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1.
Methane (CH4) emission rates were recorded automatically using the closed chamber technique in major rice-growing areas of Southeast Asia. The three experimental sites covered different ecosystems of wetland rice--irrigated, rainfed, and deepwater rice--using only mineral fertilizers (for this comparison). In Jakenan (Indonesia), the local water regime in rainfed rice encompassed a gradual increase (wet season) and a gradual decrease (dry season) in floodwater levels. Emission rates accumulated to 52 and 91 kg CH4 ha–1 season–1 corresponding to approximately 40% of emissions from irrigated rice in each season. Distinct drainage periods within the season can drastically reduce CH4 emissions to less than 30 kg CH4 ha–1 season–1 as shown in Los Baños (Philippines). The reduction effect of this water regime as compared with irrigated rice varied from 20% to 80% from season to season. Methane fluxes from deepwater rice in Prachinburi (Thailand) were lower than from irrigated rice but accumulated to equally high seasonal values, i.e., about 99 kg CH4 ha–1 season–1, due to longer seasons and assured periods of flooding. Rice ecosystems with continuous flooding were characterized by anaerobic conditions in the soil. These conditions commonly found in irrigated and deepwater rice favored CH4 emissions. Temporary aeration of flooded rice soils, which is generic in rainfed rice, reduced emission rates due to low CH4 production and high CH4 oxidation. Based on these findings and the global distribution of rice area, irrigated rice accounts globally for 70–80% of CH4 from the global rice area. Rainfed rice (about 15%) and deepwater rice (about 10%) have much lower shares. In turn, irrigated rice represents the most promising target for mitigation strategies. Proper water management could reduce CH4 emission without affecting yields.  相似文献   

2.
Methane (CH4) emissions were measured with an automated system in Central Luzon, the major rice producing area of the Philippines. Emission records covered nine consecutive seasons from 1994 to 1998 and showed a distinct seasonal pattern: an early flush of CH4 before transplanting, an increasing trend in emission rates reaching maximum toward grain ripening, and a second flush after water is withdrawn prior to harvesting. The local practice of crop management, which consists of continuous flooding and urea application, resulted in 79–184 mg CH4 m–2 d–1 in the dry season (DS) and 269–503 mg CH4 m–2 d–1 in the wet season (WS). The higher emission in the WS may be attributed to more labile carbon accumulation during the dry fallow period before the WS cropping as shown by higher % organic C. Incorporation of sulfate into the soil reduced CH4 emission rates. The use of ammonium sulfate as N fertilizer in place of urea resulted in a 25–36% reduction in CH4 emissions. Phosphogypsum reduced CH4 emissions by 72% when applied in combination with urea fertilizer. Midseason drainage reduced CH4 emission by 43%, which can be explained by the influx of oxygen into the soil. The practice of direct seeding instead of transplanting resulted in a 16–54% reduction in CH4 emission, but the mechanisms for the reducing effect are not clear. Addition of rice straw compost increased CH4 emission by only 23–30% as compared with the 162–250% increase in emissions with the use of fresh rice straw. Chicken manure combined with urea did not increase CH4 emission. Fresh rice straw has wider C/N (25 to 45) while rice straw compost has C/N = 6 to 10 and chicken manure has C/N = 5 to 8. Modifications in inorganic and organic fertilizer management and water regime did not adversely affect grain yield and are therefore potential mitigation options. Direct seeding has a lower yield potential than transplanting but is getting increasingly popular among farmers due to labor savings. Combined with a package of technologies, CH4 emission can best be reduced by (1) the practice of midseason drainage instead of continuous flooding, (2) the use of sulfate-containing fertilizers such as ammonium sulfate and phosphogypsum combined with urea; (3) direct seeding crop establishment; and (4) use of low C/N organic fertilizer such as chicken manure and rice straw compost.  相似文献   

