基于小波神经网络预测单个碳纳米管的场增强因子和开启电压

针对单个碳纳米管的场发射特性参数与几何结构之间的复杂非线性关系,构造了一种多输入多输出的小波神经网络结构来预测单个碳纳米管的场发射增强因子和开启电压,并采用BP算法和自适应的学习速率加快网络训练的收敛速度.网络的训练结果和测试结果表明,预测输出值与实验值之间的误差在2.36%以内,充分说明小波神经网络可以较好地预测碳纳米管的场发射特性.     

碳纳米管阵列密度对其场发射性能的影响

本具体研究了外电场，碳纳米管自身线度，尤其管的阵列密度对其场发射性能的影响，在均匀碳纳米管阵列模型下，从理论上给出碳纳米管阵列的尖端电场，电场增强因子以及最佳阵列密度的解析表示式，理论结果表明，电场增强因子的数量级为10^2－10^4，并且碳纳米管阵列的电场增强因子与其管密度之间有着敏感的依赖关系，即当密度取某一特殊值（又被称作最佳密度值）时，电场增强因子会明显增大，相对最佳密度而言，过高或过低的管密度都将削弱碳纳米管的尖端电场，进而晚管阵列的场发射性能。     

铝基定向碳纳米管复合膜的场发射性能研究

研究了铝基定向碳纳米管复合膜的场发射性能,获得了开启场强为1.15V/μm、最大发射电流密度为1.25mA/cm2的铝基定向碳纳米管薄膜.F-N曲线呈线性关系证明电子发射确为场致发射.     

碳纳米管场发射特性的研究

将ＣＶＤ方法制成的碳给米管沉积在钼针尖上，测试了这种材料的场发射特性。结果表明这种材料可作为一种新型高效的场发体。同时还将其与纯钼针在场发射方面进行了比较。     

碳纳米管的薄膜场发射

薄膜场发射特性是碳纳米管(CNT)研究的重要课题之一，它直接关系到CNT场发射阴极在将来的实际应用。本就CNT的场发射做一综合评述，主要涉及性能指标、结构模型、图形化方法和工艺等。     

碳纳米管场发射特性的研究

将CVD方法制成的碳纳米管沉积在钼针尖上 ,测试了这种材料的场发射特性。结果表明这种材料可作为一种新型高效的场发射体。同时还将其与纯钼针在场发射方面进行了比较     

碳纳米管场发射电子源

从实验和理论上研究单根碳纳米管(CNT)场发射电子源的稳定问题.利用透射电镜/扫描探针显微镜(TEM/SPM)和场发射显微镜/场离子显微镜(FEM/FIM)对CNTs的场发射特性进行了实验研究.同时从密度泛函理论出发,利用相关程序模拟计算了吸附对单壁碳纳米管(SWNTs)场发射的影响.发现SWNTs荷电体系的总能量与荷电电荷数量关系具有抛物线形式,先减小,达到最小值,之后增加.通常荷4个电子时达到最小值,即体系处于最稳定状态.表明SWNTs有很大的电负性,是容易发生凝聚和吸附分子的根源.进而计算了对氢、氧和水的吸附特性,讨论了吸附对场发射的影响.这些结果对CNTs的场发射特性和作为新型电子源的应用都是有重要意义的.     

利用场发射显微镜研究单壁碳纳米管的场发射特性

利用场发射显微镜研究了单壁碳纳米管（SWCNTs)的场发射特性。由于实验中所用的SWCNTs的长度基本一致，因此能同时观察到多根SWCNTs的场发射像。SWCNTs的场发射像随着热处理温度的升高而变化，直至热处理温度过高而塌缩。在一定的实验条件下，观察到了具有精细结构的单根碳纳米管顶端“帽子”的场发射像。电流－电压（I－U）曲线分析表明，SWCNTs的电流来源于场发射。     

碳纳米管场发射机理述评

较全面地介绍了碳纳米管场发射研究10年来在发射机理方面的研究结果,包括场发射能量分布、逸出功、发射模型以及发射稳定性和失效等问题,并介绍了相关方面的研究结果.     

碳纳米管复合材料场发射性能研究现状

碳纳米管具有管径小、长径比高的结构以及物理化学性能稳定等优良特性,被认为是真空冷阴极场发射电子源和场发射平板显示理想的阴极材料。加之碳纳米管兼具有机械强度高、韧性好等出众的力学性能,使其成为复合材料的理想添加相,将其与其他材料复合,可以制备出具有更加出众性能的复合材料。近年来有关碳纳米管及其复合材料场发射研究已成为一个备受关注的热点。概述了阴极场发射理论以及与碳纳米管场发射相关的几种场发射物理机制,介绍了碳纳米管复合场发射阴极的研究现状及制备方法,最后对碳纳米管复合阴极场发射的发展前景进行了展望。     

碳纳米管和镓掺杂碳纳米管场发射性能研究

采用催化热解方法分别 制备出碳纳米管和镓掺杂碳纳米管, 并利用丝网印刷工艺将其制备成纳米管薄膜. 对此薄膜进行低场致电子发射测试表明, 碳纳米管和镓掺杂纳米管开启电场分别为2.22和1.0V/μm, 当外加电场为2.4V/μm, 碳纳米管发射电流密度为400μA/cm², 镓掺杂纳米管发射电流密度为4000μA/cm². 可见镓掺杂碳纳米管的场发射性能优于同样条件下未掺杂时的碳纳米管. 对镓掺杂纳米管场发射机理进行了探讨.     

