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在充分搅拌和可忽略粒度影响条件下,测定了间歇搅拌反应釜中001×7(732)阳离子交换树脂催化醋酸甲酯水解反应动力学数据,建立了其拟均相与非均相反应动力学模型,进行了模型筛选和参数估值.结果表明,醋酸甲酯与水均吸附,表面反应为控制步骤的非均相反应动力学模型能较好地拟合实验数据,并满足统计检验.根据优选的反应动力学模型,对醋酸甲酯水解过程进行了模拟计算,考察了反应温度、树脂浓度、水酯摩尔比对水解过程的影响,得到的优化反应条件为:反应温度55℃、树脂浓度260 g·L-1、水酯摩尔比1.5∶1.此时反应90 min接近醋酸甲酯平衡水解率34.8%. 相似文献
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对一个Cs-137辐射源、7个扇型排列探测器旋转方式的γ射线CT测量气液反应釜气含率分布实验装置作了介绍,建立了该实验装置测量气含率分布和数字彩色图像重建的数学模型,并对20 cm内直径的标准Rushton气液搅拌釜进行了空釜扫描验证实验和气液搅拌两种状态的比较实验.实验结果证明该CT实验装置测量结果准确,所形成气液两相气含率分布数字彩色图像清晰可辨,空间分辨率可达2 mm.为了进一步进行气含率分布的定量比较,列出了平均气含率沿无因次半径的变化曲线. 相似文献
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The discrete particle method was used to simulate the distribution of gas holdup in a gas-liquid standard Rushton stirred tank. The gas phase was treated as a large number of bubbles and their trajectories were tracked with the results of motion equations. The two-way approach was performed to couple the interphase momentum exchange. The turbulent dispersion of bubbles with a size distribution was modeled using a stochastic tracking model, and the added mass force was involved to account for the effect of bubble acceleration on the surrounding fluid. The predicted gas holdup distribution showed that this method could give reasonable prediction comparable to the reported experimental data when the effect of turbulence was took into account in modification for drag coefficient. 相似文献
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Based on trajectory equations of gas bubble, an eddy-bubble interaction (EBI) model was developed. This model considered the effect of non-drag forces and took the eddy-bubble interaction time as the refreshing time scale of turbulent fluctuations. The relationship between the crossing-eddy time and the eddy lifetime was discussed, and the predicted distributions of radial, axial ve-locities of bubbles and gas holdup were also given. Compared with eddy lifetime (EL) model, the EBI model gives somewhat smaller axial velocity in the upper circulation region and larger velocity in the lower circulation region, causing that fewer bubbles reach the lower circulation region and gas holdup becomes higher in the upper circulation region. The predicted gas holdup by the EBI model approaches closer to the experimental data in the discharge stream region. 相似文献
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为了建立和实现137Cs γ射线CT(computed tomography)测量Rushton气液搅拌釜气含率分布彩色数字成像模型,根据137Cs发射γ射线信号和探测器接受信号的Poisson分布模型和气液两相流体吸收衰减辐射信号的二项分布模型,在给出接受信号实验样本空间条件下,采用最大似然参数估计法,对容器断面气液... 相似文献
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