3.
Methane Emission from Rice Fields at Cuttack, India   总被引:1,自引:0,他引:1  
Methane (CH4) emission from rice fields at Cuttack (State of Orissa, eastern India) has been recorded using an automatic measurement system (closed chamber method) from 1995–1998. Experiments were laid out to test the impact of water regime, organic amendment, inorganic amendment and rice cultivars. Organic amendments in conjunction with chemical N (urea) effected higher CH4 flux over that of chemical N alone. Application of Sesbania, Azolla and compost resulted in 132, 65 and 68 kg CH4 ha–1 in the wet season of 1996 when pure urea application resulted in 42 kg CH4 ha–1. Intermittent irrigation reduced emissions by 15% as compared to continuous flooding in the dry season of 1996. In the wet season of 1995, four cultivars were tested under rainfed conditions resulting in a range of emissions from 20 to 44 kg CH4 ha–1. Application of nitrification inhibitor dicyandiamide (DCD) inhibited while Nimin stimulated CH4 flux from flooded rice compared to that of urea N alone. Wide variation in CH4 production and oxidation potentials was observed in rice soils tested. Methane oxidation decreased with soil depth, fertilizer-N and nitrification inhibitors while organic amendment stimulated it. The results indicate that CH4 emission from the representative rainfed ecosystem at the experimental site averaged to 32 kg CH4 ha–1 yr–1.  相似文献   

4.
The Interregional Research Program on Methane Emissions from Rice Fields established a network of eight measuring stations in five Asian countries. These stations covered different environments and encompassed varying practices in crop management. All stations were equipped with a closed chamber system designed for frequent sampling and long-term measurements of emission rates. Even under identical treatment--e.g., continuous flooding and no organic fertilizers--average emission rates varied from 15 to 200 kg CH4 ha–1 season–1. Low temperatures limited CH4 emissions in temperate and subtropical stations such as northern China and northern India. Differences observed under given climates, (e.g., within the tropics) indicated the importance of soil properties in regulating the CH4 emission potential. However, local variations in crop management superseded the impact of soil- and climate-related factors. This resulted in uniformly high emission rates of about 300 kg CH4 ha–1 season–1 for the irrigated rice stations in the Philippines (Maligaya) and China (Beijing and Hangzhou). The station in northern India (Delhi) was characterized by exceptionally low emission rates of less than 20 kg CH4 ha–1 season–1 under local practice. These findings also suggest opportunities for reducing CH4 emission through a deliberate modification of cultural practice for most irrigated rice fields.  相似文献   

5.
Methane (CH4) emissions from rice fields were determined using automated measurement systems in China, India, Indonesia, Thailand, and the Philippines. Mitigation options were assessed separately for different baseline practices of irrigated rice, rainfed, and deepwater rice. Irrigated rice is the largest source of CH4 and also offers the most options to modify crop management for reducing these emissions. Optimizing irrigation patterns by additional drainage periods in the field or an early timing of midseason drainage accounted for 7–80% of CH4 emissions of the respective baseline practice. In baseline practices with high organic amendments, use of compost (58–63%), biogas residues (10–16%), and direct wet seeding (16–22%) should be considered mitigation options. In baseline practices using prilled urea as sole N source, use of ammonium sulfate could reduce CH4 emission by 10–67%. In all rice ecosystems, CH4 emissions can be reduced by fallow incorporation (11%) and mulching (11%) of rice straw as well as addition of phosphogypsum (9–73%). However, in rainfed and deepwater rice, mitigation options are very limited in both number and potential gains. The assessment of these crop management options includes their total factor productivity and possible adverse effects. Due to higher nitrous oxide (N2O) emissions, changes in water regime are only recommended for rice systems with high baseline emissions of CH4. Key objectives of future research are identifying and characterizing high-emitting rice systems, developing site-specific technology packages, ascertaining synergies with productivity, and accounting for N2O emissions.  相似文献   

