Sol–gel fabrication and enhanced optical properties,photocatalysis, and surface wettability of nanostructured titanium dioxide films

TiO₂ photocatalytic film, annealed at temperatures of 500 °C and 700 °C, was prepared on SiO₂ pre-coated glass via sol–gel technique for photocatalytic purposes and effects of catalyst-type on its properties were investigated by an X-ray diffractometer (XRD), Scanning Electron Microscope, UV–vis spectrophotometer, and contact angle measurements. The XRD results showed that present phases depend upon catalyst used in the solution and phase transformation behaves in a temperature-dependent manner. For the layers derived from sols containing acidic catalysts, the anatase structure dominated and exhibited much better photocatalytic activity. The results indicated that the sample derived from sol comprises H₂SO₄ as catalyst, and exhibits anatase grains with the lowest size. This could be the reason for its better photocatalytic activity. Finally, samples derived from sol containing acidic catalysts showed superhydrophilicity and superior cleaning ability.     

Introducing an Efficient Statistical Model for Automatic Modulation Classification

Journal of Signal Processing Systems - Nowadays, Automatic Modulation Classification (AMC) plays an important role in many applications of cooperative and non-cooperative communication such as...     

New potentially antihypertensive peptides liberated in milk during fermentation with selected lactic acid bacteria and kombucha cultures

Compounds with the ability to inhibit angiotensin-converting enzyme (ACE) are used medically to treat human hypertension. The presence of such compounds naturally in food is potentially useful for treating the disease state. The goal of this study was to screen lactic acid bacteria, including species commonly used as dairy starter cultures, for the ability to produce new potent ACE-inhibiting peptides during milk fermentation. Strains of Lactobacillus acidophilus, Lactobacillus casei, Lactobacillus delbrueckii ssp. bulgaricus, Lactobacillus helveticus, Lactobacillus paracasei, Lactococcus lactis, Leuconostoc mesenteroides, and Pediococcus acidilactici were tested in this study. Additionally, a symbiotic consortium of yeast and bacteria, used commercially to produce kombucha tea, was tested. Commercially sterile milk was inoculated with lactic acid bacteria strains and kombucha culture and incubated at 37°C for up to 72 h, and the liberation of ACE-inhibiting compounds during fermentation was monitored. Fermented milk was centrifuged and the supernatant (crude extract) was subjected to ultrafiltration using 3- and 10-kDa cut-off filters. Crude and ultrafiltered extracts were tested for ACE-inhibitory activity. The 10-kDa filtrate resulting from L. casei ATCC 7469 and kombucha culture fermentations (72 h) showed the highest ACE-inhibitory activity. Two-step purification of these filtrates was done using HPLC equipped with a reverse-phase column. Analysis of HPLC-purified fractions by liquid chromatography–mass spectrometry/mass spectrometry identified several new peptides with potent ACE-inhibitory activities. Some of these peptides were synthesized, and their ACE-inhibitory activities were confirmed. Use of organisms producing these unique peptides in food fermentations could contribute positively to human health.     

Calorimetric and spectroscopic investigations of β-lactoglobulin upon interaction with copper ion

The effect of copper(II) ions (Cu(+2)) on the structure of β-lactoglobulin (β-lg) was investigated spectroscopically using UV-visible, fluorescence and circular dichroism (CD) and calorimetrically using isothermal titration calorimetry (ITC), at different temperatures. Results of the UV-visible studies showed that adding Cu(+2) to β-lg solution caused increasing turbidity, indicative of protein aggregation. It was noticeable that the rate of increasing turbidity was directly proportional to increasing temperature. The far-UV CD studies displayed that the Cu(+2) cannot induce any significant changes in the secondary structures of β-lg at different temperatures. Also, the ITC data indicated that the binding process of Cu(+2) to β-lg is mainly entropically driven. The results highlight that copper ions cause the tertiary structure of β-lg to change and induce a slightly open structure leading to the formation of supramolecular aggregates in β-lg which may result in the reduced allergenicity of β-lg and its increased use in industrial applications.     

