共查询到18条相似文献,搜索用时 140 毫秒
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为了获取高质量、高取向排列规则的ZnO纳米棒,玻璃衬底预先用脉冲激光沉积方法制备一层ZnO薄膜作为籽晶层,应用水热法在玻璃衬底上生长ZnO纳米棒。探究了籽晶层及不同溶液浓度对ZnO纳米棒结构和发光的影响,用扫描电子显微镜和X射线衍射仪测量样品的形貌和结构,用组建的光致发光测试系统对样品的室温光致发光光谱进行测定。结果表明,ZnO纳米棒具有高度取向且分布致密均匀;光致发光光谱显示ZnO的近带边发射比深能级发光略低;随着溶液浓度的增加,近带边发光和深能级发光相对强度的比值依次降低。 相似文献
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衬底退火温度对ZnO纳米结构形貌和发光特性的影响 总被引:1,自引:1,他引:0
利用热蒸发Zn粉的方法,在Au/掺铝氧化锌(AZO) /石英衬底上生长ZnO纳米结构。为了研究不同 温度退火后的衬底对生长的ZnO纳米结构的影响,Au/AZO/石英衬底在生长纳米结构前分别在 300、500和700℃真空下退火。Au/AZO/石英衬底的表面形貌用原子力显微镜(AFM)观测 。ZnO纳米结构的微结构、形貌和 光学性能分别用X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和荧光光 谱仪进行测量。结果表明,在未退火和300 ℃ 退火衬底上生长了大量的ZnO纳米棒,而在500℃退火衬底上沉积了大量ZnO纳米颗粒。单晶结构 的纳米棒的平均直径分别约50nm,其 生长机制为蒸气-液体-固体(VLS)生长机制。荧光光谱显示所有的样品 都存在紫外发光峰和深能级发射带,随着退火温度的升高,生长的纳米结构的紫外发光峰相 对强度增强,而深能级发射强度减弱。 相似文献
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用退火法在玻璃、硅片衬底上先生长ZnO籽晶,然后在90℃下在醋酸锌和六亚甲基四胺溶液中生长了直径约为17 nm的ZnO纳米棒.采用X射线衍射仪(XRD)分析了不同衬底上生长的ZnO纳米棒的结构和择优生长取向,用扫描电子显微镜(SEM)观察了ZnO的形态,用荧光光谱仪分析了纳米棒的发光特性,讨论了籽晶、衬底类型和衬底放置方式对纳米棒的尺寸、排列趋向性和光学性能的影响.纳米棒的直径和排列依赖于衬底的初始状态,籽晶可以减小纳米棒的尺寸,增强纳米棒的排列有序性;一旦衬底上生长了籽晶,后续生长的纳米棒的尺寸、排列和性能与衬底的类型无关,纳米棒都具有强的紫光发射.但衬底的放置方式会影响其上纳米棒的形态,竖直放置的衬底易生长尺寸分布均匀的准有序排列的纳米棒. 相似文献
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采用溶胶-凝胶法,以六水硝酸锌和乙二醇单甲醚为主要原料,在SiO2玻璃衬底上旋涂一层致密的ZnO籽晶,用水热法,通过对ZnO籽晶层面朝下和朝上分别制备了ZnO纳米棒和微米棒。研究了不同生长液浓度对ZnO纳米/微米棒的形貌和光学性能的影响。结果表明,ZnO纳米棒直径约在Φ(60~90)nm之间,长度约为1 600nm,微米棒直径约Φ(1~4)μm,长度约8~14μm;随着生长液浓度的增加,ZnO纳米棒越致密,而ZnO微米梭生长成ZnO微米棒;ZnO纳米/微米棒的光致发光(PL)光谱强度随着生长液浓度的增加逐渐增强 相似文献
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采用简化的种子层制备工艺在ITO基底上制备了ZnO种子层,并使用化学溶液沉积法制备了高度取向的ZnO纳米棒阵列。采用XRD和SEM对ZnO纳米棒的结构和形貌进行表征,并对样品的光学性能进行了测试。测试结果表明,所制备的ZnO纳米棒为c轴择优取向的六角纤锌矿结构,直径为66~122nm可控,且排列紧密,形貌规整。光学性能测试结果表明,吸收光谱在375nm附近表现出强烈的紫外吸收边是由于禁带边吸收引起的;反射光谱具有一定的周期振荡性,可用于薄膜厚度的估算;光致发光谱在378nm附近有很强的紫外发射峰;增大生长液浓度和高温退火可降低缺陷发光,改善结晶质量。 相似文献
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采用旋涂法在洗净的玻璃衬底上制备了醋酸锌薄膜,并进一步在空气中退火获得了氧化锌(ZnO)薄膜,X射线衍射分析显示退火后获得的ZnO薄膜具有c轴(002)择优取向生长特性.通过水热法以ZnO薄膜为种子层,生长了ZnO纳米杆阵列.研究了在相同的ZnO种子层、前驱液浓度和生长温度条件下,不同生长时间对ZnO纳米杆形貌的影响.扫描电子显微镜照片显示,随着生长时间的增加,ZnO纳米杆阵列的生长具有阶段性规律,并且在经过52h生长后得到了顶端中心被溶解的ZnO纳米管.分析认为该现象和前驱液中Zn2+离子和OH-离子的浓度变化有关,同时也和ZnO的非极性结构有关. 相似文献
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采用改进的水热法对衬底进行预处理,分别在单晶硅Si(111)和蓝宝石C(0001)衬底上生长一层Ga2O3籽晶层.籽晶层退火处理后放入Ga2(NO3)3溶液高压反应釜内进行水热反应,待反应结束进行二次退火,成功制备出了Ga2 O3纳米棒.研究了不同温度对籽晶层和Ga2 O3纳米棒的影响,通过扫描电子显微镜(SEM)和X... 相似文献
