具有网络互穿结构TiC／AZ91D镁基复合材料的一种合成方法

介绍一种新的低成本合成具有网络互穿结构TiC／AZ91D镁基复合材料的方法——原位反应渗透法。该方法中，TiC陶瓷增强相由元素粉末Ti和C间原位反应直接合成．无需添加第三相金属粉末，仅在原位反应发生的同时熔融基体镁合金由毛细管力作用渗入（Tip＋Cp）预制块内部构成致密的具有网络互穿结构的TiC／AZ91D镁基复合材料。实验结果和理论计算表明：（1）通过精确控制（Tip＋Cp）预制块的致密度，考虑原位反应发生前后形成的TiC本征体积变化，即可获得具有不同TiC陶瓷含量的网络互穿结构镁基复合材料；（2）原位合成的TiC陶瓷是一可变化学剂量比的化舍物．其晶格常数随反应条件而变化，主要取决于反应条件和原始元素粉末的尺寸。     

Compressive Deformation of Semi-Solid AZ91D Magnesium Alloy

The compression tests of semi-solid AZ91D Mg alloy have been conducted on a parallel-plate viscometer. The results are as follows. With increasing the compression temperature, the deformation rate or the strain rate of the specimens rises, but the compressive stress continuously decreases; the deformation strain is obviously linear with the compressive stress and independent on compression temperature under a given compression load. In the wake of the compression load being added, the compressive strain increases but the compressive stress decreases clearly; the deformation strain is obviously linear with the compressive stress under different compression load. The mathematical apparent viscosity model about the semi-solid compressed AZ91D Mg alloy has been established, i.e. ηapp=2004.2exp(15.61fs)γ1.317fs-1.3511.     

外场对SiCp/AZ91D镁基复合材料组织和性能的影响

在常规条件、电磁模拟微重力场、脉冲电流场和"电磁模拟微重力+脉冲电流"复合场四种外场条件下制备出SiCp含量5wt％的SiCp/AZ91D镁基复合材料,分析测试结果表明:在常规条件下,样品晶粒粗大,β-Mg17Al12相呈现出无规律的网格状结构,新生相Mg2Si以颗粒状的初生相和树枝状的共晶相存在;在电磁模拟微重力场条...     

Study on tensile properties and microstructure of cast AZ91D/AlN nanocomposites

AZ91D is a widely used magnesium alloy, but its application is generally limited to below 150 °C because of its weak creep resistance and tensile properties at elevated temperatures. In this study, high temperature (200 °C) tensile properties including yield strength and tensile strength of AZ91D are much improved by adding only about 1.0 wt% AlN nanoparticles in the AZ91D matrix through an innovative ultrasonic cavitation based dispersion of nanoparticles. The good ductility of AZ91D is also retained in AZ91D/1%AlN nanocomposites. It is found that ultrasonic cavitation based solidification processing is very effective to disperse AlN nanoparticles in AZ91D melts, which is difficult to obtain by traditional mechanical stirring methods. With a good combination of high temperature yield strength, tensile strength and ductility, AZ91D/1%AlN nanocomposite is promising as a new class of structural materials to be used at temperatures up to 200 °C or higher.     

AZ91D镁合金的触变成形及其磨损性能的研究

研究了加热时间和模具预热温度对AZ91D镁合金触变成形性、组织和磨损性能的影响。结果表明,适合AZ91D镁合金触变成形的最佳加热时间为90min(在585℃),模具预热温度为350℃;在此工艺条件下,初生相颗粒较圆整、粒度较小,组织最致密,相应地,其耐磨性也最好;与金属型铸造相比,明显地提高了耐磨性。     

Study on microstructure of squeeze casting AZ91D alloy

Abstract

The present paper reports the investigation of the microstructure distribution of squeeze cast AZ91D alloy. The microstructure of squeeze cast AZ91D alloy is not uniform and is composed of four zones, which are chilled layer, segregation zone, pressured crystallisation area and hot spot area respectively. Moreover, in the pressured crystallisation area, the microstructure sequence in the transverse section from the outside to the inside could be divided into four sublayers, such as fine equiaxial dendrite area, dendrite area with a high directivity, confusion dendrite area and disorder dendrite area. The volume fraction of the intermetallic compound Mg₁₇Al₁₂ also varied with the location. The volume fraction of Mg₁₇Al₁₂ in the pressured crystallisation area is the largest except in the segregated zone.     

