INVESTIGATION OF NANO-STRUCTURED PVD COATINGS FOR DRY HIGH-SPEED MACHINING

The objective of this paper is to investigate the performance of different categories of hard PVD coatings in terms of friction and tool wear under dry high-speed machining (HSM) conditions. In this study five different categories of commercially available coatings (nano-composite AlTiN/Si₃N₄, nano-crystalline Al₆₇Ti₃₃N and mono-layered Ti₁₀Al₇₀Cr₂₀N) and experimental nano-multilayered coatings (Ti₂₅Al₆₅Cr₁₀N/BCN and Ti₂₅Al₆₅Cr₁₀N/WN) were studied by machining hardened steel AISI H13 (HRC 50). The coefficients of friction against steel versus temperature were measured. Tool wear and cutting forces were measured in-situ under dry high speed machining conditions. The morphology of the worn tools and the chips collected during cutting were studied using an SEM (Scanning Electron Microscopy) and the EDX (Energy Dispersive X-ray analysis). The cutting temperatures were estimated based on the color of the chips generated during cutting. The comparison among these categories of coatings was conducted based on tool wear, coefficient of friction, cutting forces and chip formation. From this study, it was revealed that the solid self-lubricating layers, automatically formed in the cutting zone under elevated temperatures, play a key role in leading to a significant improvement of tool performance under dry high-speed machining.     

Some studies on hard turning of AISI 4340 steel using multilayer coated carbide tool

Hard turning with multilayer coated carbide tool has several benefits over grinding process such as, reduction of processing costs, increased productivities and improved material properties. The objective was to establish a correlation between cutting parameters such as cutting speed, feed rate and depth of cut with machining force, power, specific cutting force, tool wear and surface roughness on work piece. In the present study, performance of multilayer hard coatings (TiC/TiCN/Al₂O₃) on cemented carbide substrate using chemical vapor deposition (CVD) for machining of hardened AISI 4340 steel was evaluated. An attempt has been made to analyze the effects of process parameters on machinability aspects using Taguchi technique. Response surface plots are generated for the study of interaction effects of cutting conditions on machinability factors. The correlations were established by multiple linear regression models. The linear regression models were validated using confirmation tests. The analysis of the result revealed that, the optimal combination of low feed rate and low depth of cut with high cutting speed is beneficial for reducing machining force. Higher values of feed rates are necessary to minimize the specific cutting force. The machining power and cutting tool wear increases almost linearly with increase in cutting speed and feed rate. The combination of low feed rate and high cutting speed is necessary for minimizing the surface roughness. Abrasion was the principle wear mechanism observed at all the cutting conditions.     

Friction and wear behaviors of C/C-SiC composites containing Ti3SiC2

In the present paper, friction and wear behaviors of a carbon fiber reinforced carbon–silicon carbide–titanium silicon carbide (C-SiC–Ti₃SiC₂) hybrid matrix composites fabricated by slurry infiltration and liquid silicon infiltration were studied for potential application as brake materials. The properties were compared with those of C/C-SiC composites. The composites containing Ti₃SiC₂ had not only higher friction stability coefficient but also much higher wear resistance than C/C-SiC composites. At an initial braking speed of 28 m/s under 0.8 MPa pressure, the weight wear rate of the composites containing 5 vol% Ti₃SiC₂ was 5.55 mg/cycle, which was only one-third of C/C-SiC composites. Self-lubricious film-like debris was formed on the composites containing Ti₃SiC₂, leading to the improvement of friction and wear properties. The effect of braking speed and braking pressure on the tribological properties of modified composites were investigated. The average friction coefficient was significantly affected by braking speed and braking pressure, but the wear rate was less affected by braking pressure.     

