tends to spall and expose the underlying substrate to the hot gases. Erosion is commonly accepted as a secondary failure mechanism, which thins the TBC thus reducing its insulation capability and increasing the TGO growth rate. In severe conditions, erosion can completely remove the TBC over time, again resulting in the exposure of the substrate, typically Ni-based superalloys. Since engine efficiency is related to turbine entry temperature (TET), there is a constant driving force to increase this temperature. With this drive for higher TETs comes corrosion problems for the yttria stabilised zirconia (YSZ) ceramic topcoat. YSZ is susceptible to attack from molten calcium–magnesium–alumina–silicates (CMAS) which degrades the YSZ both chemically and micro-structurally. CMAS has a melting point of around 1240 °C and since it is common in atmospheric dust it is easily deposited onto gas turbine blades. If the CMAS then melts and penetrates into the ceramic, the life of the TBC can be significantly reduced. This paper discusses the various failure mechanisms associated with the erosion, corrosion and erosion–corrosion of EB PVD TBCs. The concept of a dimensionless ratio D/d, where D is the contact footprint diameter and d is the column diameter, as a means of determining the erosion mechanism is introduced and discussed for EB PVD TBCs.     

Erosion–corrosion performance of high-Cr cast iron alloys in flowing liquid–solid slurries

In many slurry transportation systems, such as in FGD (Flue Gas Desulphurization) and chemical processing applications, corrosion and erosion are the two main mechanisms of material degradation of the pump wet-end components including pump casing, impeller and liners. The performance of a selected material is mostly dependent upon its relative corrosion and erosion resistance to the service environment. In these cases erosion, corrosion and the related synergistic effects can be very complicated since they are affected by numerous factors including solid and slurry properties, chemical contents, hydraulic conditions and temperatures. In this experimental study, sliding Coriolis erosion testing has been performed with various corrosion factors such as pH value, chlorides content and temperature to evaluate the erosion–corrosion resistance of some high-alloyed white cast irons containing different levels of chromium and other elements. Optical microscope and SEM-EDS have also been used to examine microstructure and surface conditions of tested materials. Results indicated that material loss due to corrosion factors increased as acidity-chlorides and temperature increased. At relatively high corrosion intensity, the white cast irons with higher alloy content (especially chromium) clearly showed improved corrosion resistance and combined erosion–corrosion resistance over those with lower alloy content. Under certain corrosion and hydraulic conditions, particle size is perhaps the single most influential factor on erosion–corrosion rate of the high-Cr cast iron alloys. Relatively large particles are much more effective than small ones at removing both the corroded surface layer and the fresh material, causing substantially higher rate of material loss. Some other related factors have also been addressed.     

The cavitation behavior of a metastable Cr–Mn–Ni Steel

The cavitation behavior of metastable Cr–Mn–Ni steel was investigated in a rotating disk machine. The microstructure of the cavitated area was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical microscopy. The results of XRD showed that the γ→ phase transformation and ηNi₃Ti precipitation had occurred during cavitation testing. Cavitation damage of the material occurred by combined thermal–mechanical fatigue failure. It was deduced that the high-temperature behavior and properties should be taken into account in evaluating the cavitation resistance of such materials.     

Fretting damage assessment of titanium alloys using orientation imaging microscopy

The formation of fretting damage and cracks depends strongly on the microstructure. Recent advances in orientation imaging microscopy (OIM) make it possible to obtain new assessment measurements of the near-surface layers containing fretting damage. In particular, crystallographic grain orientation, misorientations between grains, accumulation of plastic deformation, and the evolution of microstructure leading to microtexture formation and twinning can be determined using OIM. Insight into the hexagonal close packed (HCP) structured metals and alloys is the focus of this study. The examination of the subsurface layers of Ti–6Al–4 V samples reveals that OIM using electron backscatter diffraction (EBSD) is a useful tool to quantify evolution of strain-induced microstructural changes due to deformation in the near-surface layers both in surface treatment processes and in fretting or sliding conditions. Fretting damage in a commercially pure titanium (CP Ti) and a near α Ti–5Al–2.5Sn is also assessed to further evaluate this new characterization method. This study summarizes what can be gained from OIM and the challenges associated with using the technique to characterize near surface microstructures.     

