基于单颗磨粒划切试验的SiCp/Al复合材料表面去除机理研究

碳化硅颗粒增强铝基（SiCp/Al）复合材料中含有不规则碳化硅颗粒使得材料内部形成大量非理想截面,为材料表面的有效去除带来困难. 为了揭示材料去除机理,进行SiCp/Al 复合材料单颗磨粒变切深划切的表面去除仿真分析和试验验证. 研究结果表明,界面破坏对表面创成有重要影响,存在铝合金基体撕裂、界面分离,碳化硅颗粒裸露、裂纹扩展、破碎脱落、压入铝合金基体、碎片滑擦材料表面等去除过程,碳化硅颗粒中部大面积破碎脱落形成凹坑,并在刀具推挤作用下对材料进行二次切削,使铝合金基体表面形成非连续裂纹. SiCp/Al复合材料中由于铝合金基体的存在,实际划切深度小于名义切削深度. 研究可以为SiCp/Al复合材料去除机理与加工研究提供一定借鉴.     

A mesomechanical ductility model of SiCp/Al composite

1 INTRODUCTIONAl alloy matrix composites reinforced with SiCparticles are widely usedin aerospace , military andcivil industries because of their high specificstrength, modulus , wear resistance and fatigue re-sistance . With the increase of volume fraction ofSiC,the tensile ductility al ways decreases ,the e-lastic modulus increases ,and the strength changescomplexly .It is a noticeable issue to opti mize themechanical properties .Recently , many researchershave established some mechani…     

冷却速度对SiCp/2024Al热残余应力影响的数值模拟

针对冷却速度对SiCp／2024Al复合材料热残余应力的影响，通过复合材料显微组织观察，根据复合材料的形貌特征，建立了平面应力状态的复合材料组织模型，利用有限元方法对SiCp／2024Al复合材料淬火和退火过程的热应力进行了数值模拟．结果表明，由于SiC增强颗粒与铝基体之间的热膨胀系数差异较大，热处理后颗粒和基体的界面附近产生很大的热残余应力场，同时基体发生塑性应变；冷却速度对复合材料热残余应力没有明显影响．     

Al2O3/ZL101-La合金复合材料凝固组织与溶质偏析的研究

利用挤压铸造法制备了Al2O3/ZL101-La复合材料,研究了稀土La对复合材料凝固组织以及基体合金凝固时溶质偏析的影响.结果表明,稀土La可细化基体合金的凝固组织,并且富集在界面附近,有利于改善铝合金液对氧化铝短纤维的润湿性,但是未发现任何富稀土相在界面上形成.稀土La对基体合金中的镁的偏聚没有很明显的影响,镁和稀土La均在界面处富集,且它们的分布位置大致近似.     

(TiB_2+SiC_p)/ZL101复合材料组份优化及其力学性能

为了确定(TiB2+SiCp)/ZL101复合材料的最佳成分,通过采用正交实验分析方法,研究复合材料的制备工艺,测试了复合材料的力学性能,并对该材料进行了显微金相分析和透射电子显微分析.结果表明,复合材料经过热处理后,抗拉强度、布氏硬度分别较基体合金ZL101提高了21.4%、49.3%;热膨胀系数较基体合金降低了14.1%;热处理后,复合材料中的共晶硅以粒状形态均匀分布于基体中;复合材料中增强相TiB2为粒状,SiC粒子为多边形尖角块状,两相较均匀分布于基体晶粒内部,且与-αAl的界面结合良好.     

Effects of Al addition on the microstructure and properties of Nb/Nb5Si3 in situ composites fabricated via spark plasma sintering

Dense Nb/Nb5Si3 composites were fabricated via spark plasma sintering technology using Nb, Si, and Al elemental powders as raw materials. The microstructttres of the synthesised composites were analyzed through scanning electron microscopy, X-ray diffraction, and electron probe microanalysis. The results show that the composites consisted of residual Nb particle phase and Nb5Si3 phase. The microstructure of the Nb/ Nb5Si3 in situ composites was evidently affected by Al addition, which prompted the formation of the Al3Nb10Si3 phase. In addition, the Rockwell hardness of the composites decreased with the increase in AI additions. The Rockwell hardness of Nb-20Si is 60HRC, which decreased to approximately 52.7 HRC when the Al content increased to 15 at%. The oxidation resistance of the Nb/NbsSi3 in situ composites significantly improved with the increase in Al addition.     