Ultra‐high frequency tribometer for reciprocating sliding motion

A novel tribometer has been designed using commercially available components for sliding motion at 40kHz with amplitude between 2.5 and 5µm. The tribometer is equipped with means to measure amplitude, frequency, power required to keep the sample in motion and load applied. The effective motion between the two contacting bodies is monitored. These data are used to evaluate the coefficient of friction. The wear rate was determined after the tests. The set‐up was tested using novel, non‐commercial substrates such as AlFeCrTi‐alloys and tungsten carbide‐based coatings as well as Magnéli‐type coatings (Ti_n−2Cr₂O_2n−1 and Ti_nO_2n−1). This paper presents the principle of the ultra‐high frequency tribometer and first tribological quantities of materials and coatings tested. Copyright © 2007 John Wiley & Sons, Ltd.     

Cr2N/CrN multilayer coatings for wood machining tools

The present paper describes results from a recent research project aimed at forming a wear resistant coating based on chromium on tools to wood machining. Cr₂N/CrN multilayer coatings deposited on HS6-5-2 steel substrates using cathodic arc evaporation were tested. These coatings were formed from 7 bilayers being ca. 340 nm thick and equally thick Cr₂N and CrN layers. For comparison, Cr₂N and CrN monolayer coatings were also prepared. Hardness measurements, indentation and scratch tests, friction and wear were performed to characterize the mechanical properties. The wear tracks and Rockwell indentations enable to assess wear mechanisms of the coatings. The results of the Cr₂N/CrN coatings investigated show high hardness: ca. about 22 GPa and a critical force being higher than 95 N and a low wear rate.The industrial tests of planer knives with Cr₂N/CrN multilayer coatings were carried out on a down-spindle milling machine to determine the durability of tools with wear resistant coatings for woodworking. These tools show increase of “life time” two times. Another positive feature of the use of such tools is the increase of the quality of wood surface machined when compared with uncoated tools.     

Architecture of Multilayer Cr/CrN Coatings for Wear Protection in Seawater: Cr/CrN Ratio and Total Thickness

Cr/CrN multilayer coatings with various Cr/CrN thickness ratios and total thicknesses were deposited on 316L stainless steel by multi-arc ion plating. The coatings were systematically characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and nanoindentation. Tribological behaviors were investigated using a ball-on-disk tribometer in artificial seawater. The results showed that the multilayer coating phases changed from Cr₂N + CrN to Cr + Cr₂N + CrN phases with an increase in Cr/CrN thickness ratio. The adhesion showed a slight difference for the coatings with different thickness ratios but significantly increased with total thickness. The hardness was also slightly improved by thickening the coatings. The friction coefficient and wear rate were lowest at a thickness ratio of about 0.3. However, there was no large difference in the friction coefficient between coatings with different thicknesses. The wear rate was lower for the thicker coatings under various loads. The load-bearing capacity was also improved by thickening the coatings.     

Friction and Wear Behavior of WS2/Zr Self-lubricating Soft Coatings in Dry Sliding Against 40Cr-Hardened Steel Balls

WS₂ and WS₂/Zr self-lubricating soft coatings were produced by medium-frequency magnetron sputtering, multi-arc ion plating and ion-beam-assisted deposition technique on the cemented carbide YT15 (WC + 15 % TiC + 6 % Co) substrates. Microstructural and fundamental properties of these coatings were examined. Sliding wear tests against 40Cr-hardened steel using a ball-on-disk tribometer method were carried out with these coated materials. The friction coefficient and wear rates were measured with various applied loads and sliding speeds. The wear surface features of the coatings were examined using SEM. The results showed that the WS-1 specimen (with WS₂/Zr composite coating) has higher hardness and coating/substrate critical load compared with that of the WS-2 specimen (only with WS₂ coating). The friction coefficient of WS-1 specimen increases with the increase in applied load and is quite insensitive to the sliding speed. The wear rate of the WS-1 specimen is almost constant under different applied loads and sliding speeds. The WS-1 specimen shows the smallest friction coefficient and wear rate among all the specimens tested under the same conditions. The WS-1 specimen exhibits improved friction behavior to that of the WS-2 specimen, and the antiwear lifetime of the WS₂ coatings can be prolonged through adding Zr additives. The self-lubricating and wear mechanism of the WS₂/Zr coating was also found from the sliding wear tests.     