A Field Effect Transistor Fabricated with Metallic Single-Walled Carbon Nanotubes

We report novel transport properties of the individual single-walled carbon nanotube (SWNT) field effect transistors (FETs) decorated with the protein (streptavidin)-coated nanoparticles. Upon adsorption of the protein-coated nanoparticles at the metal-nanotube contact, the metallic SWNT devices abruptly exhibit a p-type semiconducting behavior. In the case of semiconducting SWNT devices, the adsorptions of protein-coated nanoparticles make the gating more effective, resulting in a far suppressed off-state leakage current as well as an enhanced on-state p-channel current. Through the ab initio electronic structure calculations, it is suggested that such an apparent metal-semiconductor transition may be due to the intervening charged species in the contact area, originated from the surface of the proteins. Noting the separation of the semiconducting nanotubes from metallic ones would be a formidable task; we suggest that the device concept here could be another breakthrough for the nanotube-based electronic devices, in which the nanotubes are not necessarily semi-conducting.     

纳米管场发射的电场计算

利用电磁场理论计算出单根纳米管场发射时其尖端附近的电势和电场分布。结果表明 ,纳米管尖端表面电场非常强 ,随着距离尖端表面的距离的增加 ,电场迅速下降 ;尖端附近的场强与纳米管场发射有低的阈值电压相符合。计算还给出在保持极板间距离和电压不变的情况下 ,纳米管长径比越大 ,尖端电场越强 ,因此 ,具有更低的阈值电压     

Electron Field Emission from Multiwall Carbon Nanotubes in Air Gas

Electron field emission (FE) from multiwall carbon nanotubes (CNTs) in air for excitation of atmospheric pressure microplasma was investigated in a scanning electron microscope (SEM). The results showed that, the FE properties of the CNTs in air at 10 kPa and lower pressures were the same as those in vacuum. At pressures more than 10 kPa, the FE threshold voltages in air were higher than those in vacuum and increased with increasing air pressures. When the FE threshold voltages became higher than those of the conventional gas breakdown voltage, microplasma was ignited before FE appearance. FE properties of the CNTs were stable in air before appearing the conventional gas discharges.     

Molecular Imaging with Single-Walled Carbon Nanotubes

Nanoparticle-based molecular imaging has emerged as an interdisciplinary field which involves physics, chemistry, engineering, biology, and medicine. Single-walled carbon nanotubes (SWCNTs) have unique properties which make them suitable for applications in a variety of imaging modalities, such as magnetic resonance, near-infrared fluorescence, Raman spectroscopy, photoacoustic tomography, and radionuclide-based imaging. In this review, we will summarize the current state-of-the-art of SWCNTs in molecular imaging applications. Multifunctionality is the key advantage of nanoparticles over traditional approaches. Targeting ligands, imaging labels, therapeutic drugs, and many other agents can all be integrated into the nanoparticle to allow for targeted molecular imaging and molecular therapy by encompassing many biological and biophysical barriers. A multifunctional, SWCNT-based nanoplatform holds great potential for clinical applications in the future.     

Synthesis, Structure and Field Emission of Carbon Nanotubes

Multiwall and single-wall nanotubes were produced by carbon arc discharge in helium, and their structures were investigated by electron microscopy. Field emission from (1) as-grown multiwall nanotubes (MWNTs), (2) purified MWNTs and (3) purified single-wall nanotubes (SWNTs) was investigated by field emission microscopy. Of the three kinds of nanotubes studied, purified MWNTs whose tips are open provided the highest current at a fixed voltage. Although purified SWNTs provided the second highest current, SWNTs are not so robust as MWNTs against ion bombardment. As an application of nanotube field emitters, we manufactured cathode ray tube (CRT) lighting-elements by replacing conventional thermionic cathodes with nanotube field emitters. Stable electron emission, adequate luminance, and long life of the emitters were substantiated.     

Synthesis,Structure and Field Emission of Carbon Nanotubes

Abstract

Multiwall and single-wall nanotubes were produced by carbon arc discharge in helium, and their structures were investigated by electron microscopy. Field emission from (1) as-grown multiwall nanotubes (MWNTs), (2) purified MWNTs and (3) purified single-wall nanotubes (SWNTs) was investigated by field emission microscopy. Of the three kinds of nanotubes studied, purified MWNTs whose tips are open provided the highest current at a fixed voltage. Although purified SWNTs provided the second highest current, SWNTs are not so robust as MWNTs against ion bombardment. As an application of nanotube field emitters, we manufactured cathode ray tube (CRT) lighting-elements by replacing conventional thermionic cathodes with nanotube field emitters. Stable electron emission, adequate luminance, and long life of the emitters were substantiated.     

定向碳纳米管的制备及其场发射性能研究

定向碳纳米管的制备方法是碳纳米管场发射显示器技术领域一项十分关键的技术.简要介绍了定向碳纳米管的制备方法、结构检测技术,并综合评述了影响定向碳纳米管场发射性能的因素.     

Alignment of Nanoscale Single-Walled Carbon Nanotubes Strands

Nano-Micro Letters - Depositing single-walled carbon nanotubes (SWNTs) with controllable density, pattern and orientation on electrodes presents a challenge in today’s research. Here, we...