Electrically commanded surfaces: A new liquid‐crystal‐display concept

Abstract— Fast in‐plane switching of the optic axis was realized in liquid‐crystal displays (LCDs) based on the concept of Electrically Commanded Surfaces (ECS). According to this concept, the liquid‐crystal layer in such a display is aligned by means of thin ferroelectric liquid‐crystal‐polymer (FLCP) film deposited onto the inner side of the display substrates. An electric field, applied normal to the substrates, switches the molecules of the ferroelectric film, representing the commanded surface that, via elastic forces, further transfers to the liquid‐crystal layer. The concept of electrically commanded surfaces opens the door to a new generation of advanced LCDs exhibiting extraordinary performance such as fast in‐plane switching.     

A submillisecond‐response liquid crystal for color sequential projection displays

We report a new LC with low viscosity and high clearing point (T_c ~102 °C) for color‐sequential projection displays. Using a 1.95‐µm mixed‐mode twisted nematic cell, the averaged gray‐to‐gray response time is less than 1 ms, which is ~3.6× faster than the current state of the art. Such a mixed‐mode twisted nematic liquid‐crystal‐on‐silicon can be used for near‐to‐eye wearable projection displays and head‐up displays in vehicles.     

A novel driving method for field sequential color using an OCB TFT‐LCD

We report a new technique for the design of field‐sequential‐color liquid‐crystal displays (FS‐LCDs), which maximizes the liquid‐crystal response,t_LC, by dividing the display area into as few sub‐areas,N, as possible. We obtained the following results: (1) ^tLC increased as N increased, although saturation tended to occur. Increasing N from 1 to 2 gave the largest increase in ^tLC. (2) ^tLC was maximized by dividing the display area unequally.     

Azo‐dye aligning layers for liquid‐crystal cells

Abstract— The photo‐induced alignment of liquid crystal onto a photochemical stable azo‐dye film was studied for liquid‐crystal display (LCD) applications. The photo‐aligning of azo dye takes place due to the pure reorientation of the molecular absorption oscillators perpendicular to the UV‐light polarization. The order parameters S = ?0.4 (80% of the maximum absolute value S_m = ?0.5) was measured at a wavelength of 372 nm from the polarized absorption spectra. The temperature‐stable pretilt angle of 5.3° was obtained by a two‐step exposure of azo‐dye film using normally incident polarized light followed by oblique non‐polarized light. The azimuthal anchoring energy of the photo‐aligned substrate was A_? > 10^?4 J/m², which is of the same magnitude as the anchoring of the rubbed PI layer. The VHR value of the photo‐aligned LC cell was also found to be very high (98–99%) at room temperature and more than 95% at T=80°C. The thermal stability of the photo‐aligned azo‐dye layers is sufficiently high, while UV stability has to be improved, _e.g., by polymerization. The new LCD aligning technology based on photochemical stable azo‐dye layers is envisaged.     

Liquid‐crystal mixtures having tolane substances for field‐sequential‐color TN‐LCDs

Novel liquid‐crystal (LC) mixtures featuring high optical anisotropy Δn) and small rotational viscosity (γ¹) were developed for field‐sequential‐color TN‐LCD applications. The dynamic behavior of the TN cells in a narrow‐gap range was studied and new tolane LC substances were introduced. The newly developed LC mixtures, having a narrow‐gap cell, enable a TN‐LCD to switch fast enough to be applied to field‐sequential‐color displays not only at a room temperature but also at low temperatures. It was also confirmed that the voltage‐holding ratio (VHR) is sufficiently high in field‐sequential addressing conditions and, therefore, the LC mixtures can be used in active‐matrix LCDs. For practical use, a storage test of the TN cells under light irradiation was performed to evaluate their voltage‐holding property. It was also confirmed that their high VHR can be maintained for over 10,000 hours under practical conditions.     

Highly reliable mobile liquid crystal display using AlOx deposited by atomic layer deposition for side sealing structure

A side sealing structure including, outside a sealant, AlO_x deposited using an atomic layer deposition apparatus was employed for a low‐frequency driving liquid crystal display (LCD) with a bezel width of 0.7 mm. This side‐sealing structure can effectively prevent the entry of external moisture. Prevention of decrease in voltage‐holding ratio was confirmed with a test cell having this structure. A narrow‐bezel LCD with c‐axis‐aligned a‐b‐plane‐anchored crystal In‐Ga‐Zn Oxide backplane can have long‐term high reliability as a low‐frequency driving LCD.     

