MIL-101@g-C
3N
4 nanocomposite was prepared by solvothermal synthesis and used for CO
2 adsorption. The parent materials (MIL-101 and g-C
3N
4) and the MIL-101@g-C
3N
4 were characterized by X-ray diffraction, argon adsorption/desorption, Fourier transform infrared spectroscopy, thermal analysis (TG/DTA), transmission electronic microscopy, and Energy-dispersive X-ray spectroscopy. The results confirmed the formation of well-defined MIL-101@g-C
3N
4 with interesting surface area and pore volume. Furthermore, both MIL-101 and MIL-101@g-C
3N
4 were accomplished in carbon dioxide capture at different temperatures (280, 288, 273 and 298 K) at lower pressure. The adsorption isotherms show that the nanocomposite has a good CO
2 adsorption affinity compared to MIL-101. The best adsorption capacity is about 1.6 mmol g
?1 obtained for the nanocomposite material which is two times higher than that of MIL-101, indicating strong interactions between CO
2 and MIL-101@g-C
3N
4. This difference in efficacy is mainly due to the presence of the amine groups dispersed in the nanocomposite. Finally, we have developed a simple route for the preparation of an effective and new adsorbent for the removal of CO
2, which can be used as an excellent candidate for gas storage, catalysis, and adsorption.
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