Hydrogen purge and reactant feeding strategies in self-humidified PEM fuel cell systems

A 6 kW proton exchange membrane fuel cell system, operating in self-humidified conditions, was characterized in two anode operative modes: dead-end and flow through with exhaust recirculation. The anode sub-system was specifically designed in order to adjust the level of recycled anodic stream. The role of anode purge frequency, anode recirculation level and air stoichiometric ratio was analysed in the power range 1–5 kW. The aim of this study was to define management strategies to assure efficient and reliable cell performance during steady-state, warm-up and load variation phases. The results evidenced the combined effect of hydrogen purge, air flow rate impulse, and recycled anodic stream on individual cell performance recovery when unstable working conditions were detected during system start-up and load variations.     

Real-time AC voltage control and power-following of a combined proton exchange membrane fuel cell,and ultracapacitor bank with nonlinear loads

The nonlinear loads create a wide range of current harmonics in the system. Such loads can make distortions on the output voltage profile, influence on the fuel cell (FC) performance, and endanger safe operation of the FC unit. In this paper, new strategies for power-following and AC voltage control have been developed. The proposed system consists of the ultracapacitor (UC) bank and proton exchange membrane fuel cell (PEMFC) supplying nonlinear AC loads. The power tracking strategy is based on the Fourier analysis of total load demand. The Fourier analysis is used as an effective tool to eliminate destructive effect of current harmonics on the PEMFC output current. To supply the nonlinear AC loads under sinusoidal voltage with the fast response, a dynamic model for the inverter control loop is also presented. This model is used to enhance the input reference tracking and reject input/output disturbances. The simulation outcomes confirm the desirable PEMFC performance against nonlinear load disturbances. In addition, the output AC voltage is kept sinusoidal and has low deviations under nonlinear load variations.     

A preliminary study of a six-cell stack with dead-end anode and open-slits cathode

A practical air-breathing stack consisting of six cells was fabricated as a stair configuration for the integrated series connection of proton exchange membrane fuel cells. All the six cathodes of the stack contacting the ambient air through the open slits presented highly efficient (uniform and sufficient) oxygen supply for each cell. Hydrogen was supplied in series and circulated inside the stack to enhance the hydrogen utility and to improve the sufficiency of hydrogen supply to each cell of the stack. Polarization curves of the stack were measured without water-heat management. Gradual change processes of both the cells’ temperature and voltage from the startup to equilibrium were recorded and analyzed. The cells produced the maximum power density of 350 mW/cm² at 650 mA/cm² averagely. The preliminary experimental results show the practicability of the design configuration due to both the high efficient oxygen supply to each cell and the hydrogen circulation inside the stack.     

Experimental investigation on dynamic characteristics of proton exchange membrane fuel cells at subzero temperatures

Cold start and operation of a proton exchange membrane fuel cell (PEMFC) at the cold temperatures are crucial to the commercialization of it in the field of transportation. A 32 cm² two cell stack is prepared to conduct the experiments at subzero temperatures, including cold start processes and cell performance testing, aiming of the characteristics of the cell. The startup study under subfreezing temperatures is conducted by galvanostatic method at various operation conditions, i.e. ambient temperature (−3 and −5 °C), current density and anode stoichiometry. The results show that the voltage evolutions are proportional to the operating current densities under the former two conditions, but the relationship becomes the opposite at the last condition. It is also found that the time constant for the cell to reach steady status is no more than 100 s and highly depends on the startup mode. In addition, the performance of the cell is tested at the temperature of 0 °C and −3 °C. The comparison of pre-humidification and normal operations indicate that the initial water content of membrane affects the cell performance.     

Development of a fast empirical design model for PEM stacks

A simple and fast empirical design model for a 5 kW proton exchange membrane (PEM) stack is presented in this paper. The performance analysis of the PEM stack operating on a membrane humidifying method is made through a series of experiments, including current–voltage–power characteristics, uniformity of cell unit voltages, gas pressure impact and air flux impact. Based on the above analysis, an empirical predicted model for the PEM stack has been developed by the combination of mechanistic and empirical modeling approaches to characterize and predict the voltage–current characteristics without examining in depth all physical/chemical phenomena. The good agreement between the predicted and experimental results covering a range of optimal operating conditions shows that the proposed model provides an accurate representation of the behavior for the PEM stack.     