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Mohamed AbuDakka Ahsanulhaq Qurashi Parameswar Hari Mir Wakas Alam 《Materials Science in Semiconductor Processing》2010,13(2):115-118
A cost effective, low-temperature approach has been developed for the large-area deposition of ZnO nanorod/nanotube arrays on a ZnO coated glass substrate by the natural oxidation of zinc metal in formamide/water mixtures. The two-step seed deposition and wet-chemical approach exhibited well-controlled growth of highly oriented and densely packed ZnO nanorod/nanotube arrays with large-area homogeneity and uniform morphologies. In order to investigate the quality and alignment of ZnO nanorod arrays grown on the ZnO seed layer coated substrate, three different methods of ZnO coating have been deposited by ultrahigh vacuum evaporation system, DC sputtering and RF sputtering, respectively. Our results showed that the ZnO seed layer grown by RF sputtering resulted in high quality ZnO nanorod arrays. 相似文献
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Jizhong Song Ying He Jie Chen Di Zhu Zhaodong Pan Yaofei Zhang Jun-an Wang 《Journal of Electronic Materials》2012,41(3):431-436
The current study reports a novel inorganic/organic light-emitting diode (LED), consisting of zinc oxide (ZnO) nanorod arrays
and poly(2-methoxy, 5-octoxy)-1,4-phenylenevinylene (MOPPV). ZnO nanorod arrays passivated using polyacrylamide (PAM) with
70 nm diameter were successfully prepared by a simple polymer-assisted chemical method. Enhancement of the ZnO defect emission
is caused by PAM passivation, as observed in photoluminescence spectra. Infrared absorption spectra reveal that PAM is chemically
or physically adsorbed on the surfaces of ZnO nanorod arrays. The electroluminescence (EL) spectrum shows bluish light at
406 nm from ZnO transition emission, and light emission with center at 600 nm from exciton emission in MOPPV. The potential
EL mechanism is electron transition to zinc vacancy in PAM/ZnO nanorod arrays, and exciton radiation luminescence in MOPPV
film. This novel PAM/ZnO-MOPPV device may be helpful to promote development of multicolor LEDs. 相似文献
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Kh. A. Abdullin N. B. Bakranov D. V. Ismailov J. K. Kalkozova S. E. Kumekov L. V. Podrezova G. Cicero 《Semiconductors》2014,48(4):471-475