Effect of surface treatments on fretting fatigue damage of biomedical titanium alloys

Fretting fatigue is an adhesive wear damage caused by tangential micromotion under normal force at contact areas. It is observed along the contact points of hip implants and bone plates. Surface-modified biomedical titanium alloys offer better resistance against fretting damage. PVD TiN coatings and plasma nitriding have proved effective in minimizing friction and delaying the failure of materials. In the present study, attempt has been made to explain the fretting fatigue failure mechanism sequence of PVD TiN-coated and plasma-nitrided Ti–6Al–4V and Ti–6Al–4V couple through friction measurement and microscopic examination.     

Erosion–corrosion and corrosion properties of DLC coated low temperature gas-nitrided austenitic stainless steel

Low temperature nitriding of stainless steel leads to the formation of a surface zone of so-called expanded austenite, i.e. by dissolution of large amounts of nitrogen in solid solution. In the present work the possibility of using nitrogen expanded austenite “layers” obtained by gaseous nitriding of AISI 316 as substrate for DLC coatings are investigated. Corrosion and erosion–corrosion measurements were carried out on low temperature nitrided stainless steel AISI 316 and on low temperature nitrided stainless steel AISI 316 with a top layer of DLC. The combination of DLC and low temperature nitriding dramatically reduces the amount of erosion–corrosion of stainless steel under impingement of particles in a corrosive medium.     

Fretting wear behavior of nitrogen ion implanted titanium alloys in bovine serum lubrication

Nitrogen ion implantation was performed on biomedical titanium alloys by using of the PBII technology to improve the surface mechanical properties for the application of artificial joints. The titanium nitride phase was characterized with X-ray photoelectron spectroscopy (XPS). The nanohardness of the titanium alloys and implanted samples were measured by using of in-situ nano-mechanical testing system (TriboIndenter). Then, the fretting wear of nitrogen ion implanted titanium alloys was done on the universal multifunctional tester (UMT) with ball-on-flat fretting style in bovine serum lubrication. The fretting wear mechanism was investigated with scanning electron microscopy (SEM) and 3D surface profiler. The XPS analysis results indicate that nitrogen diffuses into the titanium alloy and forms a hard TiN layer on the Ti6Al4V alloys. The nanohardness increases from 6.40 to 7.7 GPa at the normal load of 2 mN, which reveals that nitrogen ion implantation is an effective way to enhance the surface hardness of Ti6Al4V. The coefficients of friction for Ti6Al4V alloy in bovine serum are obviously lower than that in dry friction, but the coefficients of friction for nitrogen ion implanted Ti6Al4V alloy in bovine serum are higher than that in dry friction. Fatigue wear controls the fretting failure mechanism of nitrogen ion implanted Ti6Al4V alloy fretting in bovine serum. The testing results in this paper prove that nitrogen ion implantation can effectively increase the fretting wear resistance for Ti6Al4V alloy in dry friction, and has a considerable improvement for Ti6Al4V alloy in bovine serum lubrication.     

Erosive wear of hardfaced Fe–Cr–C alloys at elevated temperature

Many engineering components are subjected to erosive wear at elevated temperature. As erosive wear at elevated temperature is governed by the synergistic effect of erosive wear and oxidation, it is possible to modify surfaces of the components in order to achieve improved performances. In view of the above, two different types of hardfacing alloys of Fe–Cr–C were designed incorporating Nb, Mo and B to ensure improved performances at elevated temperature. In order to achieve the above objective, mild steel was hardfaced with these alloys under optimised gas metal arc welding (GMAW) condition. The microstructures of the hardfaced coating was characterised with the help of optical microscopy (OM) and scanning electron microscopy (SEM). The mechanical properties of these coatings were obtained by means of micro indenter. Erosive wear of these coatings was evaluated for four different temperatures, for two different impact angles and at one impact velocity. The morphologies and the transverse sections of the worn surfaces are examined with SEM. The erosive wear of these coatings were compared with conventional M2 tool steel. Results indicate that erosion rate of these coatings increases with increase of test temperature and impact angles. Among various coatings, Fe–Cr–C coating containing higher amount of Nb, Mo and B exhibits best erosion resistance particularly at elevated temperature.     