Polyaniline/akaganéite nanocomposite for detoxification of noxious Cr(VI) from aquatic environment

In this work, a removal of toxic hexavalent chromium Cr(VI) ion from aqueous solution was investigated and studied using nanocomposite of polyaniline (PANI) and akaganéite nanoparticles (NP). HCl doped PANI, and akaganéite NPs were prepared by chemical oxidative polymerization and co-precipitation techniques, respectively. The synthesized materials were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), and high-resolution transmission electron microscope (HRTEM). It was indicated that the formed oxide NPs were consisted of akaganéite as dominant phase plus minor phases of hematite, magnetite, and/or maghemite. HRTEM images of the prepared nanocomposite demonstrated that the phases of oxide NPs embedded in the nanocomposite had the same crystallinity and morphology of pristine oxide NPs. It was found that size of nanocomposite particles has diameter ranged from 8.95 to 16.21 nm. Cr(VI) removals in a wide pH range from 2 to 9 were appropriated for prepared nanocomposite. The nanocomposite has demonstrated high removal percentage of 99.2 % and removal capacity of 17.36 mg/g for 7.0 mg/L Cr(VI) polluted aqueous solution at pH 2.0 for 5-min contact time. The synthesized nanocomposite was applied to remove Cr(VI) from a leather tanning wastewater sample with efficiency of 93.4 %.     

High Productive Ethylene Trimerization Catalyst Based on CrCl<Subscript>3</Subscript>/SNS Ligands

Abstract  

Methylaluminoxane (MAO)-activated chromium (III) complexes of tridentate SNS ligands of the form (RSCH₂–CH₂)₂NH (R = alkyl, aryl) have been prepared and tested for the trimerization of ethylene to 1-hexene. The effect of ethylene pressure, Al/Cr ratio and S donor substitution on 1-C6 selectivity and productivity has been examined. It is shown that when the substitution on S is pentyl group it will lead to the highest productivity, 174200 g 1-C6/g Cr h, due to the synergistic effect of this group.     

CEO观点：在新兴市场中，微型蜂窝基站制造业者须保持弹性!

无线营运业者的目标,是提供充分的移动能力及无缝式的漫游,以为使用者确保能永久存取宽带连接功能。目前这个目标可透过移动电话网络达成．但其涵盖率于室内和偏远地区具有局限性,这也意味着并非所有使用者都能得到想要的无缝式涵盖率。     

Impact of Freezing Process on Salt Diffusivity of Seafood: Application to Salmon (Salmo salar) Using Conventional and Pressure Shift Freezing

The depression of the melting temperature of ice under pressure permits to obtain a rapid freezing of foods. The expected benefit lies in reduced water diffusion from the intra- toward the extracellular media, resulting in a reduced drip loss during thawing. Beside, the modification of the cellular structure induced by ice formation may affect the mass diffusivity of the flesh. In the present study, salmon was used as a model food. Slabs of salmon (1-cm thick) were frozen using blast air and pressure shift freezing at 200 MPa. The impact of the freezing process on the mass diffusivity of salt was evaluated using an aqueous solution (NaCl, 3% w/w). Results indicate that the effective mass diffusivity was slightly increased in comparison to non-frozen flesh when a rapid freezing process was used. This may be attributed to a change in the permeability of cell membranes caused by freezing and high pressure.     

A Framework for Ground Water Management Based on Bayesian Network and MCDM Techniques

Groundwater resources are steadily subjected to increasing water demands. The aquifers are considered as the most accessible source of fresh water. In recent years, they have been faced with severe water withdrawal in arid and semi-arid countries like Iran and thus some aquifers was considered as forbidden aquifers that it means the water withdrawal from these aquifers is unauthorized. Given a critical situation, groundwater resources management in the form of tools such as monitoring the level of the aquifers and developing the restoring scenarios is essential. Therefore, for this purpose, a framework has been developed based on prediction of groundwater level using Bayesian Networks (BNs) model. Furthermore, Multi Criteria Decision Making methods (MCDM) techniques proposed and employed for ranking of proposed groundwater management scenarios. This framework was evaluated for restoring the Birjand aquifer in Iran in different hydrological conditions. A probabilistic Dynamic BN was proposed for groundwater level prediction under uncertainties. After analyzing the obtained results, the applicable short term scenarios for groundwater management as well as appropriate economic, social and technical criteria were defined for decision making procedure. Then, using elicitation of decision makers’ opinions on the relative importance and performance of criteria, SAW, TOPSIS and PROMETHEE-II techniques were applied to rank the scenarios and the obtained results were aggregated by Borda method for final ranking of the scenarios. Lastly, the final results demonstrates the capability of the proposed framework for groundwater resources planning and management which can be employed for reducing the risk of aquifer level declining.