应变速率对AZ91D镁合金力学行为影响

本文通过静态拉伸试验机和高应变速率冲击拉伸试验装置,对AZ91D压铸镁合金分别进行了不同应变率下(10-4、10-2、300和1400s-1)拉伸力学性能的试验,获得了各应变速率下完整的应力-应变曲线.并通过扫描电镜对其拉伸断口进行分析.试验结果表明,其屈服应力(σs)、拉伸强度(σb)随着应变速率的增加而增加,失稳应变(εb)则随着应变速率的增加而有所减小;而弹性模量则对应变率不敏感.采用John-son-Cook材料模型描述AZ91D镁合金应变速率相关的应力应变本构模型,其拟合结果和实验结果基本相吻合.扫描电镜断口分析结果表明,动态和静态的断裂方式基本相同,都是以准解理断裂特征为主,局部区域伴有解理断裂;存在典型的缩松断裂形貌.     

AZ91D室温环境棘轮及其低周疲劳行为

通过AZ91D室温环境应力控制下的低周疲劳试验,对铸造镁合金棘轮及其低周疲劳行为进行了研究,讨论了室温环境下材料的应力循环特性、棘轮行为、塑性应变范围、全应变范围等疲劳参量随载荷水平和加载历史的变化规律,同时基于平均应力修正对材料的应力-寿命曲线进行了讨论。研究结果表明:AZ91D在室温环境下的应力循环呈循环硬化,材料的棘轮行为和塑性应变范围、全应变范围等疲劳参量依赖于载荷水平和加载历史,另外考虑平均应力修正后的应力-寿命曲线预测效果有明显改观。     

AZ91D镁合金化学镀Ni-P/Ni-W-P双层镀层研究

为了提高镁合金的耐磨耐蚀性,研究了一种镁合金直接化学镀Ni-P/Ni-W-P双层镀层的方法.采用扫描电镜(SEM)和X-射线衍分析射仪(XRD)分析了镀层的微观结构.对镀层进行了极化曲线分析,并进行了盐酸腐蚀试验和结合力试验.结果表明,该复合镀层组织致密无孔,具有较高的显微硬度和高耐蚀性.镀层硬度可达622HKV,试样在10%的HCl溶液中可保持近3h不腐蚀基体,对镁合金起到很好的保护作用.     

挤压复合AZ91-(SiC_(P)/AZ91)复合板材显微组织和力学性能EI北大核心

在300,350,400℃下成功通过挤压复合法制备多层AZ91-(SiC_(P)/AZ91)复合板,探究AZ91-(SiC_(P)/AZ91)复合板中SiC_(P)/AZ91复合材料层和AZ91层的显微组织演变、界面的演化机制和力学性能变化规律。结果表明:热挤压复合中,AZ91-(SiC_(P)/AZ91)多层复合板中合金层发生完全动态再结晶,晶粒细化,合金组织随挤压温度的升高更均匀,而且外层合金层比内层合金层晶粒尺寸略大;SiC_(P)/AZ91复合材料层同样发生完全动态再结晶,晶粒尺寸小于合金层,随着挤压温度的升高,SiC_(P)的分布更加均匀;不同挤压温度下AZ91-(SiC_(P)/AZ91)复合板合金层与复合材料层界面均未出现明显的分层以及开裂现象;AZ91-(SiC_(P)/AZ91)复合板的室温力学强度位于AZ91合金与SiC_(P)/AZ91复合材料之间,SiC_(P)/AZ91层中SiC_(P)与基体界面脱粘是导致复合板材失效的主要原因。     

