Interview mit Hans-Christian Boos zum Thema „Unternehmertum in der IT-Branche“

Ohne Zusammenfassung     

Segmented polymer networks containing amino‐dendrimers

Polymer networks in which poly(propylene imine) dendrimers (Astramol?) are connected to each other by linear polytetrahydrofuran (polyTHF) segments, were prepared by two methods. The first method was a one‐step procedure in which bifunctionally living polyTHF, obtained by initiation of the THF polymerization with trifluoromethane sulfonic anhydride (triflic anhydride), was reacted with an amino‐dendrimer. This reaction was very fast but did not allow formation of the end products. The second method was a two‐step procedure. In a first step, living polyTHF, prepared with acryloyloxybutyl triflate as initiator, was grafted on an amino‐dendrimer, to form a star‐like, acrylate‐terminated polyTHF multi‐macromonomer with the dendrimer as core. In a second step, networks were obtained by Michael addition between the acrylate end‐groups and unreacted amino‐groups of the dendrimer. This cross‐linking reaction occurred spontaneously upon heating of the solution of the multi‐macromonomer with gelation times varying from a few minutes to a few hours, depending on the temperature and the composition of the prepolymers. With this method it was possible to prepare networks in the form of coatings or films. © 2003 Society of Chemical Industry     

Polymer networks based on α,ω-methacrylate-terminated poly(1,3-dioxolane)

α,ω-Methacrylate-terminated poly(1,3-dioxolane)s (polyDXL) were synthesized by cationic ring-opening polymerization of DXL in the presence of methylene-bis(oxyethylmethacrylate) as transfer agent. If the initiator concentration is small compared with the transfer agent concentration, the molecular weights of the polymers are governed by the ratio of the reacted monomer to the reacted transfer agent. The α,ω-methacrylate-terminated polyDXLs obtained undergo free radical polymerization with formation of polyacetal networks. The properties of the networks as function of the molecular weight of the corresponding prepolymers are reported.     

Grenzen der Anwendbarkeit der Theorie der analytischen Signale

Zusammenfassung Bei der praktischen Anwendung der analytischen Signale ist es erforderlich, die Ermittlung der Hilbert-Transformation numerisch durchzuführen. Dazu wurden u.a. Verfahren von H.W. Schü?ler, R. Unbehauen und G. Wunsch vorgeschlagen. In der Arbeit werden allgemeine Ergebnisse zur numerischen Umsetzung der Hilbert-Transformation dargestellt. Es wird gezeigt, da? alle praktisch realisierbaren Verfahren für bestimmte Signale divergieren. Damit ist es m?glich, die in der Experimentalphysik schon l?nger bekannten Schwierigkeiten bei der Umsetzung der Hilbert-Transformation zu erkl?ren.     

用于制导弹药的自适应自动驾驶仪设计

传统制导弹药自动驾驶仪的设计要求精确的气动模型,并依赖于变增益(gainschedule),以说明系统的非线性.本文给出了一种简化自动驾驶仪设计程序的方法:在单一飞行条件下设计逆控制器,将逆控制器与在线神经网络组合,以说明因近似逆引起的误差,这样减少了大量设计程序及精确的气动数据.这些数据在大攻角或其它情况下很重要,因为这些领域中的空气动力特征变得高度非线性化.研究发现:逆的选择在其实现的过程中很重要,所以详细讨论.最后,给出该方法在非线性6自由度制导弹药中的模拟结果.     

Computing hysteresis points of nonlinear equations depending on two parameters

A direct method is described for computing a hysteresis point (double turning point) corresponding to a cusp point of a system ofn nonlinear equations inn variables depending on two parameters. By addition of two equations a minimally extended system ofn+2 nonlinear equations is constructed for which the hysteresis point is an isolated solution. An efficient implementation of Newton's method is presented not requiring evaluations of second derivatives of the original problem. Two numerical examples show the efficiency of theQ-quadratically convergent method.     

Betriebsvereinbarung contra BDSG?

Ob Betriebsvereinbarungen im Sinne des § 4 Abs. 1 BDSG eine „andere Rechtsvorschrift” sind und damit die Regelungen des BDSG einschr?nken dürfen, geh?rt zu den Standardfragen des praktischen Arbeitnehmerdatenschutzes. Die Autoren befürworten eine weite betriebliche Regelungskompetenz, beschr?nken diese aber zum Schutz der Arbeitnehmer durch eine Reihe datenschutzrechtlicher Mindestanforderungen, die Betriebsvereinbarungen einzuhalten haben.