WC/DLC/WS2 nanocomposite coatings for aerospace tribology

Tribological properties of three-phase composite coatings consisting of nanocrystalline WC, amorphous diamond-like carbon (DLC), and nanocrystalline WS₂ are evaluated. The WC/DLC/WS₂ coatings have 0.5 μm thickness, 7–8 GPa hardness, excellent wear resistance, and low friction coefficients: 0.03 in vacuum, and 0.15 in air; with unique friction recovery in cycling between dry and moist environments. The benefits of carbide/dichalcogenide/DLC nanocomposites for aerospace tribology are highlighted. This revised version was published online in July 2006 with corrections to the Cover Date.     

Experimental investigations on machinability aspects in finish hard turning of AISI 4340 steel using uncoated and multilayer coated carbide inserts

The present work deals with some machinability studies on flank wear, surface roughness, chip morphology and cutting forces in finish hard turning of AISI 4340 steel using uncoated and multilayer TiN and ZrCN coated carbide inserts at higher cutting speed range. The process has also been justified economically for its effective application in hard turning. Experimental results revealed that multilayer TiN/TiCN/Al₂O₃/TiN coated insert performed better than uncoated and TiN/TiCN/Al₂O₃/ZrCN coated carbide insert being steady growth of flank wear and surface roughness. The tool life for TiN and ZrCN coated carbide inserts was found to be approximately 19 min and 8 min at the extreme cutting conditions tested. Uncoated carbide insert used to cut hardened steel fractured prematurely. Abrasion, chipping and catastrophic failure are the principal wear mechanisms observed during machining. The turning forces (cutting force, thrust force and feed force) are observed to be lower using multilayer coated carbide insert in hard turning compared to uncoated carbide insert. From 1st and 2nd order regression model, 2nd order model explains about 98.3% and 86.3% of the variability of responses (flank wear and surface roughness) in predicting new observations compared to 1st order model and indicates the better fitting of the model with the data for multilayer TiN coated carbide insert. For ZrCN coated carbide insert, 2nd order flank wear model fits well compared to surface roughness model as observed from ANOVA study. The savings in machining costs using multilayer TiN coated insert is 93.4% compared to uncoated carbide and 40% to ZrCN coated carbide inserts respectively in hard machining taking flank wear criteria of 0.3 mm. This shows the economical feasibility of utilizing multilayer TiN coated carbide insert in finish hard turning.     

Reciprocating friction and wear behavior of Ti3AlC2 and Ti3AlC2/Al2O3 composites against AISI52100 bearing steel

In this work, the dry sliding friction and wear properties of Ti₃AlC₂ and Ti₃AlC₂/Al₂O₃ composites against AISI52100 steel ball were investigated using a reciprocating ball on flat configuration under different normal loads. The results indicated that the friction/wear processes of both Ti₃AlC₂ and the composites against AISI52100 steel experienced two different stages with an abrupt transition between them under all test conditions. The first stage was characterized by low coefficient of friction (μ) and neglectable wear rate. While the second stage was of much higher wear rate and μ. When the transition occurred, μ increased dramatically accompanied with formation of a mass of debris. In Ti₃AlC₂, the main wear mechanisms during the first stage involved surface materials transfer and oxidation accompanied with subsurface damages by grains kinking, delamination as well as transgranular and intergranular cracks. Accumulating of such contact damages under repeated sliding contact finally leaded to surface and subsurface microfracture of Ti₃AlC₂. Then microfracture controlled severe wear started. Incorporation of Al₂O₃ in Ti₃AlC₂ not only improved wear resistance of Ti₃AlC₂ but also extended the first mild friction/wear stage, because Al₂O₃ particles borne load and restrained large-scale deformation and microfracture of Ti₃AlC_2.     