Multifunctional glassy liquid crystals for photonics

Abstract— As an emerging class of photonic materials, morphologically stable glassy liquid crystals, were developed following a versatile molecular design approach. Glassy cholesteric liquid crystals with elevated phase‐transition temperatures and capability for selective‐wavelength reflection and circular polarization were synthesized via deterministic synthesis strategies. Potential applications of glassy cholesteric liquid crystals include high‐performance polarizers, optical notch filters and reflectors, and circularly polarized photoluminescence. A glassy nematic liquid crystal comprising a dithienylethene core was also synthesized for the demonstration of nondestructive rewritable optical memory and photonic switching in the solid state.     

Novel liquid‐crystal materials for AMLCDs

Abstract— We have developed novel liquid‐crystal (LC) materials with a difluoromethyleneoxy CF₂O) moiety as the linkage group in order to satisfy the various requirements of active‐matrix liquid‐crystal displays (AMLCDs). We measured the physical properties of the CF₂O LC materials. The novel CF₂O LC materials have excellent physical properties, that is, high dielectric anisotropy, low viscosity, a broad nematic range, high reliability, etc. It was revealed that several advantages can be obtained by the introduction of CF₂O moiety into the LC molecules. The mixture containing CF₂O LC materials for various applications indicated a decrease in rotational viscosity of about 15–25% compared with that for conventional LC mixtures. Also, these novel mixtures with CF₂O LCM demonstrated a higher voltage‐holding ratio (VHR). It was confirmed that mixtures containing CF₂O LC materials have suitable characteristics for various applications, for example, low‐driving‐voltage note‐book PCs, quick response monitors, and transflective applications.     

Comparison of organic and inorganic alignment layers for low‐power liquid‐crystal devices using low‐frequency applied‐voltage waveforms

Abstract— Bistable displays are known to have low‐power consumption, but they usually lack the ability to display full‐color video‐rate images. Operating active‐matrix liquid‐crystal displays (AMLCDs) with an ultra‐wide refresh‐rate range, down to ～1 Hz, can lower the power consumption to that of bistable devices and offer video rates as well. A SiO^x‐layer‐based liquid‐crystal (LC) alignment technique is studied here to overcome the ion problems typically encountered with low‐refresh‐rate devices. The effect of ions on the voltage‐holding ratio (VHR) and residual DC voltage (RDC) with SiO^x‐based LC alignment is compared with those for polyimide‐based LC alignment. It is found that only SiO^x alignment provides high VHR and small RDC, with good stability over time. Therefore, it is shown that SiO^x alignment is an excellent candidate for low‐power AMLCDs operated with an ultra‐wide refresh‐rate range.     

LCD applications of thin‐crystal‐film polarizers

Abstract— We have developed a new technique for the production of thin crystal film (TCF) by deposition, molecular alignment, and the drying of water‐based lyotropic‐liquid‐crystal (LLC) materials. TCF exhibits high optical anisotropy and birefringence. This paper presents liquid‐crystal‐display (LCD) applications and opportunities for TCF plastic sheet polarizers, retarders, and color‐correction films as well as LCD designs with TCF internal polarizers.     

Tuning the alignment of liquid crystals by means of nano‐structured surfaces (Invited Paper)

Abstract— The solid‐surface/liquid‐crystal interactions, defining the field‐free alignment of the liquid crystal in conventional liquid‐crystal displays, are playing a vital role in their optical appearance and performance. Nano‐scale changes in the solid‐surface structure induced by light have been recently shown to affect the anchoring strength and the easy‐axis direction. Fine tuning of the anchoring strength is also demonstrated by nano‐structuring of the Langmuir‐Blodgett monolayer employed as liquid‐crystal alignment layers promoting homeotropic orientation. On the basis of nano‐engineering of the surface alignment properties, two novel alignment concepts have been introduced: electrically commanded surfaces (ECS) and high‐performance alignment layers (HiPAL). Nano‐structured polymers related to these concepts have been designed, synthesized, and used as materials for alignment layers in LCDs. ECS materials belong to the category of active alignment materials designed to mediate switching of the liquid crystal, whereas the HiPAL materials make possible the control of the molecular tilt angle in a broad range, from 0° to 90°, and they seem to enable the control of the anchoring strength as well. The nano‐structured alignment materials are strong candidates for implementation in a new generation of advanced liquid‐crystal displays and devices.     

