Color measurement of single yarn based on hyperspectral imaging system

This article proposed a novel approach to color measurement of a single yarn using hyperspectral imaging system (HIS). Due to the size of a single yarn, it is impossible for spectrophotometers to measure its color directly. The HIS can acquire the spectral reflectance of continuous bands within a region of interest on a yarn sample, which can achieve color measurement of a single yarn compared with traditional spectrophotometers. A single yarn is segmented from the background by a spectral matching method through adaptively setting threshold of Fréchet distance values. The spectral reflectance of single yarn is specified by a method that lightness of pixels used as weight. The experiment based on Pantone Cotton Chip Set shows that the interinstrument agreement between the HIS and a standard spectrophotometer Datacolor SF650 has a significant improvement after using the R-Model, and the average percentage improvement of the color difference is up to 54.99%. The yarn segmentation comparative experimental results show that the proposed method to segment single yarn from background is better in retaining the edge information of the yarn than the modified K-means clustering method, and the color of the yarn segmented by the proposed method is more similar to the actual color of single yarn.     

Diffuse reflectance and transmittance of IR absorbing polymer film

This study employs the ray tracing method to analyze and develop mathematical formulae for the internal reflectance of a free standing thick polymer film. The proposed formulae are then used to simulate the diffuse reflectance and diffuse transmittance. Analysis results indicate that internal reflectance is not a constant and varies with film thickness and absorption property. Internal reflectance of the front surface (irradiated surface) surpasses that of the back surface. In addition, all the internal reflectances decrease with the film thickness and the absorption property. In light of the measured thickness and experimentally determined diffuse transmittance of a polymer film, the extinction coefficient to diffuse IR irradiation can be obtained by interpolating in the graphs provided in this study.     

Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings

Prediction of radiative transport through translucent thermal barrier coatings (TBCs) can only be performed if the scattering and absorption coefficients and index of refraction of the TBC are known. To date, very limited information on these coefficients, which depend on both the coating composition and the microstructure, has been available for the very commonly utilized plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) TBCs. In this work, the scattering and absorption coefficients of freestanding plasma-sprayed 8YSZ coatings were determined from room-temperature normal-incidence directional-hemispherical reflectance and transmittance spectra over the wavelength range from 0.8 to 7.5 μm. Spectra were collected over a wide range of coating thickness from 60 to almost 900 μm. From the reflectance and transmittance spectra, the scattering and absorption coefficients as a function of wavelength were obtained by fitting the reflectance and transmittance values predicted by a four flux model to the experimentally measured values at all measured 8YSZ thicknesses. While the combined effects of absorption and scattering were shown in general to exhibit a nonexponential dependence of transmittance on specimen thickness, it was shown that for sufficiently high absorption and optical thickness, an exponential dependence becomes a good approximation. In addition, the implications of the wavelength dependence of the plasma-sprayed 8YSZ scattering and absorption coefficients on (1) obtaining accurate surface-temperature pyrometer measurements and on (2) applying mid-infrared reflectance to monitor TBC delamination are discussed.     

A multispectral imaging approach to colour measurement and colour matching of single yarns without winding

This paper investigates a multispectral imaging approach to colour measurement and colour matching of single yarns. The small size of a single yarn makes it impossible for spectrophotometers directly to acquire its spectral reflectance. Multispectral imaging systems, on the other hand, have the potential to measure the reflectance of single yarns as they can record both the spectral and the spatial information of a sample. A multispectral imaging system, namely imaging colour measurement, has been developed to conduct colour measurement of single yarns. A single yarn is first detected from backgrounds by a modified K‐means clustering method. The reflectance of the single yarn is then specified by an averaging method. Comparative experiments based on 100 pairs of single yarns and corresponding yarn windings show that the reflectance magnitude of a single yarn acquired by imaging colour measurement is smaller than that of corresponding yarn winding measured by a Datacolor 650 spectrophotometer. Experiments on 16 single yarns show that the repeatability and spatial reproducibility of the imaging colour measurement system in measuring a single yarn colour are 0.1185 and 0.2827 CMC(2:1) units. A colour matching comparison experiment (pass or fail), using 24 pairs of single yarns and corresponding pairs of solid‐colour yarn dyed fabrics, shows that single yarns measured by imaging colour measurement can achieve similar colour matching results to solid‐colour yarn dyed fabrics measured by the Datacolor 650 spectrophotometer, with degrees of similarity of 87.5 and 83.3% when the CMC(2:1) and CIE2000(2:1:1) colour difference formulas are employed.     

Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360°C in a wavelength range from 1.2 μm up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka–Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (<1 cm⁻¹) at wavelengths between 2 μm and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as "edge to shorter wavelengths."]     

The color of absorbing scattering substrates. I. The color of fabrics

A treatment of the color of textile materials is proposed which is an extension of G. G. Stokes' “pile of plates” problem. Unlike the conventional treatment of this subject, e.g., that by Kubelka and Munk, this approach permits independent determination of all variables: coefficient of absorption of the dye, refractive indexes of the fibers, the effect on color of the geometry of the fabric and yarn, and the distribution of the dye within the fiber. Here, cylindrical, optically homogeneous fibers in a parallel array are assumed. Experimental data show that this treatment predicts far more satisfactorily the color of fabrics at high dye concentrations and low reflectance values than does the Kubelka-Munk approach.     

Automatic detection of layout of color yarns of yarn‐dyed fabric. Part 1: Single‐system‐mélange color fabrics

To recognize the layout of color yarns of single‐system‐mélange color fabric automatically, a novel FCM‐based stepwise classification method is proposed in this article. This method consists of three main steps: (1) warp yarn segmentation, (2) weft color recognition, and (3) the layout of color warps recognition. In the first step, the yarn segmentation method based on mathematical statistics of subimages is adopted to localize warp yarns preliminarily; and then the segmentation results of warp yarn are corrected by misrecognized‐boundary remove and missing‐boundary interpolation. In the second step, the weft color is extracted based on RGB color histograms of whole fabric image. In the third step, the pixels in each warp yarn are classified into two clusters by fuzzy C‐means clustering (FCM) algorithm in CIELAB color model separately, and the preliminary recognized layout of color warps is obtained. All warp colors are clustered by FCM algorithm in CIELAB color model again and the precise layout of color warps is output. The experimental and theoretical analysis proved that the proposed method can recognize the layout of color yarns of single‐system‐ mélange color fabrics with satisfactory accuracy and good robustness. © 2015 Wiley Periodicals, Inc. Col Res Appl, 40, 626–636, 2015     

Color pattern recognition for yarn‐dyed fabrics

In the process of designing and analyzing the yarn‐dyed fabric, the yarn color pattern has an important effect on the appearance of the fabric. An automatic color pattern recognition method for yarn‐dyed fabric is proposed in this study. The proposed method uses the fabric images obtained from a high‐resolution digital camera image acquisition system. The local statistical texture features are used for yarn texture segmentation. The yarn color classification problem is then formulated in a research framework of multiregion fuzzy segmentation, which can be added auxiliary variables and solved efficiently by the fast dual projection algorithm. The color values of the yarn crossing points are calculated by the yarn color classification results. The locations of the yarn crossing points are detected by a lightness gradient projection method. Different kinds of fabrics are tested in the experiments. Experiments on 14 actual fabrics show that the approach proposed in this study is effective for classifying yarn color and extracting the yarn color pattern in yarn‐dyed fabric.     

Simplified measurement of virgin olive oil color by application of the characteristic vector method

There are several simplified methods to measure the color of virgin olive oils. However, their reliability is questionable, as they provide errors that sometimes can be considerable. A new method to calculate color coordinates and objective chromatic parameters in the color region of these olive oils is proposed with the aim of overcoming these objections. The method is a simplification of the original method proposed by the Commission Internationale de l'Eclairage (CIE), based on the measurement of the complete visible spectrum, from 380 to 770 nm. The characteristic vector analysis provides new equations to calculate tristimulus values as functions of these transmittance values based on a reconstruction of oil transmission spectra measuring from three to six wavelengths. The results show that color differences exist between the color coordinates of the experimental samples and those obtained by means of the proposed method. For more than 90% of the samples, the difference was smaller than three CIELAB units when equations based on four or more wavelengths were used.     

