The effect of support morphology on the reaction of oxidative dehydrogenation of ethane to ethylene at short contact times

The oxidative dehydrogenation of ethane is carried out in short contact time reactors over Pt and LaMnO₃ based catalysts supported on a large number of different ceramic substrates (45, 60 and 80 ppi foam monoliths and 200, 400, 600, 900 and 1200 cpsi honeycomb monoliths). Experimental results, obtained under the same conditions at varying the C₂H₆/O₂ ratio, showed that the highest performance in terms of ethylene selectivity and yield is always attained on LaMnO₃ catalysts. Furthermore, the results are significantly influenced by the morphology and cell density of the support, with 45 and 60 ppi foams and 400 and 600 cpsi honeycombs giving the best performance. The experimental results are explained by means of geometrical and fluid dynamic considerations on the support, and by means of a 2D mathematical model, which clearly indicates an optimal intermediate cell density for maximising ethylene selectivity and yield.     

Use of zeolite-rich rocks and waste materials for the production of structural lightweight concretes

This paper aims at testing the use of mixtures constituted by natural zeolitized products and SiC-bearing industrial wastes (sludge deriving from polishing of porcelain stoneware tiles, hereafter DPM) for the production of lightweight expanded aggregates as constituents of structural and/or thermo-insulating lightweight concretes. Two commercial products have been used as zeolite natural source: Cab70 (Yellow facies of Campanian Ignimbrite) and IZclino (Turkish clinoptilolite-rich epiclastite). Different amounts of a calcareous material (Pozzano limestones — hereafter CP) from the Sorrento peninsula (Naples — Italy) were also added to a Cab70–DPM mixture. All raw materials were characterized by means of mineralogical (XRPD) and chemical (XRF) analyses. All the products and mixtures were tested from a technological point of view by means of fusibility and firing tests in order to evaluate the expanding properties. It was evidenced that the expansion of the mixture was deeply depending on the occurrence of SiC in the industrial waste. The addition of CP (10 wt.%) to the mixtures accounts for an even increased expansion, though this is accompanied by a worsening of the mechanical features of the material.These results along with literature data allowed to select 3 mixtures (70% Cab70–30% DPM, 70% IZclino–30% DPM, 60% Cab70–30% DPM–10% CP) and each of them was used for the preparation of 5 l of lightweight aggregates afterward employed for the manufacture of lightweight concretes. It was remarked that natural zeolitized materials mixed with DPM (30 wt.%) can provide lightweight aggregates with densities ranging between 0.8 and 1.0 g/cm³ suitable for the preparation of structural lightweight concretes. The addition to the mixture of CP (10 wt.%) produces less dense aggregates (0.6–0.7 g/cm³) potentially useful for the manufacture of thermo insulating lightweight concretes.     

D-Index: Distance Searching Index for Metric Data Sets

In order to speedup retrieval in large collections of data, index structures partition the data into subsets so that query requests can be evaluated without examining the entire collection. As the complexity of modern data types grows, metric spaces have become a popular paradigm for similarity retrieval. We propose a new index structure, called D-Index, that combines a novel clustering technique and the pivot-based distance searching strategy to speed up execution of similarity range and nearest neighbor queries for large files with objects stored in disk memories. We have qualitatively analyzed D-Index and verified its properties on actual implementation. We have also compared D-Index with other index structures and demonstrated its superiority on several real-life data sets. Contrary to tree organizations, the D-Index structure is suitable for dynamic environments with a high rate of delete/insert operations.     

Securing Threshold Cryptosystems against Chosen Ciphertext Attack

For the most compelling applications of threshold cryptosystems, security against chosen cipher text attack is a requirement. However, prior to the results presented here, there appeared to be no practical threshold cryptosystems in the literature that were provably chosen ciphertext secure, even in the idealized random oracle model. The contribution of this paper is to present two very practical threshold cryptosystems, and to prove that they are secure against chosen ciphertext attack in the random oracle model. Not only are these protocols computationally very efficient, but they are also non-interactive, which means they can be easily run over an asynchronous communication network. Received November 2000 and revised September 2001 Online publication 11 March 2002     

MQAM Performance over Nakagami channels with diversity

This paper presents the error probability performance for M-ary quadrature amplitude modulation (mqam) signalling with L-branch diversity receiver over Nakagami fading channel. Both maximal ratio combining (mrc) and selection diversity combining (sdc) techniques are considered with reference to predetection diversity architecture, in the case of integer values of fading severity and independent fading. Average symbol error probability is analitycally derived in terms of finite sum of Gauss hypergeometric functions for balanced branches with identical values of the fading severity. In particular, performance analysis of sdc for mqam in Nakagami fading is new since it has not been presented in any previous work. Numerical results are presented allowing to identify those operational conditions in which diversity techniques can aid successfully in counteracting the effects of slow and nonselective short-term fading.     

使简单欧姆计具备千兆欧量程的积分器

德州仪器公司(TI)的IVC102精密积分器有高质量的内部电容.图1的电路可以用来测量非常高的Rx电阻值.一只精密差分放大器(TI的INA105)为Rx施加一个基准电压.积分期间,在IVC12的输出端产生一个负电压斜坡Vo.两只LM311将Vo的振幅与两个固定阈值作比较,产生两个数字信号:开始和停止.     

Near- and Far-Field Characterization of Planar mm-Wave Antenna Arrays with Waveguide-to-Microstrip Transition

We present the design and characterization of planar mm-wave patch antenna arrays with waveguide-to-microstrip transition using both near- and far-field methods. The arrays were designed for metrological assessment of error sources in antenna measurement. One antenna was designed for the automotive radar frequency range at 77 GHz, while another was designed for the frequency of 94 GHz, which is used, e.g., for imaging radar applications. In addition to the antennas, a simple transition from rectangular waveguide WR-10 to planar microstrip line on Rogers 3003? substrate has been designed based on probe coupling. For determination of the far-field radiation pattern of the antennas, we compare results from two different measurement methods to simulations. Both a far-field antenna measurement system and a planar near-field scanner with near-to-far-field transformation were used to determine the antenna diagrams. The fabricated antennas achieve a good matching and a good agreement between measured and simulated antenna diagrams. The results also show that the far-field scanner achieves more accurate measurement results with regard to simulations than the near-field scanner. The far-field antenna scanning system is built for metrological assessment and antenna calibration. The antennas are the first which were designed to be tested with the measurement system.