A strategy for the electro-organic synthesis of new hydrocaffeic acid derivatives

Electrochemical treatment processes can significantly contribute to the protection of the environment through the minimization of waste and toxic materials in effluents. From a pharmaceutical point of view and due to the existing resemblance between the electrochemical and biological reactions, it can be assumed that the oxidation mechanisms on the electrode and in the body share similar principles. In this paper, the application of electrochemical studies in the design of an environmentally friendly method was delineated for the new hydrocaffeic acid (HCA, 3,4-dihydroxy hydrocinnamic acid) derivatives synthesis at carbon electrodes in an undivided cell. In this cell, the EC mechanism reaction was involved, comprising two steps alternatively; (1) electrochemical oxidation and (2) chemical reaction. In particular, the electro-organic reactions of HCA, an important biological molecule, were studied in a water–acetonitrile (90:10 v/v) mixture in the presence of benzenesulfinic acid (3) and p-toluenesulfinic acid (4). The research included the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis and product spectroscopic identification.     

Synthesis and thermomechanical characterization of polyurethane elastomers extended with α,ω‐alkane diols

A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, ¹H‐NMR, and ¹³C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Precise Tip Positioning of a Flexible Manipulator Using Resonant Control

A single-link flexible manipulator is fabricated to represent a typical flexible robotic arm. This flexible manipulator is modeled as an SIMO system with the motor torque as the input and the hub angle and the tip position as the outputs. The two transfer functions are identified using a frequency-domain system identification method, and the resonant modes are determined. A feedback loop around the hub angle response with a resonant controller is designed to damp the resonant modes. A high-gain integral controller is also implemented to achieve zero steady-state error in the tip position response. Experiments are performed to demonstrate the effectiveness of the proposed control scheme.     

SD‐WLB: An SDN‐aided mechanism for web load balancing based on server statistics

Software‐defined networking (SDN) is a modern approach for current computer and data networks. The increase in the number of business websites has resulted in an exponential growth in web traffic. To cope with the increased demands, multiple web servers with a front‐end load balancer are widely used by organizations and businesses as a viable solution to improve the performance. In this paper, we propose a load‐balancing mechanism for SDN. Our approach allocates web requests to each server according to its response time and the traffic volume of the corresponding switch port. The centralized SDN controller periodically collects this information to maintain an up‐to‐date view of the load distribution among the servers, and incoming user requests are redirected to the most appropriate server. The simulation results confirm the superiority of our approach compared to several other techniques. Compared to LBBSRT, round robin, and random selection methods, our mechanism improves the average response time by 19.58%, 33.94%, and 57.41%, respectively. Furthermore, the average improvement of throughput in comparison with these algorithms is 16.52%, 29.72%, and 58.27%, respectively.     

A new design of optical add/drop filters and multi-channel filters based on hexagonal PhCRR for WDM systems

Photonic Network Communications - In this research, using photonic crystal dielectric rods with a triangular lattice constant, a photonic crystal ring resonator (PhCRR) has been designed in order...     

Ultra-high-Q optical filter based on photonic crystal ring resonator

In this study, a photonic crystal ring resonator with a triangular lattice is used to design an optical filter. The proposed structure is able to filter the central wavelength of 1548 nm with a transmission coefficient of over 95%. Moreover, this structure has an ultra-high-quality factor (Q) of about 1290. With altering the features of the structure including the refractive index, the lattice constant and the radius of the rods in the resonator core, their effects on the central wavelength of the filter, transmission coefficient, quality factor and bandwidth are investigated. The plane wave expansion and finite-difference time-domain methods are used to extract photonic band gap and investigate the photonic behavior of the proposed structure, respectively.     

Power Control for Cognitive Radio Networks: A Game Theoretic Approach

In communication industry one of the most rapidly growing area is wireless technology and its applications. The efficient access to radio spectrum is a requirement to make this communication feasible for the users that are running multimedia applications and establishing real-time connections on an already overcrowded spectrum. In recent times cognitive radios (CR) are becoming the prime candidates for improved utilization of available spectrum. The unlicensed secondary users share the spectrum with primary licensed user in such manners that the interference at the primary user does not increase from a predefined threshold. In this paper, we propose an algorithm to address the power control problem for CR networks. The proposed solution models the wireless system with a non-cooperative game, in which each player maximize its utility in a competitive environment. The simulation results shows that the proposed algorithm improves the performance of the network in terms of high SINR and low power consumption.

     

Using a modified Modal Series to analyse weakly nonlinear circuits

In this paper, a modified Modal Series to model and analyse weakly nonlinear circuits is introduced. This method not only provides an analytical expression for the response to input signals, as does Volterra Series, the popular method for the analysis of nonlinear circuits, but also provides the response to initial conditions as well as interaction between the initial conditions and the input signals, which Volterra Series does not. The extension of this method to multi-input circuits is straightforward. The method is applied to analyse three examples: a single-stage amplifier, a typical track and hold sampler, and the Colpitts oscillator. The results are discussed and compared with existing methods.