AZ91D镁合金在NaHCO_3薄液膜下的腐蚀行为

镁合金大气腐蚀的研究十分重要,而目前有关侵蚀性离子HCO_3~-在薄液膜下对镁合金腐蚀行为的研究报道较少。通过阴极极化曲线和电化学阻抗谱研究了AZ91D镁合金在NaHCO_3薄液膜下的腐蚀行为,详细讨论了液膜厚度、NaHCO_3浓度和时间等参数的影响,并用扫描电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)进行了表征。结果表明:随着液膜厚度的降低,阴极和阳极过程均受到限制,AZ91D镁合金腐蚀速率变小;NaHCO_3浓度增加会加剧AZ91D在薄液膜下的腐蚀;浸泡24.0 h后,本体溶液中腐蚀表现为均匀腐蚀,主要腐蚀产物为MgCO_3和Al_2O_3,而薄液膜下则表现为局部腐蚀,主要腐蚀产物为MgCO_3,Al_2O_3,MgCO_3·2H_2O和Mg_5(CO_3)_4(OH)_2·5H_2O。     

The Dry Sliding Wear Behavior of Interpenetrating Titanium Trialuminide/Aluminium Composites

Owing to the brittle reinforced phase are introduced into ductile matrix phase, metal–intermetallic interpenetrating composites exhibit various types of wear mechanism such as adhesive, abrasive, and fatigue wear. In present work, the wear model has been proposed according to the mixing rule. Many factors such as special topology structure characteristic of reinforcement and elastic module were discussed in this model. The model based on the maximal and minimal hypothesis posts the mathematic relation among volume content of reinforcement, elastic module and wear rate. Increase in the volume fraction of reinforcement leads to improvement in the wear resistance. Unlike the Khruschov model and Zum-Gahr model, the proposed model was no longer follow linear rule. One kind of Al₃Ti/Al composite with different volume content was fabricated and many wear test data were obtained to validate the correctness and universality of the model.     

Analyses on Ignition—Proof Mechanics of AZ91D Alloy Added with Ce

Theoretical analysis on ignition-proof of AZ91D alloy added with Ce was studied.The effect of Ce on burning temperature was investigated.The burning temperature increases with increasing Ce by insulation work at different temperatures.The influence of Ce on maximum insulation work time was also studied.The maximum insulation work time increases with increasing Ce and decreases with the melting temperature .There is a tendency for Ce to concentrate on the surface of melting AZ91D alloy.Ce will react with MgO and O2 .The resultant will fill the cavity of MgO film to form multifilm.So the density of surface film of liquid Mg will increase to prevent burning.     

压铸态AZ91D镁合金搅拌摩擦焊接头微观组织研究

采用搅拌摩擦焊工艺对4mm厚的压铸态AZ91D镁合金进行对接工艺实验,搅拌头旋转速率1500r/min,焊接速率120mm/min;使用光学显微镜和扫描电镜对焊接接头微观组织进行了研究。结果表明:焊缝外观成形美观,但内部存在贯穿型隧道状孔洞缺陷;焊核区为典型的变形-再结晶组织,为细小、均匀的等轴晶;机械-热影响区为变形-部分再结晶组织,热影响区组织形貌与母材相近但伴有轻微的长大现象;焊核区与机械-热影响区的过渡具有以下特征:在前进侧呈现"突变"特征,在后退侧呈现"渐变"特征。     

AZ91D镁合金托弹板半固态触变模锻研究

为了掌握半固态触变模锻中工艺参数对成形零件的微观组织和力学性能的影响规律,借助拉伸试验机和金相显微镜对AZ91D镁合金托弹板的半固态触变模锻过程进行了研究.AZ91D镁合金半固态坯料分别采用传统SIMA法和新SIMA法制备.结果表明:压力对托弹板零件的充型过程有很大影响,当压力为500 kN,托弹板零件充型不满;当压力为2000 kN,托弹板零件充型良好.坯料加热温度和保温时间对托弹板零件的力学性能有一定影响.当压力为2000 kN,模具预热温度为450 ℃,坯料在545 ℃保温20 min时,新SIMA法制备的半固态坯半固态触变模锻成形的托弹板零件获得最佳的力学性能.与传统SIMA法相比,新SIMA法制备的半固态坯成形的托弹板零件的室温力学性能和100℃的高温力学性有很大提高.     