6.
Methane (CH4) emissions were determined from 1993 to 1998 using an automated closed chamber technique in irrigated and rainfed rice. In Jakenan (Central Java), the two consecutive crops encompass a gradient from low to heavy rainfall (wet season crop) and from heavy to low rainfall (dry season crop), respectively. Rainfed rice was characterized by very low emission at the onset of the wet season and the end of the dry season. Persistent flooding in irrigated fields resulted in relatively high emission rates throughout the two seasons. Average emission in rainfed rice varied between 19 and 123 mg CH4 m–2 d–1, whereas averages in irrigated rice ranged from 71 to 217 mg CH4 m–2 d–1. The impact of organic manure was relatively small in rainfed rice. In the wet season, farmyard manure (FYM) was completely decomposed before CH4 emission was initiated; rice straw resulted in 40% increase in emission rates during this cropping season. In the dry season, intensive flooding in the early stage promoted high emissions from organically fertilized plots; seasonal emissions of FYM and rice straw increased by 72% and 37%, respectively, as compared with mineral fertilizer. Four different rice cultivars were tested in irrigated rice. Average emission rates differed from season to season, but the total emissions showed a consistent ranking in wet and dry season, depending on season length. The early-maturing Dodokan had the lowest emissions (101 and 52 kg CH4 ha–1) and the late-maturing Cisadane had the highest emissions (142 and 116 kg CH4 ha–1). The high-yielding varieties IR64 and Memberamo had moderately high emission rates. These findings provide important clues for developing specific mitigation strategies for irrigated and rainfed rice.  相似文献   

7.
Methane (CH4) emissions from irrigated rice fields were measured using an automatic sampling-measuring system with a closed chamber method in 1995–98. Average emission rates ranged from 11 to 364 mg m–2 d–1 depending on season, water regime, and fertilizer application. Crop management typical for this region (i.e., midseason drainage and organic/mineral fertilizer application) resulted in emission of 279 and 139 mg CH4 m–2 d–1 in 1995 and 1997, respectively. This roughly corresponds to emissions observed in other rice-growing areas of China. Emissions were very intense during the tillering stage, which accounted for 85% of total annual emission, but these were suppressed by low temperature in the late stage of the season. The local irrigation practice of drying at mid-season reduced emission rates by 23%, as compared with continuous flooding. Further reduction of CH4 emissions could be attained by (1) alternate flooding/drying, (2) shifting the drainage period to an earlier stage, or (3) splitting drainage into two phases (of which one is in an earlier stage). Emission rates were extremely sensitive to organic amendments: seasonal emissions from fields treated with pig manure were 15–35 times higher than those treated with ammonium sulfate in the corresponding season. On the basis of identical carbon inputs, CH4 emission potential varied among organic amendments. Rice straw had higher emissions than cattle manure but lower emissions than pig manure. Use of cultivar Zhongzhuo (modern japonica) reduced CH4 emission by 56% and 50%, in 1995 and 1997, respectively, as compared with Jingyou (japonica hybrid) and Zhonghua (tall japonica). The results give evidence that CH4 emissions from rice fields in northern China can be reduced by a package of crop management options without affecting yields.  相似文献   

8.
The Effects of Cultural Practices on Methane Emission from Rice Fields   总被引:1,自引:0,他引:1  
A field experiment was conducted in a clayey soil to determine the effects of cultural practices on methane (CH4) emissions from rice fields. The factors evaluated were a) direct seeding on dry vs wet soil, b) age of transplanted seedlings (8 d old and 30 d old), and c) fall vs spring plowing. Methane emissions were measured weekly throughout the rice-growing season using a closed static chamber technique. Transplanted 8-d-old seedlings showed the highest emission of 42.4 g CH4 m–2 season–1, followed by transplanted 30-d-seedlings (40.3 g CH4 m–2 season–1), and direct seeding on wet soil (37.1 g CH4 m–2 season–1). Direct seeding on dry soil registered the least emission of 26.9 g CH4 m–2 season–1. Thus transplanting 30-d-old seedlings, direct seeding on wet soil, and direct seeding on dry soil reduced CH4 emission by 5%, 13%, and 37%, respectively, when compared with transplanting 8-d-old seedlings. Methane emission under spring plowing was 42.0 g CH4 m–2 season–1 and that under fall plowing was 31.3 g CH4 m–2 seasons–1. The 26% lower emission in the field plowed in spring was caused by degradation of organic matter over the winter.  相似文献   