Optimizing polymer electrolyte membrane thickness to maximize fuel cell vehicle range

Automotive hydrogen polymer electrolyte membrane (PEM) fuel cell systems require periodic purges to remove nitrogen and water from the anode. Purging increases system performance by limiting anode hydrogen dilution, but reduces hydrogen utilization. State of the art fuel cell membrane electrode assemblies utilize thin ionomer membranes in an effort to increase performance and reduce cost. Thinner membranes also increase the required anode purge rates due to the increased transport of inert gases. A model was developed to examine the relationship between membrane thickness and vehicle range which takes into account anode purge rate. The model includes changes in efficiency and hydrogen utilization as a function of PEM thickness for a variety of operating conditions. The model predicts that an optimal membrane thickness which maximizes vehicle range exists, but this thickness is highly dependent on other system conditions. The results of this study can be extended to help optimize stack development and balance of plant design.     

An energy management strategy based on dynamic power factor for fuel cell/battery hybrid locomotive

In order to efficiently absorb more regenerative braking energy which sustains much longer compared with the conventional vehicle, and guarantee the safety of the hybrid system under the actual driving cycle of locomotive, an energy management control based on dynamic factor strategy is proposed for a scale-down locomotive system which consists of proton exchange membrane fuel cell (PEMFC) and battery pack. The proposed strategy which has self-adaption function for different driving cycles aims to achieve the less consumption of hydrogen and higher efficiency of the hybrid system. The experimental results demonstrate that the proposed strategy is able to maintain the charge state of battery (SOC) better than Equivalent Consumption Minimization Strategy (ECMS), and the proposed strategy could keep the change trend of SOC, which the final SOC is closed to the target value regardless of the initial SOC of battery. Moreover, the hydrogen consumption has been reduced by 0.86g and the efficiency of overall system has been raised of 2% at least than ECMS under the actual driving cycle through the proposed strategy. Therefore, the proposed strategy could improve the efficiency of system by diminishing the conversion process of energy outputted by fuel cell.     

Experimental study of proton exchange membrane fuel cells using Nafion 212 and Nafion 211 for portable application at ambient pressure and temperature conditions

Low humidification, large air stoichiometry, dry hydrogen and low operational temperature makes open-cathode proton exchange membrane fuel cells (PEMFCs) with forced-air convection, which is designed for portable applications, quite different from that used in automobile vehicles. In this paper, PEMFCs humidified at 30 °C using Nafion 212 and Nafion 211 as electrolytes were systematically investigated under simulating conditions. These conditions included air stoichiometry from 3 to 100 and cell temperature from 30 °C to 60 °C. The results indicate that the thinner membrane (Nafion 211) had better performance and more stable voltage output under air dual-function configuration than Nafion 212. Furthermore, the dynamic response of the voltage with cell temperature was also studied during rising and cooling procedure between 30 °C and 60 °C.     

Dynamic modeling of a proton exchange membrane fuel cell system with a shell-and-tube gas-to-gas membrane humidifier

The proton exchange membrane fuel cell (PEMFC) system with a shell-and-tube gas-to-gas membrane humidifier is considered to be a promising PEMFC system because of its energy-efficient operation. However, because the relative humidity of the dry air flowing into the stack depends on the stack exhaust air, this system can be unstable during transients. To investigate the dynamic behavior of the PEMFC system, a system model composed of a lumped dynamic model of an air blower, a two-dimensional dynamic model of a shell-and-tube gas-to-gas membrane humidifier, and a one-dimensional dynamic model of a PEMFC system is developed. Because the water management during transient of the PEMFC system is one of the key challenges, the system model is simulated at the step change of current. The variations in the PEMFC system characteristics are captured. To confirm the superiority of the system model, it is compared with the PEMFC component model during transients.     

Electrolyzer-fuel cell combination for grid peak load management in a geothermal power plant: Power to hydrogen and hydrogen to power conversion

This study provides comprehensive energy, exergy, and economic evaluations and optimizations of a novel integrated fuel cell/geothermal-based energy system simultaneously generating cooling and electricity. The system is empowered by geothermal energy and the electricity is mainly produced by a dual organic cycle. A proton exchange membrane electrolyzer is employed to generate the oxygen and hydrogen consumed by a proton exchange membrane fuel cell utilized to support the network during consumption peak periods. This fuel cell can be also used for supplying the electricity demanded by the network to satisfy the loads at different times. All the simulations are conducted using Engineering Equation Solver software. To optimize the system, a multi-objective optimization method based on genetic algorithm is applied in MATLAB software. The objective functions are minimized cost rate and maximized exergy efficiency. The optimum values of exergy efficiency and cost rate are found to be 62.19% and 18.55$/h, respectively. Additionally, the results reveal that combining a fuel cell and an electrolyzer can be an effective solution when it comes to electricity consumption management during peak load and low load periods.     

