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Corrosion of steel in reinforced concrete structures is a recurrent problem affecting civil engineering structures and costing the world billions of dollars per year. This physical phenomenon mainly results from chloride ingress or concrete carbonation. Corrosion can be diagnosed through a nondestructive method such as half-cell potential measurements. The present paper studies this method on a reinforced concrete wall containing eighteen unconnected steel bars and subjected to chloride-induced macrocell corrosion. Three corrosion systems with different configurations of connections between the steel bars are generated, involving three different anode-to-cathode surface ratios. Then, half-cell potential variations are observed versus macrocell corrosion current. The results lead to a critical discussion regarding the physical relevance of the usual potential threshold method to detect corroding rebars in reinforced concrete structures. In addition, the experiments demonstrate that electrical continuity between reinforcing steel bars is not necessary to get meaningful information about the macrocell corrosion system. At last, the paper show that the electric field (potential gradient) relative to a macrocell corrosion system may be measured by connecting the measurement system (reference electrode?+?voltmeter) to any electrochemical system in electrolytic contact with the concrete. 相似文献
3.
Mickaël Daniel Yves Lionel Elie Thomas Philippe Claude 《Sensors and actuators. A, Physical》2008,147(1):263-272
This paper introduces the conceptual architecture of a fully integrated, truly self-powered structural health monitoring (SHM) scheme. The challenge here is to power an array of numerous distributed actuators and sensors as well as wireless data transmission modules without recurring to heavy and costly wiring. Based on microgenerators which directly convert ambient mechanical energy into electrical energy, using the synchronized switch harvesting (SSH) method, the proposed solution allows avoiding the periodic replacement or reloading of batteries. This addresses environmental and economic issues at the same time, knowing that such elements are heavy, polluting and might be installed in rather inaccessible locations. Indeed, especially in airborne structures saving weight and maintenance cost is of priority importance.Previous work showed that such microgenerators provide a stand-alone power source, whose performances meet the requirements of autonomous wireless transmitters (AWTs) that comprise an acoustic Lamb wave's actuator and a radio frequency (RF) emitter (D. Guyomar, Y. Jayet, L. Petit, E. Lefeuvre, T. Monnier, C. Richard, M. Lallart, Synchronized switch harvesting applied to self-powered smart systems: Piezoactive microgenerators for autonomous wireless transmitters, Sens Actuators A: Phys. 138 (1) (2007) 151–160, doi:10.1016/j.sna.2007.04.009). Following this work, the present contribution presents a further step towards the integration of the SHM technique. It shows the ability of our microgenerators to provide enough energy to give logical autonomy to each self-powered sensing node, named autonomous wireless receiver (AWR), and thus to provide some local (decentralized) pre-processing ability to the SHM system.A preliminary design of the device using off-the-shelf electronics and surface mounted piezoelectric patches will be presented. Since the existence of a positive energy balance between the harvesting capabilities of the SSH technique and the energy requirements of the proposed device will be proved, the system formed by the combination of the AWR with the previously developed AWT, is a proof of concept of truly self-powered smart systems for damage detection in simple structures, setting apart application-specific optimization or miniaturization concerns that will be addressed in future works. 相似文献
4.
Nana Achile Alomayri Thamer Salman Venyite Paul Kaze Rodrigue C. Assaedi Hasan Suliman Nobouassia Christelle Bewa Sontia Jordan Valdès Metekong Ngouné Jean Kamseu Elie Leonelli Cristina 《SILICON》2022,14(1):263-274
Silicon - The synthesis, mechanical behaviour, and microstructure of metakaolin-based geopolymer mortar reinforced with quartz sand are presented in this investigation. Fine sand (quartz sand)... 相似文献
5.