Composites formed from ZnO nanorods in combination with CuO or Ag nanoparticles are produced by the deposition of CuO or Ag nanoparticles onto ZnO nanorod arrays grown by the hydrothermal technique. The CuO nanoparticles are synthesized by the vacuum thermal deposition of a Cu layer followed by vacuum annealing at a temperature of 350°C for 1 h. CuO particles covered with a layer of nanoneedles are obtained. The current-voltage characteristics of the ZnO/CuO layers are indicative of the formation of a p-n junction. The ZnO/Ag composites are produced by the electrical deposition of Ag nanoparticles synthesized in an aqueous solution of silver nitrate and sodium citrate. The surface morphology and the optical and electrical properties of the samples are studied. 相似文献
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A. A. Bobkov N. A. Lashkova A. I. Maximov V. A. Moshnikov S. S. Nalimova 《Semiconductors》2017,51(1):61-65
The prospects of the fabrication of solar cells based on metal oxides (ZnO formed by the hydrothermal method) with a bulk heterojunction are considered. The results of synthesizing zinc-oxide nanorods on different seed layers are presented. The important role of seed-layer formation is noted. It is shown that the structure of nanorod arrays can be controlled using a surfactant. Faceted nanorods are obtained, which are promising for designing new-generation solar cells. 相似文献
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ZnO纳米棒光阳极的制备及其天然染料敏化研究 总被引:3,自引:3,他引:0
采用溶胶-凝胶法和旋转涂覆法在FTO导电玻璃上制备ZnO种子层,以Zn(NO3)2和六亚甲基四胺(HMT)的混合溶液为生长液在ZnO种子层上制备出ZnO纳米棒薄膜,利用X射线衍射(XRD)、扫描电镜(SEM)对ZnO种子层及纳米棒薄膜的晶相及表面微观形貌进行了表征;研究了生长液浓度、生长时间对ZnO纳米棒薄膜生长的影响。实验表明,制备排列整齐的ZnO纳米棒阵列薄膜最佳条件为90℃环境下,基底竖直放置在0.025mol/L的生长液中,生长4h,纳米棒平均直径80nm左右。从新鲜草莓、桑葚中提取天然色素,对ZnO纳米棒电极进行敏化,组装成光电池;测试敏化电极的吸收光谱及光电池的伏安特性曲线。结果表明,桑葚色素在可见光区有更强的吸收特性,由桑葚色素敏化的电极组装的光电池,在模拟太阳光下,得到开路电压为228.75mV,短路电流为189μA,填充因子为0.37,光电转换效率为5.5×10-4。 相似文献
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Using a low temperature hydrothermal synthesis method,ZnO nanorod networks have been directly grown across trenched Au microelectrodes arrays,which were modified with a layer of ZnO seeds.The characteristics of the current-voltage(I-V) and the photoresponse were obtained both in the dark and under ultraviolet illumination.The bridged nanorod network demonstrated a highly sensitive response to UV illumination in atmosphere at room temperature.It can be useful for nanoscale optoelectronic applications,serving as chemical sensors,biological sensors,and switching devices. 相似文献
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在锌衬底上制备了取向生长、形貌各异、不同密度的氧化锌纳米棒阵列.研究发现,氧化锌纳米棒在温度低于70℃、适量的碱性溶液、大气压下能够在锌衬底上大规模制备,并且氧化锌纳米棒的直径,在锌衬底上的密度和形貌完全依赖于氢氧化钠和硝酸锌的浓度.场发射测试表明:氧化锌纳米棒阵列开启电场较低(电流密度达1μA/cm2时场强仅为3.8 V/μm),显示了氧化锌纳米棒阵列在场发射方面的潜在应用. 相似文献