Die-Casting Parameter Sizing for AZ91D in Notebook Computer Base Shell

This study investigates die-casting process parameter optimization for magnesium alloy AZ91D. The Taguchi experimental approach with the orthogonal array was employed. Furthermore, analysis of variance (ANOVA) was applied to find the parameters, which most influence the AZ91D die-casting process in the base shell of notebook computers. Finally, the mechanical properties such as stress, elongation, and hardness were investigated, and the abruption surfaces of after tensile test were identified from scanning electron micrographs (SEM). A low fusion slurry velocity reduces both hardness and stress, and increases the number of pinholes on the cross surface.     

电磁搅拌对半固态AZ91D镁合金组织的影响

研究了电磁搅拌参数对连续冷却条件下AZ91D镁合金组织的影响.结果表明:当电磁搅拌的频率达到或高于50 Hz时,半固态AZ91D镁合金浆料或坯料组织中的球状初生固相越来越多,越来越圆整;在电磁搅拌频率为200 Hz和冷却速率较低的条件下,搅拌的功率越大,半固态AZ91D镁合金组织中的球状初生固相越多,晶粒也越细小.在电磁搅拌条件下,AZ91D镁合金熔体的激烈流动导致较为均匀的温度场和溶质场、更加剧烈的温度起伏,促进了半固态AZ91D镁合金球状组织的形成.半固态重熔加热使半固态AZ91D镁合金坯料初生固相的形态发生进一步的球化.     

Improvement on the Corrosion Resistance of AZ91D Magnesium Alloy by Aluminum Diffusion Coating

By combination of magnetron sputtering deposition and vacuum annealing, an aluminum diffusion coating was prepared on the substrate of AZ91D alloy to improve its corrosion resistance. The microstructure and composition of the diffusion coating was investigated by scanning electron microscopy and X-ray diffraction. The diffusion coating was mainly comprised of β phase-Al12Mg17. The continuous immersion test in 3.5 wt pct neutral NaCl solution indicated that the specimen with diffusion coating had better corrosion resistance compared with the bare AZ91D alloy specimen. The potentiodynamic polarization measurement indicated that the diffusion coating could function as an effectively protective layer to reduce the corrosion rate of AZ91D alloy when exposed to 3.5 wt pct NaCl solution.     

Energy-storage Welding Connection Characteristics of Rapid Solidification AZ91D Mg Alloy Ribbons

Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and performance of the connection joints are analyzed and studied. The research results indicate that energy-storage welding is able to realize the spot welding connection of AZ9ID Mg alloy ribbons. The welding nugget consists of developed α-Mg equiaxed grains with the sizes of 1.2-2.7 μm and intergranular distributed β-Mg17Al12 compounds. The thickness of bond zone is about 4 μm and the solidification microstructure is characterized by the fine equiaxed grains with the sizes of 0.8-1.2μm and grain boundary has become coarsening. The columnar crystal in HAZ also becomes slightly coarsening and the grain boundary has broadened, however, there is no obvious change in its primitive morphology and crystallographic direction. When welding energy is about 2.0 J, the welding joints with higher shear str     

Effect of Holding Time on Thixotropic Fluidity of Semi-solid AZ91D Magnesium Alloy

To investigate the thixotropic fluidities, microstructures and mechanical properties of semi-solid AZ91D magnesium alloy during reheating, a self-made die set with channels of different sizes were used. The results show that critical forming forces and maximal forming forces could be obtained and related to the holding times in the semi-solid forming process. In the holding time of 0-2700 s, with increasing the holding time, maximal forming force decreased sharply and critical forming force decreased slowly. In the whole thixotropic flowing process, the filling-in was steady and the surface fineness was good. The forming force increased when the slurry changed the flowing direction or flowed from the big-diameter chamber to the small-diameter one. The tensile strength and elongation to failure of the sample after holding time for 2700 s, compared to as-cast sample, are increased by approximately 42.7% and 180%, respectively, and the fractured surfaces presented dimple-like pattern.