Joseph Zobo Mfomo Daniel Lissouck Elie Younang Samuel N’sikabaka Ibrahim Mbouombouo Ndassa 《International Journal of Food Properties》2017,20(9):1935-1948
Density functional methods were used to predict the antioxidative efficiency of thirteen 4-benzylidenamino-4, 5-dihydro-1H-1,2,4-triazol-5-one derivatives in the gas phase and in the solution phase (water and benzene). Optimized geometries of molecules and reaction thermodynamic energies (enthalpies and reaction-free energies) of three main antioxidant mechanisms (hydrogen atom transfer, single electron transfer-proton transfer, and sequential proton loss electron transfer) were studied at B3LYP/6-31G (d,p) level. Solvent contributions to thermodynamic energies were computed employing integral equation formalism integral equation formalism polarized continuum model method. Obtained results revealed that the three main working mechanisms were endothermic, but not spontaneous especially in the gas phase. We found that the single electron transfer process from the anionic form was more preferable than that from the neutral form in the gas phase. The comparison of the ionization potentials of 4-benzylidenamino-4, 5-dihydro-1H-1,2,4-triazol-5-one derivatives to those of classical antioxidants (gallic acid, caffeic acid, ferulic acid, and ascorbic acid) indicated that the electron transfer mechanism was more predominant in the thirteen 4-benzylidenamino-4, 5-dihydro-1H-1,2,4-triazol-5-one derivative compounds. Thermodynamically, single electron transfer process from the anionic form was the most preferable mechanism in the gas phase. Solvent effect drastically modified thermodynamic energies of mechanisms. The proton transfer process was the thermodynamically favored mechanism as compared to other mechanisms in both solvents. It is worth mentioning that all the mechanisms were found not to be spontaneous in the solution phase except the proton transfer process. 相似文献
6.
Wu W Black MJ Mumford D Gao Y Bienenstock E Donoghue JP 《IEEE transactions on bio-medical engineering》2004,51(6):933-942
We present a switching Kalman filter model for the real-time inference of hand kinematics from a population of motor cortical neurons. Firing rates are modeled as a Gaussian mixture where the mean of each Gaussian component is a linear function of hand kinematics. A "hidden state" models the probability of each mixture component and evolves over time in a Markov chain. The model generalizes previous encoding and decoding methods, addresses the non-Gaussian nature of firing rates, and can cope with crudely sorted neural data common in on-line prosthetic applications. 相似文献
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Dalal Bakhos-Douaihy Elie Seaayfan Sylvie Demaretz Martin Komhoff Kamel Laghmani 《International journal of molecular sciences》2021,22(4)
Mutations in the Na-K-2Cl co-transporter NKCC2 lead to type I Bartter syndrome, a life-threatening kidney disease. We previously showed that export from the ER constitutes the limiting step in NKCC2 maturation and cell surface expression. Yet, the molecular mechanisms involved in this process remain obscure. Here, we report the identification of chaperone stress 70 protein (STCH) and the stress-inducible heat shock protein 70 (Hsp70), as two novel binding partners of the ER-resident form of NKCC2. STCH knock-down increased total NKCC2 expression whereas Hsp70 knock-down or its inhibition by YM-01 had the opposite effect. Accordingly, overexpressing of STCH and Hsp70 exerted opposite actions on total protein abundance of NKCC2 and its folding mutants. Cycloheximide chase assay showed that in cells over-expressing STCH, NKCC2 stability and maturation are heavily impaired. In contrast to STCH, Hsp70 co-expression increased NKCC2 maturation. Interestingly, treatment by protein degradation inhibitors revealed that in addition to the proteasome, the ER associated degradation (ERAD) of NKCC2 mediated by STCH, involves also the ER-to-lysosome-associated degradation pathway. In summary, our data are consistent with STCH and Hsp70 having differential and antagonistic effects with regard to NKCC2 biogenesis. These findings may have an impact on our understanding and potential treatment of diseases related to aberrant NKCC2 trafficking and expression. 相似文献
9.
Simone Goergen Elie Fayad Sébastien Laforge Patrick Magnoux Loïc Rouleau Joël Patarin 《Journal of Porous Materials》2011,18(5):639-650
Layered MCM-22(P) was synthesized in the presence of hexamethonium (HM) cations. Compared to zeolite EU-1 (EUO-type structure), which crystallizes in similar conditions, its formation is favored at high HM concentrations (HM/SiO2 ≥ 0.3) and in the absence of Na2O. HM-containing MCM-22(P) was used as starting material for zeolite formation. Upon hydrothermal treatment, HM-MCM-22(P) transforms into zeolite EU-1 and upon calcination into a MWW-type zeolite. Transformation mechanisms were studied by standard characterization techniques such as XRD, SEM and TEM. Catalytic properties of the MWW-type zeolite obtained from this precursor were evaluated in a m-xylene isomerization reaction. Compared to zeolite MCM-22 prepared with hexamethyleneimine, a higher catalytic activity and an increased isomerization selectivity were observed and discussed. 相似文献
10.
在全球经济快速发展的今天,人类赖以生存的地球正面临着严峻的环境威胁。虽然2009年全球温室气体排放量比上年下降1.3%,创10年来首降,但全球碳计划机构指出2010年全球二氧化碳排放量将再创历史纪录。 相似文献