Switchable transmissive and reflective liquid‐crystal display using a multi‐domain vertical alignment

Abstract— A wide‐view transflective liquid‐crystal display (LCD) capable of switching between transmissive and reflective modes in response to different ambient‐light conditions is proposed. This transflective LCD adopts a single‐cell‐gap multi‐domain vertical‐alignment (MVA) cell that exhibits high contrast ratio, wide‐viewing angle, and good light transmittance (T) and reflectance (R). Under proper cell optimization, a good match between the VT and VR curves can also be obtained for single‐gamma‐curve driving.     

Molecular design for stabilizing a blue phase III and electro‐optical switching in the blue phase

Abstract— The molecular design of a liquid crystal to stabilize a blue phase III (BPIII) is reviewed, and the electro‐optical switching with a response time on the order of 10^?2 sec for BPIII exhibited by a novel chiral liquid crystal is reported. Binaphthyl derivatives and T‐shaped compounds are presented, and the structure‐property correlations of the chiral compounds are discussed. Two origins of the twisting power of the compounds, i.e., their inherent molecular chirality and the chirality‐induced twist conformation, play an important role in the appearance of the BPIII. Furthermore, BPIII was also induced in some binary mixtures of a host nematic liquid‐crystal possessing molecular biaxiality and a conventional chiral compound. The electro‐optical switching in the BPIII is attributed to an electric‐field‐induced phase transition between the BPIII and nematic (N) phases. BPIII is on the microscopically twisted nematic order, but is macroscopically isotropic. Therefore, the present technology can offer a pronounced black state in the BPIII without surface treatment and a homogeneous bright state in the induced N phase.     

Electrical models of TFT‐LCD panels for circuit simulations

Abstract— As thin‐film‐transistor liquid‐crystal‐display (TFT‐LCD) panels become larger and provide higher resolution, the propagation delay of the row and column lines, the voltage modulation of Vcom, and the response time of the liquid crystal affect the display images now more than in the past. It is more important to understand the electrical characteristics of TFT‐LCD panels these days. There are several commercial products that simulate the electrical and optical performance of TFT‐LCDs. Most of the simulators are made for panel designers. However, this research is for circuit, system, and panel designers. It is made in a SPICE and Cadence environment as a commercial circuit‐design tool. For circuit and system designers, it will help to design the circuit around a new driving method. Also, it can be easily modified for every situation. It also gives panel designers design concepts. This paper describes the electrical model of a 15‐in. XGA (1024 × 768) TFT‐LCD panel. The parasitic resistance and capacitance of the panel are obtained by 3‐D simulation of a subpixel. The accuracy of these data is verified by the measured values of an actual panel. The developed panel simulation platform, the equivalent circuit of a 1 5‐in. XGA panel, is simulated by HSPICE. The results of simulation are compared with those of experiment, according to changing the width of the OE signal. The proposed simulation platform for modeling TFT‐LCD panels can be especially applied to large‐sized LCD TVs. It can help panel and circuit designers to verify their ideas without making actual panels and circuits.     

New method to improve the dynamic parameters of liquid crystals: Surface wave treatment of the interface between solid phase and mesophase

Abstract— As a new method to enhance the speed of liquid‐crystal‐display elements, the surface electromagnetic‐wave treatment of the conducting layers has been used. The procedure indicated above improves the control of nematic liquid crystals, decreases the number of layers in a sandwiched structure, decreases the magnitude of the supply voltage, and drastically decrease the relaxation time of the mesophase. The re‐orientation of the liquid‐crystal dipoles under field action can be observed with high speed. Thus, a new method of speed enhancement of pure or nano‐objects‐doped nematic liquid crystal has been demonstrated.     