Low Friction CrNMPP/TiNDCMS Multilayer Coatings

Transition metal nitrides like CrN and TiN are widely used in automotive applications due to their high hardness and wear resistance. Recently, we showed that a multilayer architecture of CrN and TiN, deposited using the hybrid—high power impulse magnetron sputtering (HIPIMS) and direct current magnetron sputtering (DCMS)—HIPIMS/DCMS deposition technique, results in coatings which indicate not only increased mechanical and tribological properties but also friction coefficients in the range of diamond-like-carbon coatings when tested at RT and ambient air conditions. The modulated pulsed power (MPP) deposition technique was used to replace the HIPIMS powered cathode within this study to allow for a higher deposition rate, which is based on the complex MPP pulse configuration. Our results on MPP/DCMS deposited CrN/TiN multilayer coatings indicate excellent mechanical and tribological properties, comparable to those obtained for HIPIMS/DCMS. Hardness values are around 25 GPa with wear rates in the range of 2 × 10⁻¹⁶ Nm/m³ and a coefficient of friction around 0.05 when preparing a superlattice structure. The low friction values can directly be correlated to the relative humidity in the ambient air during dry sliding testing. A minimum relative humidity of 13% is necessary to guarantee such low friction values, as confirmed by repeated tests, which are even obtained after vacuum annealing to 700 °C. Our results demonstrate that the co-sputtering of high metal ion sputtering techniques and conventional DC sputtering opens a new field of applications for CrN/TiN coatings as high wear resistance and low friction coatings.     

Tribological Properties of TiAl Matrix Self-Lubricating Composites Containing Multilayer Graphene and Ti3SiC2 at High Temperatures

An investigation is conducted on the unexplored synergistic effects of multilayer graphene (MLG) and Ti₃SiC₂ in self-lubricating composites for use in high-temperature friction and wear applications. The tribological properties of TiAl matrix self-lubricating composites with different solid lubricant additions (Ti₃SiC₂-MLG, MLG) are investigated from room temperature to 800°C using a rotating ball-on-disk configuration. Tribological results suggest the evolution of lubrication properties of MLG and the excellent synergistic lubricating effect of MLG and Ti₃SiC₂ as the testing temperature changes. It can be deduced that MLG has great potential applications as a promising high-temperature solid lubricant within 400°C, and a combination of MLG and Ti₃SiC₂ is an effective way to achieve and maintain desired tribological properties over a wide temperature range.     

Friction coefficient and wear rate of sputter-deposited thin films and plasma-sprayed thick coatings at high temperatures in room air

Silver, calcium fluoride (CaF_x with x = 1.85) and chromium-carbon (Cr₃C₂) thin films were deposited onto various tribological test specimens by sputtering. The friction properties of sputter-deposited Ag and CaF_x single layers as well as Ag/CaF_x multilayer films were determined by ball-on-disk tribological tests conducted in room air under various experimental conditions. The tribological properties (friction coefficient and wear rate) of sputter-deposited CaF_x films were also determined at 500°C by pin-on-disk tribological tests performed with pin specimens made of cobalt-based alloy (alacrite). Chromium-carbon films sputter-deposited onto alacrite disk and counterfaces were found to be of interest for reducing the formation of alacrite wear debris in the wear tracks; thus reduced friction coefficient and wear rate values were obtained. The friction behavior of sputter-deposited CaF_x/Cr₃C₂ thin bilayer structures and plasma-sprayed (PS) chromium carbide/Ag/BaF₂-CaF₂ eutectic composite coatings (PS-212 type coatings) was investigated by plane-on-plane tribological tests conducted in room air at 500°C and 700°C. The friction performance of solid lubricant thin bilayer films was compared with that of thick PS-212 type coatings similar to coatings developed by NASA.     

