Concentrations of native and gold defects in HgCdTe from first principles calculations

We have studied the defect formation energies of the various native (vacancies, interstitials, and antisites) and Au defects in Hg_1−xCd_xTe using density functional-based total energy calculations with ultrasoft pseudo-potentials. These studies are important for infrared (IR) detection technology where the device performance can be severely degraded because of defects. To calculate formation energies, we modeled the neutral and charged defects using supercells containing 64 atoms. From the formation energies, we have determined the defect concentrations as a function of stoichiometry and temperature. We find the prevalent neutral defects to be Au at the Hg site (Au_Hg ), Hg vacancies (V_Hg ), and Te antisites (Te_Hg ). We have also explicitly studied charged defects and have found Te _Hg ²⁺ , Au _Hg ¹⁻ , V _Hg ¹⁻ , V _Hg ²⁻ , and V _Te ²⁺ to have low formation energies. We have identified Au_Hg to be the prevalent Au defect, having concentrations several orders of magnitude greater than the other Au defects. We find that the charge state of V_Hg is primarily (1−) or (2−) depending on the electronic chemical potential.     

On the design of reliable distributed databases

One of the main advantages of distributed databases is their inherent reliability but also associated are problems that must be overcome before it can be achieved. In this paper, we attempt to discuss major design alternatives faced by the designer of a reliable fully replicated distributed database.     

Characterization of information improvement due to N revisions and its generalization by a functional equation

The idea of information improvement was introduced by Thiel [3]. This idea was further extended by the first author to information improvement due to 2 and N revisions and specifically states that different experimenters (a finite number) are required to proceed with given distributions P and U and are permitted to choose a suitable revision. We attempted to provide a measure of information corresponding to Theil's measure which reflected the effect of all revisions. In this paper, the authors have studied a joint characterization of information improvement of N revisions and its generalization by considering a suitable functional equation.     

Natural convection mass transfer behaviour of vertical and horizontal cylinders embedded in an inert fixed bed of Raschig rings

Natural convection mass transfer at vertical and horizontal cylinders embedded in a fixed bed of Raschig rings was studied by an electrochemical technique which involves measuring the limiting current of copper deposition from acidified CuSO₄ solution. Variables studied were Raschig ring diameter, physical properties of the solution and cylinder height in case of vertical cylinders or cylinder diameter in case of horizontal cylinders. Under the present conditions where high porosity beds were used, a slight decrease in the rate of mass transfer was observed in the case of vertical cylinders whereas no rate decrease was observed in the case of horizontal cylinders in the bed. Implication of the present results for the design of fixed bed reactors operating at low feed rates and containing a vertical or horizontal array of tubes for heat exchange with the bed was noted.     

Hardware vs software reliability—A comparative study

High levels of reliability can be predicted and achieved as far as the hardware portions of modern large and complex real-time computer-based control systems are concerned but software is a critical part and plays a vital role in influencing the overall system reliability. This paper presents a comparative study between hardware reliability and software reliability from three definitions: top level, intermediate level and low level based on user's point of view, system designer's point of view and quantitative measurement point of view, respectively. Also discussed is the hardware reliability theory vs software reliability theory on the basis of analysis of malfunctions and prevailing reliability trends.     

The relationship between laboratory-based outcome measures and mortality in end-stage renal disease: A systematic review

Despite data that traditional laboratory-based outcome measures in dialysis are improving over time, population-based data indicate that mortality rates are not improving in parallel. With increased focus on performance measures based on laboratory-based outcomes (e.g., hematocrit, albumin, and parathyroid hormone), less emphasis has been placed on other markers, some of which may be stronger predictors of mortality. We performed a systematic review to interpret the predictive value of laboratory-based outcome measures in dialysis. We identified studies with data regarding the predictive value of laboratory-based outcomes for mortality in dialysis. We calculated the sample size-weighted pooled relative risk of death with dichotomized high vs. low levels of each measure. We rank-ordered predictors by scaling the pooled relative risk of each measure by its pooled standard deviation. There were 5171 titles, of which 128 (representing 44 laboratory-based outcomes) were selected. Nine were significantly associated with mortality, in order of decreasing scaled effect size: (1) tumor necrosis factor-α, (2) hematocrit, (3) interleukin-6, (4) troponin T, (5) Kt/V_urea, (6) prealbumin, (7) urea reduction ratio, (8) serum albumin, and (9) C-reactive protein. Other oft-cited measures such as calcium phosphate product and parathyroid hormone were not significantly associated with mortality in pooled analysis. Quality improvement efforts to improve traditional laboratory-based outcomes in end-stage renal disease are necessary, but likely insufficient, to improve overall mortality in dialysis. Renewed consideration of cardiovascular, inflammatory, and nutritional markers that are especially strong predictors of mortality may have important implications for risk stratification and targeted therapeutic interventions.     

A blockchain-based approach for a multi-echelon sustainable supply chain

Blockchain technology is destined to revolutionise supply chain processes. At the same time, governmental and regulatory policies are forcing firms to adjust their supply chains in response to environmental concerns. The objective of this study is therefore to develop a distributed ledger-based blockchain approach for monitoring supply chain performance and optimising both emission levels and operational costs in a synchronised fashion, producing a better outcome for the supply chain. We propose the blockchain approach for different production allocation problems within a multi-echelon supply chain (MESC) under a carbon taxation policy. As such, we couple recent advances in digitalisation of operations with increasingly stringent regulatory environmental policies. Specifically, with lead time considerations under emission rate constraints (imposed by a carbon taxation policy), we simultaneously consider the production, distribution and inventory control decisions in a production allocation-based MESC problem. The problem is then formulated as a Mixed Integer Non-Linear Programming (MINLP) model. We show that the distributed ledger-based blockchain approach minimises both total cost and carbon emissions. We then validate the feasibility of the proposed approach by comparing the results with a non-dominated sorting genetic algorithm (NSGA-II). The findings provide support for policymakers and supply chain executives alike.     

On the information improvement due to 2 and N revisions

The idea of information improvement was introduced by Theil in 1967. This idea is further extended in this paper to information improvement due to 2 and N revisions. These measures are characterized by a generalized functional equation. Some related properties of information improvement due to N revisions are also mentioned.     

Generalized error bounds in pattern recognition

Upper as well as lower bounds on the probability of error for the general pattern classification problem are obtained in terms of generalized entropy. It is proved that the bounds studied here are sharper than several previously known ones. Some properties of generalized entropy are also given.