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1.
Observations are reported on isotactic polypropylene (i) in a series of tensile tests with a constant strain rate on specimens annealed for 24 h at various temperatures in the range from 110 to 150 °C, (ii) in two series of creep tests in the subyield region of deformations on samples not subjected to thermal treatment and on specimens annealed at 140 °C, and (iii) in a series of tensile relaxation tests on non-annealed specimens. Constitutive equations are derived for the elastoplastic and non-linear viscoelastic responses of semicrystalline polymers. A polymer is treated as an equivalent transient network of macro-molecules bridged by junctions (physical cross-links, entanglements and lamellar blocks). The network is assumed to be highly heterogeneous, and it is thought of as an ensemble of meso-regions with different activation energies for separation of strands from temporary nodes. The elastoplastic behavior is modelled as sliding of junctions in meso-domains with respect to their reference positions driven by macro-deformation. The viscoelastic response is attributed to detachment of active strands from temporary junctions and attachment of dangling chains to the network. Constitutive equations for isothermal deformations with small strains are derived by using the laws of thermodynamics. Adjustable parameters in the stress–strain relations are found by fitting the experimental data. 相似文献
2.
We study the computational complexity of the qualitative algebra which is a temporal constraint formalism that combines the point algebra, the point-interval algebra and Allen's interval algebra. We identify all tractable fragments and show that every other fragment is NP-complete. 相似文献
3.
N. V. Vostokov Yu. N. Drozdov Z. F. Krasil’nik O. A. Kuznetsov A. V. Novikov V. A. Perevoshchikov M. V. Shaleev 《Russian Microelectronics》2005,34(4):203-209
The results are presented of the fabrication of strain-relaxed graded Si1 − x
Gex/Si(001) buffer layers with a maximum Ge fraction of about 0.25 that have a low density of threading dislocations (<106 cm−2) and low surface roughness. The buffer layers are grown by atmospheric-pressure hydride CVD. It is found that chemical mechanical polishing can reduce their surface roughness to a level comparable with that of the original Si(001) substrates. It is shown that the polished buffer layers can serve as substrates for MBE-grown SiGe/Si heterostructures.__________Translated from Mikroelektronika, Vol. 34, No. 4, 2005, pp. 243–250.Original Russian Text Copyright © 2005 by Vostokov, Drozdov, Krasil’nik, Kuznetsov, Novikov, Perevoshchikov, Shaleev. 相似文献
4.
Results of ballistic tests for obstacles made of combined materials in relation to striker shape are presented in the form of penetration curves. It is established that striker shape affects not only quantitative indices, but also the qualitative nature of these curves.Translated from Problemy Prochnosti, No. 1, pp. 60–62, January, 1992. 相似文献
5.
6.
Prediction of Undrained Sinkhole Collapse 总被引:2,自引:0,他引:2
Charles E. Augarde Andrei V. Lyamin Scott W. Sloan 《Canadian Metallurgical Quarterly》2003,129(3):197-205
Sinkholes are surface depressions or shafts resulting from the collapse of a submerged cavity in soil. The cavities that lead to sinkholes form as a result of underlying geology in limestone areas, or as a result of human activity such as mining or leakage from a sewer. The formation of sinkholes is often sudden and can lead to extensive damage and loss of life, especially in urban areas. Much of the literature on the subject of sinkhole formation is empirical in nature, often being associated with specific locations. This paper presents the results of a study, using numerical modeling, of the undrained stability of the submerged cavities that lead to sinkhole formation. Finite-element limit analysis techniques (using programs developed at the University of Newcastle) are used to obtain upper and lower bound values of a suitable load parameter, which bracket the exact solution. The results are compared to analytical solutions, both from literature and derived independently. 相似文献
7.
We have measured the heat capacities of3He films and liquid3He in porous Vycor glass at 10 to 600 mK. With increasing the film thickness from 1 to 3 atomic layers, the specific heat evolves gradually from that typical to solid to that of liquid3He. At about 2 atomic layers, however, its low-temperature part is nearly temperature-independent; we interpret this as a result of gradual freezing of spins in an amorphous solid3He film with decreasing the temperature. The contribution of liquid3He in the center of the Vycor pores can be described as the specific heat of bulk liquid3He at corresponding pressures in the range 0 to 28 bar. The thickness of amorphous solid on the pore walls increases with external pressure roughly linearly. Preplating the walls with4He allows to determine the positions of3He atoms contributing to the surface specific heat at 10 to 50 mK. In addition, the contribution from the specific heat of3 He -4He mixing at 100 to 600 mK is discussed as a function of pressure and amount of4He.0n leave from ISSP Acad. Sci. of Russia, Chernogolovka, Russia 相似文献
8.
V. G. Shengurov S. P. Svetlov V. Yu. Chalkov B. A. Andreev Z. F. Krasil'nik B. Ya. Ber Yu. N. Drozdov 《Inorganic Materials》2003,39(1):3-5
The Ge and Er depth profiles in Si1 – x
Ge
x
layers grown on Si(100) substrates by Si sublimation-source molecular-beam epitaxy in GeH4 were studied by secondary ion mass spectrometry. The results demonstrate that Ge facilitates Er incorporation into the growing Si–Ge layer. The Er dopant profile becomes sharper with increasing Ge content. The Ge profile also has rather sharp boundaries, indicating that there is no Ge surface segregation, which is attributable to the presence of adsorbed hydrogen, acting as a surfactant. 相似文献
9.
10.
Sergei Zinovyev Andrei Shelepchikov Pietro Tundo 《Applied catalysis. B, Environmental》2007,72(3-4):289-298
A multipurpose study deals with the transfer hydrogenolysis of 1,3,5-trichlorobenzene to benzene in the 2-propanol–Raney nickel system in the presence of KOH. At 70 °C, no reaction occurs without KOH or with weaker bases, e.g. amines or poorly soluble inorganic bases; however saturated KOH as well as water over 1% suppress the reaction rate, presumably due to the competitive adsorption of these species on the catalyst. The catalytic activity also drops with time because of the deposition of the solid KCl on the catalyst but can be recovered at washing the catalyst with water. The deactivation by KCl can be mitigated with the addition of promoters, e.g. quaternary ammonium salts (Aliquat 336, CTAC) or trioctylamine. Aliquat 336 also promotes hydrodechlorination in the hydrothermal system using a 10% solution of 2-propanol in water, Raney nickel and potassium carbonate as base at 150–200 °C and 10–20 bar. Under these conditions, hexachlorobenzene was also selectively dechlorinated to benzene. 相似文献