Development of a proton exchange membrane fuel cell cogeneration system

A proton exchange membrane fuel cell (PEMFC) cogeneration system that provides high-quality electricity and hot water has been developed. A specially designed thermal management system together with a microcontroller embedded with appropriate control algorithm is integrated into a PEM fuel cell system. The thermal management system does not only control the fuel cell operation temperature but also recover the heat dissipated by FC stack. The dynamic behaviors of thermal and electrical characteristics are presented to verify the stability of the fuel cell cogeneration system. In addition, the reliability of the fuel cell cogeneration system is proved by one-day demonstration that deals with the daily power demand in a typical family. Finally, the effects of external loads on the efficiencies of the fuel cell cogeneration system are examined. Results reveal that the maximum system efficiency was as high as 81% when combining heat and power.     

A novel approach on the determination of the minimal operating efficiency of a PEM fuel cell

In this article, a novel mathematical approach is proposed to determine the minimal proton exchange membrane fuel cell efficiency below which it is not recommended to operate the fuel cell. The objective of this proposal is to minimize the annual fuel cost and the electricity cost of a proton exchange membrane (PEM) fuel cell since both terms are efficiency dependent. A new concept developed in this article might be used as a valuable mathematical tool to determine the minimal efficiency required to operate a fuel cell in a reasonable fashion in order to make the fuel cell system technically and economically feasible. Two dimensionless mathematical criteria J₁ and J₂ were proposed for the annual fuel cost and electricity cost, respectively. A minimum fuel cell efficiency of was obtained with J₁ and J₂ values of 2.7 and 0.026, respectively.     

An air-cooled proton exchange membrane fuel cell with combined oxidant and coolant flow

Combining the oxidant and coolant flow in an air-cooled proton exchange membrane fuel cell can significantly simplify the fuel cell design. In this paper, an air-cooled PEM fuel cell stack with an open cathode flow field, which supplied the oxidant and removed the heat produced in the fuel cell, was fabricated and tested. The influence of different operating parameters on cell voltage performance and the overall cell ohmic resistance, such as cell temperature and airflow rate, was investigated. The cell temperature and the temperature difference between the cell and the hydrogen humidifier were shown to serve important roles in reducing the fuel cell ohmic resistance. The test results also showed a noteworthy temperature gradient between each cell of a 5-cell stack. A hydrophilic treatment of the cathode flow field channels was demonstrated to be an effective way to mitigate water management issues caused at elevated operating temperatures.     

An overview: Current progress on hydrogen fuel cell vehicles

The harmful consequences of pollutants emitted by conventional fuel cars have prompted vehicle manufacturers to shift towards alternative energy sources. Currently, fuel cells (FCs) are commonly regarded as highly efficient and non-polluting power sources capable of delivering far greater energy densities and energy efficiency than conventional technologies. Proton exchange membrane fuel cells (PEMFC) are viewed as promising in transportation sectors because of their ability to start at cold temperatures and minimal emissions. PEMFC is an electrochemical device that converts hydrogen and oxidants into electricity, water, and heat at various temperatures. The pros and cons of the technology are discussed in this article. Various fuel cell types and their applications in the portable, automobile, and stationary sectors are discussed. Additionally, recent issues associated with existing fuel cell technology in the automobile sector are reviewed.     

A Nafion-based self-humidifying membrane with ordered dispersed Pt layer

A double-layer Nafion-based membrane consisting of a pure Nafion layer and an ordered dispersed Pt particles layer was investigated. The Pt particles were dispersed under the anode graphite ribs, which provide the sites for the recombination of the permeating _H2${\mathrm{H}}_2$ and _O2${\mathrm{O}}_2$ into water. The electrochemical performances of the ordered Pt particles dispersed membrane in proton exchange membrane fuel cell (PEMFC) were studied and compared with those of the common Pt particles dispersed membrane and the pure Nafion membrane. The results indicate that the ordered Pt dispersed membrane reduces the amount of Pt dosage than the common Pt dispersed membrane and improves the performance of PEMFC operated under dry conditions than the pure Nafion membrane as well.     

Multivariable robust PID control for a PEMFC system

This paper proposes robust proportional-integral-derivative (PID) control for a proton exchange membrane fuel cell (PEMFC) system. We model a PEMFC as a multivariable system, and apply identification techniques to obtain the system’s transfer function matrices, where system variations and disturbances are regarded as uncertainties. Because robust control can cope with system uncertainties and disturbances, it has been successfully applied to improve the stability, performance, and efficiency of PEMFC systems in previous studies. However, the resulting robust controllers might be too complicated for hardware implementation. On the other hand, PID control has been widely applicable to engineering practices because of its simple structure, but it lacks stability analysis for systems with uncertainties. Therefore, by combining the merits of robust control and PID control, we design robust PID controllers for the PEMFC system. Based on evaluation of stability, performance, and efficiencies, the proposed robust PID controllers are shown to be effective.