Energy‐efficient liquid‐crystal displays (e2‐LCDs) using a photonic‐crystal backlight system

Abstract— Cholesteric liquid crystals automatically form one‐dimensional photonic crystals. For a photonic crystal in which light‐emitting moieties are embedded, unique properties such as microcavity effects and simultaneous light emission and light reflection can be expected. Three primary‐color photonic‐crystal films were prepared based on cholesteric liquid crystal in which fluorescent dye is incorporated. Microcavity effects, i.e., emission enhancement and spectrum narrowing, were observed. Two types of demonstration liquid‐crystal displays (LCDs) were fabricated using the prepared photonic‐crystal films in a backlight system. One is an area‐color LCD in which a single photonic‐crystal layer is used for each color pixel and the other is a full‐color TFT‐LCD in which three stacked photonic‐crystal layers are used as light‐conversion layers. The area‐color LCD was excited by using 365‐nm UV light, and the full‐color TFT‐LCD was excited by using 470‐nm blue LED light. Because of the photonic crystal's unique features that allow it to work as light‐emitting and light‐reflecting layers simultaneously, both LCDs demonstrate clear readable images even under strong ambient light, such as direct‐sunlight conditions, under which conventional displays including LCDs and OLED displays cannot demonstrate clear images. In particular, an area‐color LCD, which eliminated color filters, gives clear images under bright ambient light conditions even without backlight illumination. This fact suggests that a backlight system using novel photonic‐crystal layers will be suitable for energy‐efficient LCDs (e²‐LCDs), especially for displays designed for outdoor usage.     

Optical properties of composite heterophase objects with liquid crystal material for different display applications

Liquid crystal (LC) director distribution and optical transmission for different types of heterophase systems with different LC boundary conditions is simulated. The first type is a transparent isotropic material with spherical or cylindrical liquid crystalline objects. There are polymer dispersed liquid crystal, LC fiber, lyotropic LC in polarizing films, LC in microgroove and nanogrooves and pores. The second type is an LC layer incorporating an isotropic transparent or non‐transparent object like microparticles and nanoparticles, spacers, protrusions in multi‐domain vertical alignment LC display et al. The system parameters' influence on LC display performances is discussed.     

New approach to developing LC materials for IDS driving on reflective displays

As usage time for portable electronic terminals increases, associated problems regarding such extended use (e.g., battery holding times and eyestrain) are highlighted. Within the domain of power saving, we previously developed an idling stop (IDS) driving that avoids unnecessary refresh. Moreover, for reducing eyestrain to the highest extent possible, we calculated a luminance change in IDS driving that is not perceived as flickering by humans, via the use of a temporal modulation transfer function. According to the results of such calculations, a liquid crystal mixture that suppresses luminance changes perceived by humans was hence constructed. With the combined use of the liquid crystal mixture and a c‐axis‐aligned crystal oxide semiconductor with low off‐state leakage current, a display could be developed wherein leakage current in IDS driving could be significantly reduced, along with enjoyed benefits of prolonged refresh intervals and power savings. The subject display is very eye‐friendly, with less flickering than comparable technologies.     

Analog LCOS SLM devices for AR display applications

Liquid crystal on silicon (LCOS) device is a potential candidate for spatial light modulators (SLMs) due to its high resolution and the wide range of tunable phase retardation. Besides the telecom applications, SLM is also very promising for display applications, especially for the augmented reality (AR) displays. In this paper, we will discuss the advantages of analog LCOS SLM compared with the digital one. A 0.6‐in short‐loop sample test result with precise cell gap controlled is discussed. A fast liquid crystal with high birefringence that attains less than 2.5‐ms full‐on–full‐off response time is also introduced. Regarding the computer‐generated hologram (CGH), a new algorithm called multiconstraints angular spectrum algorithm (MASA) is proposed to enhance the image quality of dual‐plane holographic projection.     

Maximizing electro‐optic performances in the fringe‐field switching liquid crystal mode with negative dielectric anisotropic liquid crystal

The fringe‐field switching (FFS) mode that uses liquid crystals (LCs) with negative dielectric anisotropy is used in high‐resolution FFS liquid crystal display owing to its higher transmittance over positive LC, although its response time becomes slow and operating voltage (V_op) becomes high. In the device, reduction of the cell gap is required to achieve fast response time, which results in increase in V_op in general. In this paper, we propose the FFS mode with electrode width 1 µm and distance between the electrodes 1.5 µm. In such an electrode structure, V_op decreases with decreasing cell gap to 2 µm so that a proper V_op, high LC's light efficiency of 90%, a high color temperature, and a fast response time less than 10 ms, can be achieved, which maximizes electro‐optic performance of the FFS mode.