Recovery of gold cyanide using inherently conducting polymers

Removal of gold from basic solutions containing [Au(CN)₂]^? has been demonstrated using the inherently conducting polymer polypyrrole. Polymers containing sulfonated aromatic dopants have been found to display a significant ability to remove gold from such solutions. Experiments performed in solutions containing both gold and copper cyanide complexes indicate that the recovery process is not highly selective. However, the polypyrroles used display significantly faster rates of gold recovery than activated carbon. © 2003 Society of Chemical Industry     

Effects of luminance,wavelength and purity on the color attributes: Brief review with new data and perspectives

A color stimulus may be characterized by three psychophysical dimensions (luminance, dominant wavelength, and purity), whose corresponding color attributes are lightness, hue, and chroma/colorfulness. The 3 × 3 matrix gives nine basic effects of the psychophysical dimensions on the color attributes (e.g. the effect of luminance on hue), but there are 49 possible combinations as more complex effects (e.g. the effect of luminance on hue and chroma, i.e. on chromaticity). Researching and quantifying such effects enables modelling of the underlying neural mechanisms and of color appearance. Using a simple nomenclature to identify the effects (e.g. Ph denotes the effect of Purity on hue), this paper briefly reviews and interrelates 15 of the commonest effects, giving new data or new graphical perspectives to clarify or fill gaps in the literature. Contrast and no‐contrast effects (stimuli viewed simultaneously or singly, respectively) are differentiated. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 208–222, 2007     

A comparative study of color measurement lntstrumentation

A multiplant Quality Improvement Team [QIT] was firmed to develop and implement an evaluation program for various color measurement .systems as potential replacements for the then-current aging systems. The emphasis qf this article is the analytical methodology utilized to evaluate the various color systems. The evaluation program consisted cf two phases. Phase I was a general overview/review of several systems, while Phase II was an extensive internal comparative evaluation measurement systems. These were Milton-Roy's ColorMate HDS, HunterLab's Ultrascan, Datacolor's CS-5, and BYK-Gardner's The Color Sphere [TCS]. The main comparison criteria were interinstrument agreement [agreement between two instruments ofthe same system], user-friendly software and computer interface capability, vendor amenability to a long-term logistical and maintenance relationship, and price. All systems were evaluated by duplicate measurements on various color tiles, yarns, and polymer flakes-over 1600 measurements on each system. The systems were compared with an instrument matrix, a decision matrix, and a product matrix. The instrument matrix was a comparison qfinstrument parameters, software/math treatments, and economics. The decision matrix was a forced ranking of each system by each criteria category [1–4 scale, with 1 representing the best and 4 representing the worst]. The product matrix accentuated the relative importance ofone criterion category over another by multiplying the forced ranking by the criticality of the category. The criticality of a given category wus determined by consensus within the QIT. Thr combination qf the three matrices allowed the evaluator[.s] t o select the color rneasuremmt system that best satixfied the color measurement needs and requirements of their facility and their products. For this evaluation, all ofthe evaluated systems were superior to the then-current agingsystems. As a result of this methodology, one instrument emerged as clearly superior. © 1994 John Wrley & Sons, Inc.     