A novel analysis of color component for top dyed melange yarn with support vector machine

In view of the difficulty of distinguishing the color component in top dyed melange yarn due to the spectral overlap of the component colors, a novel color component analysis method based on support vector machine is presented. With this method, spectra data can be distinguished more accurately and effectively than with the traditional method—human‐eye detection—and therefore, the method will be very helpful for accurate color matching. In our work, the core idea was to convert the overlapped spectra data into linearly separable ones in a high dimension space, followed by recognition and determination of the composition of melange yarn by trained support vector machine classifier. The effects of four kernel functions, i.e., linear, radial basis kernel, sigmoid, and polynomial, as well as five spectral preprocessing methods, including amplification, first derivative, second derivative, principal components analysis, and L*a*b* values were studied. The results demonstrated that with the amplification factor of 100 of reflectance spectra coupled with L*a*b* as input data, and using radial basis kernel as kernel function, the highest recognition rate was achieved, with an average recognition rate of eight colors of 96.5%, indicating that it was a better color component analysis method for top dyed melange yarn. © 2015 Wiley Periodicals, Inc. Col Res Appl, 41, 636–641, 2016     

Determination of exact absorption behaviour in the mid-infrared spectral range of poly(methylmethacrylate) by Fourier transform infrared reflection spectroscopy

In the present work we demonstrate that infrared absorption fre-quencies and band shapes of poly(methylmethacrylate) (PMMA) homopolymers vary strongly with the type of spectra recorded. The reason is that, in general, any measured optical quantity, such as absorption, transmittance or reflectance, is a complicated function of the refractive index, n(ν), and the absorption index, k(ν), of the material. Kramers–Kronig analysis is applied to external reflection spectra from a single polymer surface measured near the normal incidence angle. Absorption spectra, k(ν), are then deduced and used to calculate grazing angle specular reflectance, attenuated total reflectance, diffuse reflectance and transmission spectra. Then, it is shown that the calculated spectrum for each experiment accurately predicts the experimental one, proving that differences are optical artifacts and not true sample differences. Exact peak absorption for PMMA is 1730cm^-1 and should be taken as a reference value for the calculation of frequency shifts for further physico-chemical interpretation such as specific interactions or molecular orientation. ©1997 SCI     

蓝光吸收剂在PC中的应用探究

针对白光LED光源的富蓝化现象,采用蓝光吸收剂改性聚碳酸酯(PC)基材,利用蓝光吸收剂吸收高能量的蓝光并转化为热能或无害低能辐射释放出来,以消除白光LED光谱中的高能蓝光波段。结果表明,蓝光吸收剂改性PC材料后,可以有效减少各波长处的蓝光透过率,并且随着蓝光吸收剂添加比例的增加蓝光吸收效果增强;蓝光波段的吸收会造成光谱的缺失,造成光源的显色指数、色温、光通量的下降;不同类型的蓝光吸收剂改性PC树脂的蓝光吸收效果存在差异。     

原液着色Lyocell纤维制备过程中炭黑与溶剂的相互作用

着色剂的加入是否会影响Lyocell绿色生产工艺和溶剂的回收利用是原液着色Lyocell纤维实际生产面临的问题。选用炭黑作为黑色颜料,研究了炭黑在NMMO溶液中的分散性,分析了不同炭黑添加量的溶液特性、纤维的可纺性和纺丝条件,用X射线衍射法分析了纤维的基本结构和性能的关系。着重采用红外光谱、紫外光谱分析了炭黑对溶剂NMMO的影响,用紫外光谱研究了炭黑在纺丝成形和纤维使用过程中的迁移量。结果表明:整个纺丝成形过程中炭黑没有发生迁移,炭黑的添加不影响溶剂的回收利用;制得的原液着色Lyocell纤维色牢度高;随着炭黑添加量的增大,纤维结晶度会有所降低,纤维强度略有下降,但依然满足服用要求。     

Spectral‐reflectance‐factor deconvolution and colorimetric calculations by local‐power expansion

The experimental data of the spectral‐reflectance factor are considered as dependent on the instrument‐spectral‐bandwidth function in order to perform their deconvolution and to compute the tristimulus values. The deconvolution is performed by local‐power expansion. In the case that the spectral‐bandpass dependence regards only the spectral transmittance of the monochromator, the goodness of this technique is evaluated by simulation (1325 reflectance factors of the Munsell samples are considered as trial functions) and compared with other usual techniques: Stearns and Stearns method for bandpass error, ASTM‐weighting function interpolation, and Venable‐ASTM weighting function. The zero order of the deconvoluted spectral‐reflectance factor can be related to the Stearns and Stearns method for bandpass error. With respect to any other technique, the second‐order deconvolution, for the CIE standard illuminants, gives color differences lower by a factor 0.1 or more for a bandpass Δλ = 10 nm, color differences lower by a factor 0.3 or more for a bandpass Δλ = 20 nm and, for the CIE fluorescent illuminants, color differences generally lower. © 2000 John Wiley & Sons, Inc. Col Res Appl, 25, 176–185, 2000     

