Pt nanoparticles synthesized with new surfactants: improvement in C1–C3 alcohol oxidation catalytic activity

Platinum electrocatalysts were prepared using PtCl₄ as a starting material and 1-decylamine, N,N-dimethyldecylamine, 1-dodecylamine, N,N-dimethyldodecylamine, 1-hexadecylamine, and 1-octadecylamine as surfactants. These surfactants were used for the first time in this synthesis to determine whether the primary and/or tertiary structure and/or chain length of the surfactants, affects the size and/or activity of the catalysts in C₁–C₃ alcohol electro-oxidation reactions. Electrochemical measurements (cyclic voltammetry and chronoamperometry) indicated that the highest electrocatalytic performance was observed for the Pt nanocatalysts that were stabilized by N,N-dimethyldecylamine, and this has a tertiary amine structure with a short chain length (R = C₁₀H₂₁). The high performance may be due to the high electrochemical surface area, Pt(0)/Pt(IV) ratio, %Pt utility, and roughness factor (R _f). X-ray photoelectron spectroscopy, X-ray diffraction, atomic force microscopy, and transmission electron microscopy were used to determine the parameters that affect the catalytic activities.     

Inactivation of Penicillum expansum in sour cherry juice, peach and apricot nectars by pulsed electric fields

Inhibitory effects of pulsed electric fields (PEF) on Penicillum expansum inoculated into sour cherry juice, apricot and peach nectars were determined based on germination tube elongation, spore germination rate, and light and scanning electron microscopy (SEM) observations in this study. After inoculation of juice/nectar samples with P. expansum spores at the level of 10(5)-10(6)cfu/mL, the samples were processed by bench scale PEF pulse generator as a function of differing electric field strengths (0, 13, 17, 20, 23, 27, 30 and 34kV/cm) and processing times (0, 62, 94, 123, 163, 198 and 218mus). Results revealed that with an increase in electric field strength and processing time, germination tube elongation and spore germination rate were completely inhibited. Light and SEM observations revealed considerable morphological alterations in fungal conidia such as cytoplasmic coagulation, vacuolations, shrinkage and protoplast leakage. PEF processing of juice/nectars was demonstrated to be effective in inactivating P. expansum. To our knowledge, this is the first study confirming the inhibitory effects of PEF on germination tube elongation and spore germination rate of P. expansum in fruit juice/nectars.     

Coating of TiO2 nanoparticles with PbS thin films and preparation of PbS nanoparticles using a one-pot sonochemical reaction under the multibubble sonoluminescence conditions

Preparations of PbS-coated titanium dioxide (TiO₂) and lead sulfide (PbS) nanoparticles under ultrasonic field at the multibubble sonoluminescence (MBSL) conditions were tested in water solutions. Under the optimal MBSL conditions (20 kHz and 220 W power input), PbS nanoparticles (diameter = 40-50 nm) were prepared by treating lead nitrate and thioacetamide for 20 min in water solutions. The size of PbS nanoparticles was found to be easily increased to about 90 nm in diameter by increasing the reactant concentration twice. A similar sonochemical reaction with TiO₂ nanoparticles (about 20-30 nm in diameter) gave rise to PbS-coated TiO₂ nanoparticles with a core/shell structure. The PbS thin film coating was quite uniform and the average coating depth of PbS on the TiO₂ nanoparticles was about 2-3 nm under the described conditions. It is interesting to note that the coating depth was found to be controlled to 2-10 nm range by increasing the amounts of reactants for Pb and S twice with a sonication time of 30 min.     

Planning of capacity,production and inventory decisions in a generic reverse supply chain under uncertain demand and returns

There is a growing interest for the design and operation of reverse supply chain systems due to the cost and the legislation issues. In this paper, we address the disassembly, refurbishing and production operations in a reverse supply chain setting for modular products such as computers and mobile phones considering the uncertainties in this system, which are the return amounts of the used products and demand for final products. We develop a large-scale mixed integer programming model in order to capture all characteristics of this system, and use two-stage stochastic optimisation and robust optimisation approaches to analyse the system behaviour. In the first stage, we focus on the strategic decisions about the capacities at disassembly and refurbishing sites considering different scenarios regarding the uncertainties in the system. In the second stage, we analyse the operational decisions such as production, inventory and disposal rates. We observe through our extensive numerical analysis that the randomness of demand and return values effect the performance of the system substantially and the uncertainty of the return amounts of used products is much more important than the uncertainty of demand in this system.     