Chromatic luminance,colorimetric purity,and optimal aperture‐color stimuli

Chromatic luminance (i.e., luminance of a monochromatic color) is the source of all luminance, since achromatic luminance arises only from mixing colors and their chromatic luminances. The ratio of chromatic luminance to total luminance (i.e., chromatic plus achromatic luminance) is known as colorimetric purity, and its measurement has long been problematic for nonspectral hues. Colorimetric purity (p_c) is a luminance metric in contrast to excitation purity, which is a chromaticity‐diagram metric approximating saturation. The CIE definition of p_c contains a fallacy. CIE defines maximum (1.0) p_c for spectral stimuli as monochromatic (i.e., optimal) stimuli, and as the line between spectrum ends for nonspectrals. However, this line has <0.003 lm/W according to CIE colorimetric data and is therefore effectively invisible. It only represents the limit of theoretically attainable colors, and is of no practical use in color reproduction or color appearance. Required is a locus giving optimal rather than invisible nonspectral stimuli. The problem is partly semantic. CIE wisely adopted the term colorimetric purity, rather than the original spectral luminance purity, to permit an equivalent metric for spectrals and nonspectrals, but the parameter of equivalence was never clear. Since 1 p_c denotes optimal aperture‐color stimuli for spectrals, arguably 1 p_c should denote optimal stimuli consistently for all stimuli. The problem reduces to calculating optimal aperture‐color stimuli (“optimal” in energy efficiency in color‐matching) for nonspectrals, shown to comprise 442 + 613 nm in all CIE illuminants. This remedy merely requires redefinition of 1 p_c for nonspectrals as the line 442–613 nm, and gives meaningful p_c values over the hue cycle allowing new research of chromatic luminance relations with color appearance. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 469–476, 2007     

Epoxy fatty acid ester plasticizers. Preparation and properties

Summary The preparation of epoxy fatty acid ester plasticizers has been reviewed. These plasticizers can be prepared by epoxidation reactions, utilizing a preformed peracid or anin-situ technique. A newin-situ epoxidation process, utilizing hydrogen peroxide and acetic acid in the presence of strong acid catalyst, has been described. Excellent conversions to epoxide have been achieved with a series of monounsaturated and polyunsaturated esters. Epoxy fatty acid esters are excellent plasticizers for vinyl resins. Their performance in a series of additional epoxy plasticizers of vegetable and marine origin is described. Novel epoxy plasticizers based upon mixed acetylated mono- and di-glyceride have been prepared and are found to have excellent plasticizer performance. Presented at the 28th fall meeting, American Oil Chemists’ Society, October 1954, Minneapolis, Minn.     

Function of sulfur dioxide in the kinetic mechanism of oxidation of carbon

Retardation of the gasification reaction of carbon with oxygen by SO₂ was observed. Rates of oxidation were determined by thermal gravimetric analysis (TGA) of a nuclear graphite in the temperature range of 550–700°C, and of a coconut charcoal in the temperature range of 400–505°C. The oxidant gases were dry air containing 0–6% SO₂. Reduction of the rate by SO₂ varied with burn-off. Differential thermal analysis (DTA) was also applied to detect the retardation effect of SO₂. The technique of infrared internal reflection spectroscopy (IRS) was used to examine the surface species of reacted charcoal samples. Absorption bands were assigned to surface carbonyls, lactones, and a chemisorbed SO₂ in the form of sulfate. Chemisorption of SO₂ was attributed to cause the retardation of the oxidation reaction.     

Refinement of fair action systems

An action system is a framework for describing parallel or distributed systems, for which the refinement calculus offers a formalisation of the stepwise development method. Fairness is an important notion in modelling parallel or distributed systems, and this paper investigates a calculus for refinement of fair action systems. Simulations, which are proof techniques for refinement, are extended to verify fair action systems. Our work differs from others' in that the additional condition concerning fairness is expressed through termination of related iteration statements. For this purpose, existing proof rules for termination are extended. In the tradition of the refinement calculus, our approach to fairness is based on techniques developed mainly for sequential programming. Received: 16 March 1995 / 16 April 1997     

A methodology to model the information structure of an organization

The Integrated Computer Aided Manufacturing (ICAM) program of the U.S. Air Force identified a need to better communicate and analyze manufacturing for the people involved in improving productivity. To satisfy that need, the ICAM program developed the IDEF (ICAM Definition) method to address particular characteristics of manufacturing. This IDEF method is equally applicable in analyzing other types of organizations. IDEF comprises three modeling methodologies: function model methodology (IDEF₀), information model methodology (IDEF₁) and dynamics model methodology (IDEF₂). This paper reports on the Information model methodology only. This methodology is used to construct an information model that helps in understanding the structure of information needed to support the functions of an organization.