Influence of thermal conductivity on wear when machining titanium alloys

We study failure of coated carbide tools due to thermal loading. The study emphasizes the role of thermo-physical properties of the tool material in enhancing wear resistance of the tool. We show that heat conduction in the tool active zone is a function of the so called thermodynamic forces. Due to coupling between thermal and mechanical states within the active volume of the tool material, three distinct thermal zones evolve. The first, which is located on the rake face close to the primary shear zone, exhibits a severe drop in its ability of thermal conduction. The second zone, located at the tool tip is characterized by a predominant thermo mechanically induced conduction anisotropy. The anisotropic behaviour, forces heat to partially flow toward the thermally dead zone whence contributing to the intense thermal energy accumulation within the affected material volume. The third zone is one where the thermally triggered degradation of conduction takes place. Heat flow, in light of the existence of these zones, evolves such that, the tip of the tool will be almost thermally congested. The congestion is thought to be the mechanism that renders the energy needed to activate wear mechanisms available.     

Erosion–corrosion degradation mechanisms of Fe–Cr–C and WC–Fe–Cr–C PTA overlays in concentrated slurries

In this investigation the microstructure and erosion–corrosion behaviour of a Fe–Cr–C overlay (FeCrC–matrix) produced by plasma transferred arc welding (PTA) and its metal matrix composite (FeCrC–MMC) were assessed. The FeCrC–MMC was obtained by the addition of 65 wt.% of tungsten carbide (WC). The erosion–corrosion tests (ECTs) were carried out using a submerged impinging jet (SIJ); after the ECTs the surface of the overlays was analysed to identify the damage mechanisms. Two different temperatures (20 and 65 °C) and sand concentrations (10 and 50 g/l) were used in a solution of 1000 ppm of Cl⁻ and a pH value of 8.5; the conditions were chosen to be representative of the recycling water in the tailings line in the oilsands industry. The FeCrC–matrix showed a dendritic structure and a high concentration of carbides in the interdendritic zone. The addition of the WC reinforcing phase promoted the formation of W-rich intermetallic phases, increased the microhardness values of the matrix phase of the FeCrC–MMC overlay and dramatically improved its erosion–corrosion performance as expected. For the FeCrC–matrix overlay the main erosion–corrosion degradation mechanisms were severe plastic deformation and the formation and removal of material flakes due to consecutive impacts. At 65 °C the dendritic zone was severely corroded in the area of low impact frequency. The FeCrC–MMC showed greater attack of the matrix phase compared to the WC grains; at high sand concentration the WC grains were severely fractured and flattened. The anodic polarisation analysis showed active corrosion behaviour of the FeCrC–MMC at both temperatures and sand concentrations; however the temperature dramatically increased the corrosion process of the surface studied under erosion–corrosion conditions. The paper assesses the degradation mechanisms of both FeCrC–matrix and FeCrC–MMC with the aim of understanding what aspects of MMCs must be adapted for optimum erosion–corrosion resistance.     

New Sulzer 16zav40s 柴油机缸套穴蚀原因分析和克服方法

本文论述了柴油机缸套穴蚀的原因、提高抗穴蚀能力的办法，并对已经出现穴蚀的缸套提供修补的办法。     

Relationship between the effects of velocity and alloy corrosion resistance in erosion-corrosion environments at elevated temperatures

Erosion-corrosion by either solid particle or liquid impact occurs in a wide variety of industrial environments which range from coal conversion processes to steam turbines in nuclear power generation. The effects of erosion-corrosion depend on properties of the particle, the target and the nature of the corrosion environment. Various regimes of erosion-corrosion interaction have been identified, ranging from “erosion-dominated” (erosion of the substrate) to “corrosion-dominated” (erosion of the corrosion product).

In studies of erosion-corrosion, the effects of impact velocity are generally not well understood. In some environments in which corrosion occurs, high velocity exponents have been reported, while, in others, the values are close to 1. In addition, the effects of alloy corrosion resistance in environments of different velocities have been puzzling with differences in the exponents reported, as alloy corrosion resistance is increased.

This paper considers the effect of velocity for various erosion-corrosion studies from the literature. The effects of alloy corrosion resistance for such results are evaluated. Some general provisos for the interpretation of the effects of velocity will be made for alloys of different corrosion resistance in erosion-corrosion environments. It is shown that relative erosion-corrosion resistance of alloys in one environment cannot be used arbitrarily to predict resistance in other environments, particularly if parameters such as velocity are varied significantly.     