Corrosion-wear behaviour of PVD Cr/CrN multilayer coatings for gear applications

At present, one of the most important problems in automobile engines and transmission components is due to tribological processes (friction and wear) that in many cases come accompanied by corrosion processes due to the environmental conditions to which these materials are exposed during their lifetime. Both mechanisms can be minimized by means of the development and the application of adequate coatings that combine low friction with a high corrosion and wear resistance.The new tendencies in industrial PVD coatings to improve their properties are focused in the development of new multilayer and nanostructured coatings. These structures allow in a relatively simple way enhancing their tribological properties and the corrosion resistance that can not be reached by means of the traditional monolayer coatings. The background of this type of coatings consists of the stacking up of several layers with good individual tribological and mechanical properties, but every individual layer has a thickness that can be from hundreds of nanometres down to only 5-10 nm. The properties of these nanostructured coatings depend strongly on the thickness modulation of every individual layer.Concerning PVD coatings, the chrome nitride coatings have demonstrated to possess excellent wear resistance properties. In this work, multilayer Cr/CrN coatings with different individual layer thickness have been deposited on substrates of steel F1272 and silicon. The deposition has been carried out by means of the cathodic arc method alternating an atmosphere of pure Ar with a reactive mixture of N₂/Ar. The multilayers obtained have been analyzed by means of Glow Discharge Optical Emission Spectroscopy (GD-OES) and in some cases by means of FE-SEM obtaining bilayer (Cr/CrN) periods of the order of 220 and 45 nm. The coating characterization has been complemented with hardness and composition measurements as well as by the performance of several wear and corrosion-wear tests.     

A comparative study on performance of multilayer coated and uncoated carbide inserts when turning AISI D2 steel under dry environment

The present work deals with a comparative study on flank wear, surface roughness, tool life, volume of chip removal and economical feasibility in turning high carbon high chromium AISI D2 steel with multilayer MTCVD coated [TiN/TiCN/Al₂O₃/TiN] and uncoated carbide inserts under dry cutting environment. Higher micro hardness of TiN coated carbide samples (1880 HV) compared to uncoated carbide (1430 HV) is observed and depicts better resistance against abrasion. The low erosion rate was observed in TiN coated insert compared to uncoated carbide. The tool life of TiN coated insert is found to be approximately 30 times higher than the uncoated carbide insert under similar cutting conditions and produced lower surface roughness compared to uncoated carbide insert. The dominant wear mechanism was found to be abrasion and progression of wear was steady using multilayer TiN coated carbide insert. The developed regression model shows high determination coefficient i.e. R² = 0.977 for flank wear and 0.94 for surface roughness and accurately explains the relationship between the responses and the independent variable. The machining cost per part for uncoated carbide insert is found to be 10.5 times higher than the multilayer TiN coated carbide inserts. This indicates 90.5% cost savings using multilayer TiN coated inserts by the adoption of a cutting speed of 200 m/min coupled with a tool feed rate of 0.21 mm/rev and depth of cut of 0.4 mm. Thus, TiN coated carbide tools are capable of reducing machining costs and performs better than uncoated carbide inserts in machining D2 steel.     

Tribological performance of TiN and TiCN coatings on a working tool steel

Although the applications of TiN and TiCN coatings are extensive, their mechanical and tribological properties are influenced by the substrates in which they are deposited. The present work is focused on the tribological performance of TiN and TiCN coatings on a working tool steel. Besides, adhesion and microhardness tests were carried out. The adhesion performance of both coatings resulted in class 1, according to CEN/TS 1071–8 standard, which allows observing the quality of adhesion. The composite microhardness was investigated by the analysis of relative indentation (β). Pin-on-disk tests were performed in dry and lubricated condition at 100 °C against tungsten carbide (WC). Low friction coefficients of μ_k = 0.08 for TiN and μ_k = 0.03 for TiCN were obtained in lubricated conditions. Wear mechanisms were analyzed by scanning electron microscopy (SEM). Abrasive wear was observed as the principal wear mechanism in dry condition, while in lubricated conditions wear signals seem to be scarcely noticeable.     

Tribological Behavior of Electrodeposited Ni-Fe Multilayer Coating

In the present study, the sliding wear behavior of pulse-electrodeposited multilayer Ni-Fe coatings as a function of pulse parameters including frequency and duty cycle has been studied using pin-on-disc tests against an Al₂O₃ counterbody. Sliding wear was investigated with respect to the coefficient of friction (COF), worn surfaces, wear rate, and wear debris. The results of COF with sliding distance revealed a two-region state. At the start of the test the COF was higher, which was due to high stress at the contact region and the occurrence of delamination wear. Then the COF was collapsed as a result of pin penetration and decreased stress at the contact region. The intensity of delamination is decreased at the later stage. The wear resistance of multilayer coatings is increased with increasing frequency and decreasing duty cycles as a consequence of grain refinement and hardness enhancement.     

