Preparation and properties of heavy-metal halide glasses

We have studied the effect of In³⁺, Pb²⁺, Gd³⁺, and Cl (heavier ions) substitutions for Al³⁺, Ba²⁺, La³⁺, and F^? on the crystallization stability and UV/IR optical properties of HBLAN fluorohafnatc glasses (HfF₄-BaF₂-LaF₃-AlF₃-NaF system). We obtained stable glasses containing InF₃ and BaCl₂ instead of AlF₃ and BaF₂, respectively, and offering increased IR transmission. The presence of CCl₄ in the process atmosphere and the removal of oxygen-containing impurities via directional solidification are shown to have an advantageous effect on the optical quality of the glasses. The fluoride-chloride glasses are capable of accommodating about 1.5 times higher levels of rare-earth activators in comparison with their fluoride analogs.     

Contribution of K. A. Andrianov to the development of heat-resistant adhesives

Listed are the grades of heat-resistant adhesives developed under the Andrianov’s scientific guidance at the All-Russia Institute of Aviation Materials on the basis of organosilicon polymers.     

Reconstruction of radiation situation at Chernobyl NPP service area on the basis of γ-ray spectrometric analysis of soil samples and published data

Reconstruction of the radiation situation in areas subjected to nuclear accidents was done with an example of the Chernobyl accident (1986) on the basis of the radionuclidic composition of soil samples. The radionuclidic composition of γ-emitters was determined 19 years after the accident in a pulverescent sandstone sample collected in July 1986 at a distance of 1.5 km from the 4th block. Using reference data and data from original papers, reconstruction of the radionuclidic composition of the sample is done on the first ten days after the accident, and possible variations of the γ-radiation dose rate were determined within the framework of the thin film model. Based on the results obtained, variations of the absorbed dose of γ-radiation in 10 days are estimated, which is necessary for making urgent decisions in the initial period after the accident. The results are well consistent with the published data on the dose rates, validating the decision on evacuation of the people from Pripyat town and from the 30-km exclusion zone.     

An efficient implementation of certain iterative refinement preconditioners

Preconditioned iterative methods of conjugate gradient type for solving elliptic and parabolic problems discretized on grids wth local refinement are considered. The sparsity pattern of the residuals computed throughout the iterative process is investigated. It turns out that they are nonzero only near the interface nodes between the coarse-and fine-grids. This observation is used to formulate the preconditioned CG, and when the matrix is not symmetric as in the parabolic case—the generalized CG and GMRES methods, thus substantially saving storage and computation.     

Increasing the corrosion resistance of equipment due to the use of film-forming amines

Results of a study of tube specimens cut from hot-water boilers show that film-forming octadecyl amine (ODA) used in the process of preservation removes deposition from the surface of the metal. An ODA film is preserved on the surface after repeated washing of the latter with hot water. The concentration of chlorides at the surface of the metal after treatment with ODA is lower than before the treatment. __________ Translated from élektricheskie Stantsii, No. 11, November 2005, pp. 15–18.     

Effect of prolonged high-temperature loading on the structure of the KhN65VMTYu alloy

A complex analysis of changes in the structure and in the phase composition arising as a result of both a prolonged operation of articles made of the alloy KhN65VMTYu (EI893) and after conducting imitation tests of model samples. The tests for long-term strength using samples cut out from the body of a large-dimension turbine blade which was exploited for 63 622 h showed that the blade preserved a significant residual reserve of service life (at 750°C and 250 MPa, the time to failure is 4243.5 h).     

The “Angiogenic Switch” and Functional Resources in Cyclic Sports Athletes

Regular physical activity in cyclic sports can influence the so-called “angiogenic switch”, which is considered as an imbalance between proangiogenic and anti-angiogenic molecules. Disruption of the synthesis of angiogenic molecules can be caused by local changes in tissues under the influence of excessive physical exertion and its consequences, such as chronic oxidative stress and associated hypoxia, metabolic acidosis, sports injuries, etc. A review of publications on signaling pathways that activate and inhibit angiogenesis in skeletal muscles, myocardium, lung, and nervous tissue under the influence of intense physical activity in cyclic sports. Materials: We searched PubMed, SCOPUS, Web of Science, Google Scholar, Clinical keys, and e-LIBRARY databases for full-text articles published from 2000 to 2020, using keywords and their combinations. Results: An important aspect of adaptation to training loads in cyclic sports is an increase in the number of capillaries in muscle fibers, which improves the metabolism of skeletal muscles and myocardium, as well as nervous and lung tissue. Recent studies have shown that myocardial endothelial cells not only respond to hemodynamic forces and paracrine signals from neighboring cells, but also take an active part in heart remodeling processes, stimulating the growth and contractility of cardiomyocytes or the production of extracellular matrix proteins in myofibroblasts. As myocardial vascularization plays a central role in the transition from adaptive heart hypertrophy to heart failure, further study of the signaling mechanisms involved in the regulation of angiogenesis in the myocardium is important in sports practice. The study of the “angiogenic switch” problem in the cerebrovascular and cardiovascular systems allows us to claim that the formation of new vessels is mediated by a complex interaction of all growth factors. Although the lungs are one of the limiting systems of the body in cyclic sports, their response to high-intensity loads and other environmental stresses is often overlooked. Airway epithelial cells are the predominant source of several growth factors throughout lung organogenesis and appear to be critical for normal alveolarization, rapid alveolar proliferation, and normal vascular development. There are many controversial questions about the role of growth factors in the physiology and pathology of the lungs. The presented review has demonstrated that when doing sports, it is necessary to give a careful consideration to the possible positive and negative effects of growth factors on muscles, myocardium, lung tissue, and brain. Primarily, the “angiogenic switch” is important in aerobic sports (long distance running). Conclusions: Angiogenesis is a physiological process of the formation of new blood capillaries, which play an important role in the functioning of skeletal muscles, myocardium, lung, and nervous tissue in athletes. Violation of the “angiogenic switch” as a balance between proangiogenic and anti-angiogenic molecules can lead to a decrease in the functional resources of the nervous, musculoskeletal, cardiovascular, and respiratory systems in athletes and, as a consequence, to a decrease in sports performance.     

Gold supported on ceria and ceria–alumina promoted by molybdena for complete benzene oxidation

New gold–molybdena catalysts supported on ceria and ceria–alumina in reaction of complete benzene oxidation were studied. The catalysts were characterized by means of XRD, TPR, XPS and Raman spectroscopy. High and stable catalytic activity was established in the temperature region 200–240 °C. The presence of gold causes a modification in ceria structure leading to an increase of Ce³⁺ and oxygen vacancies formation. The loading of Al³⁺ increases additionally the oxygen vacancies, while a tendency of decrease of Ce³⁺ amount was observed. The presence of alumina results also in a larger share of active oxygen species proved by analysis of O 1s XPS spectra. The differences in the activities within the starting temperature range (150–180 °C) and in the region of 100% conversion (200–240 °C) could be explained by supposing that in the LT region the electron transfer between nanosized gold and ceria particles via oxygen vacancies has a crucial role. In the HT region the oxygen mobility, provoked by the defective structure of ceria due to the presence of Al³⁺, becomes of prevailing importance. It was also concluded that alumina prevents the gold and ceria agglomeration, which is the main factor to avoid deactivation under extreme reaction conditions.