Processabilities and mechanical properties of surlyn-treated starch/LDPE blends

The esterification of the hydroxyl group of starch with DuPont Surlyn was considered as pretreatment method of starch before blending with polyolefins. In treating starch with Surlyn, two different raction conditions were taken to optimize reaction conditions. First, the esterification reaction was carried out in 110°C xylene with oleic acid as a catalyst. Second, the reaction out in a 90°C mixture of deionized water and xylene with ceric ammonium nitrate(CAN) as an initiator. Starch granules would be swollen above the gelatinization temperature in water. In both cases starch was midified by Surlyn to have good compatibility with low-density polyethylene (LDPE). The mechanical and theological properties were examined for blends of the treated starch and LDPE. This system may be one of the biodegradable polymer blends that sufficiently retain properties as a packaging film.     

Structural performance of the finger-jointed strength of some wood species with different joint configurations

This study was conducted to evaluate the effects of adhesive type, wood species, and finger joint configurations on structural performance of the finger joint. The wood species studied were oriental beech (Fagus orientalis lipsky.), oak (Quercus robur), Scots pine (Pinus sylvestris lipsky.), poplar (Populus tremula lipsk.) and Uludağ fir (Abies bormülleriana Matff.) and adhesives were poly(vinyl acetate) (PVAc), Desmodur-VTKA (D-VTKA). However, there is little information available concerning the bending strength and modulus of elasticity for finger joints in these field. In this study, it was aimed to determine the bending strength and modulus of elasticity for finger joints. For this purpose, samples were tested according to the TS EN 310 standard. It was observed that the highest bending strength and modulus of elasticity were obtained in beech control (solid wood) samples. As for the finger joints, after the control samples, the highest bending strength value (57.4 N/mm²) was obtained from Oriental beech wood samples having a 21 mm finger length and bonded with PVAc adhesive, the highest modulus of elasticity (8885.3 N/mm²) was obtained from beech wood samples having a 21 mm finger length and bonded with PVAc adhesive. As a result of the effects of finger joints on bending strength and modulus elasticity test, if the length of finger joints increases up to 21 mm, the properties of bending strength increase.     

Use of multisensor and multitemporal geospatial datasets to extract the foundation characteristics of a large building: a case study

Bulletin of Engineering Geology and the Environment - The assessment of the ground conditions for large buildings is important because the results are sensitive to the ground conditions, especially...     

The study of MIG weldability of heat-treated aluminum alloys

In this article, Metal Inert Gas (MIG) weldability of commercially received and aged samples of 6061-T₆ and 7075-T₆₅₁ aluminum alloys was investigated. The welding joints were prepared in ten different combinations. Microstructure, microhardness, EDX, energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) analyses were used in order to evaluate the effect of aged heat treatment on the performance of welded joints. In addition, the mechanical properties of welding joints were characterized using the tensile and microhardness tests. In conclusion, it was shown that prewelding aging heat treatment improves the mechanical properties of welding joints.     

Electrochemical synthesis of polyindole on 304-stainless steel in LiClO4–acetonitrile solution and its corrosion performance

The use of electrochemically synthesized polyindole (PIN) film was investigated for protective coating on 304-stainless steel (SS). Polyindole was deposited via anodic oxidation of the corresponding monomer, indole in acetonitrile (ACN) solution containing LiClO₄. It provided an adherent and stable coating on SS. The corrosion performance of coated and uncoated SS was investigated in 3.5% NaCl solution using electrochemical impedance spectroscopy (EIS), anodic polarization curves and open-circuit potential–time (E_ocp–t) diagrams. These tests demonstrated that PIN coating provided important barrier effect to SS for important immersion times in aggressive medium.