Interface Stability of the SiC Particles/Fe Matrix Composite System

The interface reaction between the SiC particles （ SiCp ） and Fe was stndicd during sintering the SiCp reinforced Fe matrix composites at 1423 K for 1 h. In the composite having 3wt% （weight ratio） SiCp （the 3SiCp/ Fe composite）, the interface reaction products of Fe3 Si, the carbon precipitates, and Fe3 C or pearlite were generated. Fe3 Si coustructs the bright matrix of the reaction zone in the original situation of the SiCp. The carbon precipitates are randondy embedded in the reaction zone. Fe3 C or pearlite exists at the grain boundaries of the Fe matrix. As increasing the SiCp concentration in the SiCp/ Fe composite, the inteusity of the interface reaction between SiCp and Fe iacreases. After the 10SiCp/ Fe composite （ having 10wt .% SiCp ） sintered at 1423 K for 1 h, all of SiCp are decomposed, and replaced by the reaction zone composed of Fe3 Si and the carbon precipitates. No Fe3 C or pearlite was genertaed during the reaction. The effects of the techniques of oxidizing of SiCp , coating SiCp by interaction with the Cr powder, and alloying the Fe matrix by adding the Cr element on the interface stability of the SiCp/ Fe composite system were also investigated, respectitely. The oxide membrane and the coating layer on SiCp can inhibit the interface reaction between SiCp and Fe by isolating SiCp from the Fe matrix during sintering. The interface reaction does not occur in the 3 SiCp/ Fe- 10 Cr composite but in the 3 SiCp/ Fe-5 Cr composite. In the SiCp/ Fe-Cr alloy composites, the interface reaction between SiCp and the Fe- Cr alloys is weaker than that between SiCp and Fe . The Cr element behaves as a diluent, it causes a redaction in the interface reaction, which is proportional to the amount of the element added.     

Al2O3f/Al合金复合材料凝固偏析研究

利用挤压铸造制备了Al2 O3f/Al合金复合材料 ,研究了复合材料的凝固偏析 .研究结果表明 ,在复合材料的凝固末期 ,由于选择结晶 ,剩余液相中的溶质变化导致基体合金类型的改变 ,最终凝固偏析主要产生在纤维 /基体界面上 .偏析对材料的组织结构和性能的影响可能是双重的 .     

Effect of heat treatment on microstructures and mechanical properties of Al-6Zn-2Mg-1.5Cu-0.4Er alloy

The microstructures and mechanical properties of A1-6Zn-2Mg-1.5Cu-0.4Er alloy under different treatment conditions were investigated by transmission electron microscopy (TEM) observation, and tensile properties and hardness test, respectively. The relationship between mechanical properties and microstructures of the alloys was discussed. With trace Er addition to A1-Zn-Mg-Cu alloy, Er and Al interact to form Al3Er phase, which is coherent with α(Al) matrix. The results show that A1-Zn-Mg-Cu alloy after retr...     

纳米复合材料超声波焊接制备下剪切强度及组织研究

采用超声波焊接方法制备碳纳米管增强铝基复合材料,研究试件表面处理状态、焊接时间和焊接压力等工艺参数对焊接接头剪切强度的影响规律。试验结果表明:碳纳米管的加入具有较好的增强效果,提高了复合材料的力学性能;试件表面加乙醇处理、焊接时间120 ms及焊接压力17.5 MPa时,复合材料的接头剪切强度最高为11.12 MPa,相比基体材料提高28.6%;通过金相观察、扫描电镜(SEM)分析,发现碳纳米管很好地嵌入到了铝合金基体中,起到增强效果。     

挤压铸造Al_2O_3／Al─Si合金复合材料的凝固组织与凝固模型

利用挤压铸造技术制备了Ａｌ２Ｏ３／Ａｌ─Ｓｉ合金复合材料，研究了这种复合材料的凝固组织．结果表明，氧化铝纤维可作为铝硅合金中硅相非自发形核的衬底，但是未观察到纤维对α相的细化作用；氧化铝纤维与浸渗压力影响了复合材料的凝固过程，复合材料具有不同于普通基体合金的最终凝固组织．基于实验结果和凝固理论，提出了Ａｌ２Ｏ３／Ａｌ─Ｓｉ合金复合材料的凝固模型．     

凝固偏析对氧化铝/铝-铜合金复合材料性能的影响

利用挤压铸造技术制备氧化铝／铝-铜合金复合材料，研究了凝固偏析对复合材料机械性能的影响．结果表明：复合材料在凝固过程中由于选择结晶，基体中的溶质元素偏聚在纤维／基体界面或晶界上；纤维加速了复合材料的时效强化过程，随着纤维体积分数的增加，复合材料的硬度、强度、弹性模量增大，而塑性下降；随着预制件预热温度的升高，冷却速度减慢，凝固偏析加剧，复合材料的机械性能下降．     