9.
Two atmospheric diffusion models, the box model ad the ATDL (Atmospheric Turbulent and Diffusion Laboratory) model, were used to calculate regional methane (CH4) emissions of rice fields in the Beijing area. Compared with conventional closed chamber measurements, the box model overestimated CH4 emission because of meteorological conditions--the ground inverse layer was not favorable for the application of the model during the rice-growing season. The ATDL model, on the other hand, handled this unfavorable meteorological condition and gave reasonable CH4 emission estimates (about 6.1–8.5 mg m–2 h–1) close to conventional measurements (about 0.3–14.3 mg m–2 h–1) in June, a period generally characterized by significant CH4 emission from rice fields. In September, CH4 emission as measured with closed chambers was negligible (about 0–0.3 mg m–2 h–1), but the ATDL model still calculated it to be about 2.8–5.3 mg m–2 h–1, albeit at a low level and considerably below the June emission level. This discrepancy cannot be explained at present and needs further stuy. Most likely causes are measurement artifacts and/or the presence of minor local CH4 sources (ditches, field depressions) in the study area. The application of atmospheric diffusion models for regional CH4 emission estimation depends greatly on meteorological conditions. Moreover, the models tend to give much more reliable results during periods of rather high CH4 emission. This coincides with the time that such regional CH4 emission estimates are most valuable. The atmospheric diffusion models complement the closed chamber method by providing integrated CH4 emission estimates from 1–100-km2 rice areas. Detailed information about agricultural management of rice fields and other potential CH4 sources within the study region are necessary to better understand the integrated regional emission estimates.  相似文献   

10.
Methane Emissions from Irrigated Rice Fields in Northern India (New Delhi)   总被引:1,自引:0,他引:1  
Methane (CH4) emission fluxes from rice fields as affected by water regime, organic amendment, and rice cultivar were measured at the Indian Agricultural Research Institute, New Delhi, using manual and automatic sampling techniques of the closed chamber method. Measurements were conducted during four consecutive cropping seasons (July to October) from 1994 to 1997. Emission rates were very low (between 16 and 40 kg CH4 m–2 season–1) when the field was flooded permanently. These low emissions were indirectly caused by the high percolation rates of the soil; frequent water replenishment resulted in constant inflow of oxygen in the soil. The local practice of intermittent flooding, which encompasses short periods without standing water in the field, further reduced emission rates. Over the course of four seasons, the total CH4 emission from intermittently irrigated fields was found to be 22% lower as compared with continuous flooding. The CH4 flux was invariably affected by rice cultivar. The experiments conducted during 1995 with one cultivar developed by IRRI (IR72) and two local cultivars (Pusa 169 and Pusa Basmati) showed that the average CH4 flux from the intermittently irrigated plots without any organic amendment ranged between 10.2 and 14.2 mg m–2 d–1. The impact of organic manure was tested in 1996 and 1997 with varieties IR72 and Pusa 169. Application of organic manure (FYM + wheat straw) in combination with urea (1:1 N basis) enhanced CH4 emission by 12–20% as compared with fields treated with urea only. The site in New Delhi represents one example of very low CH4 emissions from rice fields. Emissions from other sites in northern India may be higher than those in New Delhi, but they are still lower than in other rice-growing regions in India. The practice of intermittent irrigation--in combination with low organic inputs--is commonly found in northern India and will virtually impede further mitigation of CH4 emissions in significant quantities. In turn, the results of this study may provide clues to reduce emissions in other parts of India with higher baseline emissions.  相似文献   

11.
Methane (CH4) emissions from rice fields were monitored in Hangzhou, China, from 1995 to 1998 by an automatic measurement system based on the "closed chamber technique." The impacts of water management, organic inputs, and cultivars on CH4 emission were evaluated. Under the local crop management system, seasonal emissions ranging from 53 to 557 kg CH4 ha–1 were observed with an average value of 182 kg CH4 ha–1. Methane emission patterns differed among rice seasons and were generally governed by temperature changes. Emissions showed an increasing trend in early rice and a decreasing trend in late rice. In a single rice field, CH4 emissions increased during the first half of the growing period and decreased during the second half. Drainage was a major modifier of seasonal CH4 emission pattern. The local practice of midseason drainage reduced CH4 emissions by 44% as compared with continuous flooding; CH4 emissions could further be reduced by intermittent irrigation, yielding a 30% reduction as compared with midseason drainage. The incorporation of organic amendments promoted CH4 emission, but the amount of emission varied with the type of organic material and application method. Methane emission from fields where biogas residue was applied was 10–16% lower than those given the same quantity (based on N content) of pig manure. Rice straw applied before the winter fallow period reduced CH4 emission by 11% as compared with that obtained from fields to which the same amount of rice straw was applied during field preparation. Broadcasting of straw instead of incorporation into the soil showed less emission (by 12%). Cultivar selection influenced CH4 emission, but the differences were smaller than those among organic treatments and water regimes. Modifications in water regime and organic inputs were identified as promising mitigation options in southeast China.  相似文献   