Boundary lubrication mechanisms of carbon coatings by MoDTC and ZDDP additives

Fuel economy and reduction of harmful elements in lubricants are becoming important issues in the automotive industry. An approach to respond to these requirements is the potential use of low friction coatings in engine components exposed to boundary lubrication conditions. Diamond-like-carbon (DLC) coatings present a wide range of tribological behavior, including friction coefficients in ultra-high vacuum below 0.02. The engine oil environment which provides similar favourable air free conditions might lead to such low friction levels.In this work, the friction and wear properties of DLC coatings in boundary lubrication conditions have been investigated as a function of the hydrogen content in the carbon coating. Their interaction with ZDDP which is the exclusive antiwear agent in most automotive lubrication blends and friction-modifier additive MoDTC has been studied. Hydrogenated DLC coatings can be better lubricated in the presence of the friction-modifier additive MoDTC through the formation of MoS₂ solid lubricant material than can non-hydrogenated DLC. In contrast, the antiwear additive ZDDP does not significantly affect the wear behavior of DLC coatings. The good tribological performances of the DLC coatings suggest that they can contribute to reduce friction and wear in the engine, and so permit the significant decrease of additive concentration.     

Deposition of duplex Al2O3/TiN coatings on aluminum alloys for tribological applications using a combined microplasma oxidation (MPO) and arc ion plating (AIP)

Microplasma oxidation (MPO) has recently been studied as a cost-effective plasma electrolytic process to provide thick and hard ceramic coatings with excellent surface load-bearing capacity on aluminum alloys. However, for sliding wear applications, such ceramic coatings often exhibit relatively high friction coefficients against many counterface materials. Although coatings deposited by physical vapour deposition (PVD) techniques such as TiN coatings are well known for providing surfaces with a high hardness, in practice they often exhibit poor performance under mechanical loading, since the coatings are usually too thin to protect the substrate from the contact conditions. In this paper, these challenges were overcome by a duplex process of microplasma oxidation and arc ion plating (AIP), in which an alumina layer Al₂O₃ was deposited on an Al alloy substrate (using MPO as a pre-treatment process) for load support, and a TiN hard coatings were deposited (using AIP) on top of the Al₂O₃ layer for low friction coefficient. Microhardness measurements, pin-on-disc sliding wear tests, and antiwear tests using a Timken tester were performed to evaluate the mechanical and tribological properties. Scanning electron microscopy (SEM) was used to observe coating morphology, and to examine wear scars from pin-on-disc test. The research demonstrates that a hard and uniform TiN coating, with good adhesion and a low coefficient of friction, can successfully be deposited on top of an alumina intermediate layer to provide excellent load support. The investigations indicate that a duplex combination of MPO coating and TiN PVD coating represents a promising technique for surface modification of Al alloys for heavy surface load bearing application.     

Effect of reinforcing submicron SiC particles on the wear process of electrolytic NiP coatings

The effect of submicron silicon carbide frictional strengthening admixtures and heat treatment on the wear process of nickel phosphide coatings obtained by electrolytic deposition is studied. Despite the heat treatment and admixtures of silicon carbides, the wear of the coatings is of abrasion-oxidizing nature; in the case of NiP-SiC composite coatings, the oxide films formed during the friction process do not exhibit the shield effect; these films show a considerable effect on the wear of silicon-free NiP coatings. The silicon carbide admixtures increase the hardness of the electrolytic coatings but prevent the oxide films formed in the frictional process from attaching to the contact surface. Annealing of the coating reduces the wear rate. In the process of heat treatment, the crystalline phase Ni₃P is formed in the NiP matrix, increasing the coating hardness. At the same time, in the process of annealing of NiP-SiC composite coatings, the NiP matrix cracks around the silicon carbides. As a result, silicon carbides are extracted in the frictional process and the wear rate of the NiP-SiC composite coating grows.