The determination of optical absorption and scattering in translucent porcelain

Reflectance and transmittance theories have been used to calculate the optical absorption and scattering within materials. For these calculations, the incorporation of corrections for interfacial reflections has not been universally applied, and when corrections have been incorporated, the value used for the diffuse internal reflection coefficient has often been based on theoretical considerations. A method of incorporating interfacial-reflection corrections is presented. The importance of the incorporation of such corrections, with the proper value for the internal reflection coefficient, is clearly demonstrated for both reflectance and transmittance theories. The limitation of transmittance theory to materials with a scattering power (SX) of greater than 0.5 is also demonstrated for collimated illumination, unless an independent determination is made of the internal reflection coefficient.     

Colour change as a result of textile transformations

This paper studies the influence of textile structure on its colour. It provides a systematic analysis of the changes in spectral reflectance and hence colour differences between three textile substrates: roving, yarn and woven fabric. The transformations of the reflectance spectrum as a result of the changes of the structure were modelled and the evolutions of the colorimetric coordinates L *, a *, b *, C * and h associated with these various transformations were thus calculated and analysed. The work also offers a useful method of modelling the predicted colour from one substrate form to another, which is important to the textile industry.     

Color measurement of a ruby

The impurity transition element chromium Cr³⁺ in ruby can be excited to high energy levels by absorbing visible light. When the excited Cr³⁺ returns to ground state through an intermediate energy level, the ruby emits red light as fluorescence. The fluorescence of ruby is actually caused by visible light, not by ultraviolet. The color of ruby is attributed to both the absorption and the fluorescence. The spectrum of a natural ruby under visible light is directly measured by a dual integrating sphere spectrometer. The measured spectrum includes both the spectral reflectance and the fluorescence caused by visible light. This study confirmed that the red fluorescence of ruby is indeed caused by visible light, not by ultraviolet radiation. In addition, average color of the ruby is calculated from the measured spectrum, and true color grade is also obtained by the artificial intelligent software of the spectrometer. © 2012 Wiley Periodicals, Inc. Col Res Appl, 38, 328–333, 2013     

An investigation of how the texture surface of a fabric influences its instrumental color

In this article, the influence of texture surface of a fabric on its instrumental color is investigated. While former studies have found it is difficult to establish a quantitative relationships between texture of fabric and its instrumental color (color difference and color attributes, such as lightness, chroma, and hue), this article investigates from a theoretical and empirical perspective the interaction between texture and color. Eighty four knitted cotton yarn dyed fabric samples in four color centers and 21 texture structures were used in this study. It is revealed that fabric samples with different texture surfaces define a set of lines with identical direction in the reflectance space, and thus the normalized reflectance curves of these samples are identical. In the CIEXYZ space, tristimulus values of these fabric samples define a line, and thus their chromaticity coordinates are constant. In the CIELAB space, however, linearity is lost due to the non‐linear transformation from the CIEXYZ space to the CIELAB space. The finding of this article has the potential to discount the influence of texture of a fabric on its color. Experiments show that the influence of texture on color for samples in the four color centers can be reduced by 79, 55, 71, and 57%, respectively comparing to the real measured color difference. © 2014 Wiley Periodicals, Inc. Col Res Appl, 40, 472–482, 2015     

干法纺黑色氨纶生产技术的研发

阐述了干法纺黑色氨纶生产技术的研究过程,介绍了相关生产工艺流程以及技术关键点,即采用高色素炭黑和超分散剂,选择适当的控制条件,研制出具有良好粒度分布(平均粒径约100 nm,最大粒径约400 nm)和着色性能的色浆。利用原液着色法,选择合适的炭黑添加量(相对氨纶丝质量分数约为0.5%),生产出符合干法氨纶纺丝要求的黑色原液,实现了黑色氨纶在现有生产线上的工业化生产。     

Absorption and reflection of infrared radiation by polymers in fire‐like environments

In large‐scale fires, the input of energy to burning materials occurs predominantly by radiative transfer. The in‐depth (rather than just surface) absorption of radiant energy by a polymer influences its ignition time and burning rate. The present investigation examines two methods for obtaining the absorption coefficient of polymers for infrared radiation from high‐temperature sources: a broadband method and a spectral method. Data on the total average broadband transmittance for 11 thermoplastics are presented (as are reflectance data), and the absorption coefficient is found to vary with thickness. Implications for modeling of mass loss experiments are discussed. Copyright © 2011 John Wiley & Sons, Ltd.