12.
Methane (CH4) emission from eight cultivars planted under uniform field conditions was measured by the closed static chamber method. Mean daily CH4 emission and seasonally integrated CH4 flux followed similar trends among the different varieties, irrespective of growth duration. The CH4 flux (g CH4 m–2) among the varieties was in the order of Dasanbyeo (36.9) < Ilpumbyeo (42.9) < Gyehwabyeo (47.8) < Daeanbyeo (50.9) < Dongjinbyeo (58.8) < Hwaseongbyeo (59.7) < Odaebyeo (62.9) < Mangeumbyeo (76.0). No significant correlation was observed between CH4 emission factor and root distribution in the 0–5 cm soil profile and dry matter weight in the canopy at heading stage.  相似文献   

13.
Azolla is an aquatic fern that has been used successfully as a dual crop with wetland rice. Rice fields are a major source of atmospheric CH4, which is an important greenhouse gas. In this study, field and laboratory experiments showed that growing Azolla as a dual crop could enhance CH4 emission from rice fields. In pot experimen indications showed that Azolla could mediate CH4 transport from the floodwater of a rice soil into the atmosphere. It was also found that due to the presence of Azolla, chemical soil properties could be developed, stimulating CH4 production and decreasing in situ CH4 removal.  相似文献   

14.
周太炎  杜郢  高山  顿全秀  周春利 《粘接》2010,(11):77-79
介绍了国内外农作物秸秆的主要应用领域及基本情况;综述了我国秸秆资源现状、政府政策法规以及秸秆再利用的深远意义;重点介绍了粘合剂在秸秆发电、固体燃料及胶合板制作中的作用,同时指出了秸秆再利用工业化的关键问题。本实验室使用多种粘合剂做了秸秆粘接探索实验,证明在秸秆粘接、压缩成块,且具有足够应用强度的情况下,粘合剂成本可控制在100元/t以内;同时提出用水性聚氨酯代替“三醛胶”制作胶合板的可能。  相似文献   

15.
A greenhouse pot experiment was carried out to study the effect of land management during the winter crop season on methane (CH4) emissions during the following flooded and rice-growing period. Three land management patterns, including water management, cropping system, and rice straw application time were evaluated. Land management in the winter crop season significantly influenced CH4 fluxes during the following flooded and rice-growing period. Methane flux from plots planted to alfalfa (ALE) in the winter crop season was significantly higher than those obtained with treatments involving winter wheat (WWE) or dry fallow (DFE). Mean CH4 fluxes of treatments ALE, WWE, and DFE were 28.6, 4.7, and 4.1 mg CH4 m–2 h–1 in 1996 and 38.2, 5.6, and 3.2 mg CH4 m–2 h–1 in 1997, respectively. The corresponding values noted with continuously flooded fallow (FFE) treatment were 6.1 and 5.2 times higher than that of the dry fallow treatment in 1996 and 1997, respectively. Applying rice straw just before flooding the soil (DFL) significantly enhanced CH4 flux by 386% in 1996 and by 1,017% in 1997 compared with rice straw application before alfalfa seed sowing (DFE). Land management in the winter crop season also affected temporal variation patterns of CH4 fluxes and soil Eh after flooding. A great deal of CH4 was emitted to the atmosphere during the period from flooding to the early stage of the rice-growing season; and CH4 fluxes were still relatively high in the middle and late stages of the rice-growing period for treatments ALE, DFL, and FFE. However, for treatments DFE and WWE, almost no CH4 emission was observed until the middle stage, and CH4 fluxes in the middle and late stages of the rice-growing period were also very small. Soil Eh of treatments ALE and DFL decreased quickly to a low value suitable for CH4 production. Once Eh below –150 mV was established, the small changes in Eh did not correlate to changes in CH4 emissions. The soil Eh of treatments DFE and WWE did not decrease to a negative value until the middle stage of the rice-growing period, and it correlated significantly with the simultaneously measured CH4 fluxes during the flooded and rice-growing period.  相似文献   