阻尼合金及应用

对几种典型阻尼合金的成分和特点作了透彻分析，并就阻尼合金的应用作了详细介绍。同时展望了阻尼合金今后的发展及应用前景。     

The improvement of wettability,biotribological behavior and corrosion resistance of titanium alloy pretreated by thermal oxidation

The thermal oxidation process was performed on biomedical titanium alloys to improve surface properties for the application in artificial cervical disc. The pretreated Ti6Al4V was characterized with XPS, XRD and SEM. The wettability, biotribological behavior and corrosion resistance were evaluated under distilled water and 25 wt% bovine serum lubricant. Rutile TiO₂ as the main compound was formed with the increase in hardness. The wettability was improved significantly after oxidation. Compared with the untreated, the friction coefficients and wear volumes of treated samples all decreased with about 50% reduction in both dry sliding and lubrication conditions. Corrosion resistance for oxidized samples was also enhanced with a big reduction of corrosion current density and a shift in corrosion potential towards the positive direction.     

Vibration cavitation behaviour of selected Ni-Mn-Ga alloys

Vibration cavitation erosion tests were carried out on Ni-Mn-Ga alloys of three different crystal structures: (1) the cubic austenite, (2) the non-modulated tetragonal martensite (T) and (3) the five-layered martensite (5M). All Ni-Mn-Ga alloys exhibited cavitation behaviour characterized by a step-wise curve of mass loss versus test time. This behaviour is correlated to the microstructural nature of the alloys as well as the surface conditions of the pre-test samples. The type and concentration of the defects at the surfaces were critical to the cavitation resistance of the alloys. The best cavitation resistant alloy was of a cubic austenitic structure, followed with the alloy of a tetragonal T-martensite. The largest material loss was found in the alloy with a 5M martensite. All the studied Ni-Mn-Ga alloys had an excellent cavitation resistance compared to that of the reference stainless steel, and they even excelled some NiTi alloys found in literature. This may be due to the superelasticity of the cubic austenite and the twinning of the martensitic phases.     

Large deformation compression–torsion behaviour of a titanium alloy and its modelling

A range of sequential and compound compression-torsion tests has been carried out on titanium alloy IMI834 at 1000°C and nominal true strain rate 5 × 10⁻³ s⁻¹, typical of forging conditions. The tests were used to investigate initial and subsequent yield and flow behaviour, the nature of the material hardening and the effect of flow softening on subsequent deformation. In addition, a material model with isotropic or directional hardening has been used to predict the material behaviour.The results show that the material behaviour at large strains is reasonably isotropic, although a directional hardening model provides slightly better quantitative agreement with the experimental results. Large pre-strains (0.4), either axial or torsional, are found not to change significantly subsequent material behaviour. A stress state dependence of flow softening is observed to exist.The material model presented is shown to give good quantitative agreement of predicted and experimental results.     

Reliability of reconstructed beta-orientation maps in titanium alloys

This paper demonstrates that parent beta-orientation maps of titanium alloys can reliably be reconstructed from inherited alpha maps in most cases. Important aspects of the calculation that ensure an accurate determination of the parent orientation as well as a reliable restitution of the beta boundaries are discussed. The limits of the reconstruction method, according to the inherited alpha microstructure are also pointed out. Finally, the method is applied to a beta metastable titanium alloy, which contained enough retained beta phase so that its orientation could be measured by EBSD. The comparison between the measured and the reconstructed beta maps shows the efficiency of the method.     

In situ triboreduction of organo-copper compound in titanium alloys tapping

In this paper, an organo-copper phosphate compound was synthesized and applied as a water-based lubricating additive in a tapping test of Ti–6Al–4V alloys. The results show that the Cu-containing compound plays an effective role in the metalworking. The machined surfaces were examined by scanning electronic microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), respectively. After Ar⁺ etching, abundant metallic Cu was detected in the subsurface. This indicated that Cu(II) was reduced to Cu(0) via in situ triboreduction in the frictional process.     

泵空化现象的研究综述

介绍了空化现象发生的主要原因以及空化与空蚀对泵水力机械性能的影响,分析了影响泵空化性能的因素,阐述了对泵的空化现象的研究方法与空化监测,最后从4个方面介绍了为防止泵发生空化现象而相应采取的措施。