Al2O3f/Al-4%Cu合金复合材料凝固偏析研究

利用挤压铸造制造了Al2O3f/Al-4%Cu合金复合材料，研究了复合材料的凝固偏析，研究结果表明，在复合材料的凝固末期，由于选择结晶，剩余液相中的溶质变化导致基体合金类型的改变，最终凝固偏析主要产生在纤维／基体界面上，偏析对材料的组织结构和性能的影响可能是双重的。     

SiO2/Al-Mg复合材料的界面反应

对粉末冶金法制备的SiO2/Al-Mg复合材料的显微组织、物相组成及反应过程进行了研究,发现10%~20%SiO2-Al-Mg复合材料的最终物相均为MgAl2O4、MgO、Mg2Si、Si和Al.反应时Al、Mg由SiO2颗粒外向颗粒内扩散,SiO2被夺去氧,Si被置换到原SiO2颗粒外.总结了颗粒SiO2与Al-Mg反应的热力学,推测了颗粒内外的优先反应.     

Al2O3／ZA12复合材料凝固组织的研究

利用挤压铸造制备了Ａｌ２Ｏ３／ＺＡ１２复合材料,研究了其凝固组织。结果表明,复合材料的基体组织细小,合金元素通过适当的化学反应可改善纤维与基体的结合;在凝固过程中,Ａｌ２Ｏ３纤维可作为ＺＡ１２中共晶体非自发形核的衬底,纤维／基体界面上的硅在共晶体的共生生长过程中起了领先相作用,导致复合材料的共晶转变是由铝硅共晶转变和锌铝共晶转变组成。     

磁场对离心铸造SiCp/Al合金基复合材料中颗粒分布的影响

采用一种新型的工艺制备ＳｉＣ_Ｐ／Ａｌ合金基复合材料,即在传统离心铸造工艺条件下引入稳恒直流磁场,利用工艺中的电磁搅拌作用使离心铸造复合材料的偏聚情况得以改善,并探讨了稳直流磁场对颗粒分布均匀性的作用机理．     

Synthesis and characterization of VO<Subscript>2</Subscript>/mesoporous carbon composites for hybrid capacitors

VO₂/ordered mesoporous carbon (CMK-3) composites were prepared by solid-state reaction process. The microstructures were characterized by X-ray diffraction (XRD), nitrogen adsorption and desorption, field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The experimental results showed that the vanadium oxide in the composites was vanadium dioxide (VO₂) with monoclinic structure, which was artificially loaded on the outer surface of CMK-3. VO₂/ordered mesoporous carbon composites present a significantly improved capacitive performance (131 F/g) increased by 40.86% compared to that of CMK-3 carbon (93 F/g). Therefore, as-prepared VO₂/mesoporous carbon composites suggest promising applications in hybrid capacitors.     

SiCp／Al复合材料无压自浸透工艺

研究了用Ｋ２ＺｒＦ６作为助浸剂与ＳｉＣｐ进行混合的工艺，实现用无压自浸透的工艺制造ＳｉＣｐ／Ａｌ复合材料。结果表明，直接混合工艺比Ｋ２ＺｒＦ６水处理工艺简便，并易于控制Ｋ２ＺｒＦ６的用量，Ｋ２ＺｒＦ６与ＳｉＣ混合后，能明显提高ＳｉＣ颗粒和Ａｌ液的湿润性。     

纳米SiO2对SMA复合材料界面强度的改善

形状记忆合金纤维与基体之间较弱的界面粘结强度在很大程度上限制了其发展与应用.本文试图用纳米SiO2颗粒来改善形状记忆合金复合材料的界面力学性能,并讨论了不同种类以及不同含量的纳米SiO2颗粒对形状记忆合金复合材料界面强度的影响,并采用扫描电镜和透射电镜的方法分析了其作用机理.实验结果表明,纳米SiO2颗粒的加入能够有效提高形状记忆合金纤维增强复合材料的界面粘结强度.     

Thermodynamics and kinetics of in-situ formation of TiAl3/7075 composites

The thermodynamics and kinetics of the reaction between Titanium powder and 7075 aluminum alloy were investigated to assess the possibility of preparing TiAl₃/7075 composites by in-situ synthesis method. Results show that Ti and Al melt can form TiAl₃ spontaneously, which is considered as a reinforced phase of the matrix. Measurements such as XRD, SEM, and EDX were performed to characterize the as-synthesized samples, and results confirmed the formation of TiAl₃ in aluminum matrix composites. The reactive kinetics was controlled by three main factors, which are the system temperature, particle size of Ti, and the thickness of external diffusion layer.