16.
In this paper, we review the process-level studies that the authors have performed in rice fields of Texas since 1989 and the development of a semi-empirical model based on these studies. In this model, it is hypothesized that methanogenic substrates are primarily derived from rice plants ad added organic matter. Rates of methane (CH4) production in flooded rice soils are determined by the availability of methanogenic substrates and the influence of climate, soil, and agronomic factors. Rice plant growth and added carbon control the fraction of CH4 emitted. The amount of CH4 transported from the soil to the atmosphere is determined by the rates of production and the emitted fraction. Model calibration against observations from a single rice-growing season in Texas, USA, without organic amendments and with continuous irrigation demonstrated that the seasonal variation of CH4 emission is regulated by rice biomass and cultivar type. A further validation of the model against measurements from irrigated rice paddy soils in various regions of the world, including Italy, China, Indonesia, Philippines, and the United States, suggests that CH4 emission can be predicted from rice net productivity, cultivar character, soil texture, temperature, and organic matter amendments.  相似文献   

17.
The uncertainty in the methane (CH4) source strength of rice fields is among the highest of all sources in the global CH4 budget. Methods to estimate the source strength of rice fields can be divided into two scaling categories: bottom-up (upscaling) and top-down (downscaling). A brief review of upscaling and downscaling methodologies is presented. The combination of upscaling and downscaling methodologies is proposed as a potential method to reduce the uncertainty in the regional CH4 source strength of rice fields. Some preliminary results based on upscaling and downscaling are presented and the limitations of the approaches are discussed. The first case study focuses on upscaling by using a field-scale model in combination with spatial databases to calculate CH4 emissions for the island of Java. The reliability of upscaling results is limited by the uncertainty in model input parameters such as soil properties and organic carbon management. Because controlling variables such as harvested rice area may change on relatively short time scales, a land use change model (CLUE) was used to quantify the potential land use changes on Java in the period 1994–2010. The predicted changes were evaluated using the CH4 emission model. Temporal scaling by coupling land use change models and emission models is necessary to answer policy-related questions on future greenhouse gas emissions. In a downscaling case study, we investigate if inverse modeling can constrain the emissions from rice fields by testing a standard CH4 from rice scenario and a low CH4 from rice scenario (80 and 30 Tg CH4 yr–1, respectively). The results of this study are not yet conclusive; to obtain fine-resolution CH4 emission estimates over the Southeast Asian continent, the monitoring network atmospheric mixturing ratios need to be extended and located closer to the continental sources.  相似文献   

18.
硫酸钛催化麦秸转化制乙酰丙酸   总被引:2,自引:0,他引:2  
研究了经焙烧的硫酸钛催化剂催化麦秸转化生成乙酰丙酸的反应条件。结果表明,较好的反应条件为:催化剂用量0.3 g,反应温度220 ℃,反应时间15 min,原料粒径(45~50)目。对小麦秸秆进行预处理可提高乙酰丙酸收率。通过实验还发现,麦秆转化生成乙酰丙酸的收率比麦叶高。  相似文献   

19.
王俏 《江苏化工》2004,32(1):37-39
研究了以稻草为原料用水解-氧化-水解法制取草酸的工艺方法。最佳反应条件:硫酸质量分数70%;物料浸泡时间≥3h;m(硝酸):m(稻草)=2.1:1;氧化-水解反应时间5h;反应温度65—70℃。草酸二水合物收率可达75.8%。  相似文献   

20.
硫酸钙晶须作为无机粉体材料,具有优良的力学性能、绿色环保、且价格低廉,是石膏的高附加值产品.本文介绍了硫酸钙晶须表面改性处理的研究现状,并综述了硫酸钙晶须在高分子复合材料、催化剂、造纸、路面沥青、建筑水泥、再生混凝土以及摩擦材料等材料领域中的应用.  相似文献   

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