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排序方式: 共有399条查询结果,搜索用时 31 毫秒
1.
Mariana Ušáková Jozef Lukáč Rastislav Dosoudil Vladimír Jančárik Anna Grusková Elemír Ušák Jozef Sláma Jan Šubrt 《Journal of Materials Science: Materials in Electronics》2007,18(12):1183-1189
The paper is devoted to the preparation of NiZn ferrite with small substitutions of copper by means of ceramic technology.
The influence of small Cu substitution on the microstructural and magnetic properties of NiZn ferrites have been analysed
by means of various experimental methods and interpreted from the point of view of preparation technology optimisation and
possible applications of such materials. A strong correlation between the substituent content and resulting properties has
been observed, thus allowing preparation of material with the properties tailored for any particular application. 相似文献
2.
This contribution summarizes our recent efforts to unravel the radical chemistry of autoxidations. Abstraction of the weakly bonded αH-atom of the primary hydroperoxide product by chain carrying peroxyl radicals is identified as the source of major end products such as alcohol and ketone/aldehyde. In the case of cyclohexane autoxidation, this reaction is even responsible for the majority of ring-opened by-products. In a second part, different approaches to autoxidation catalysis are discussed, ranging from transition metal ion catalysis to organocatalysis with immobilized N-hydroxyphthalimide. 相似文献
3.
Jozef P H Linssen Anneloes L G M Janssens Hanneke C E Reitsma Wender L P Bredie Jacques P Roozen 《Journal of the science of food and agriculture》1993,61(4):457-462
Taste recognition threshold concentrations (TRTC) of styrene were determined in samples of oil-in-water emulsions (30–300 g kg?1 oil) and yoghurts (1–30 g kg?1 fat), spiked with styrene. The observed TRTC increased linearly with increasing fat content and ranged from 0–3 to 2–1 mg kg?1 for the emulsions and from 36 to 171 g kg?1 for the yoghurts. Styrene equilibrium partition coefficients between emulsions and their respective vapour phases were determined. The concentrations of styrene in the continuous aqueous phase of the emulsions and yoghurts were calculated at the TRTC. The styrene concentrations in the continuous phase had constant values of about 15 g kg?1 indicating that perception of styrene for oil-in–water emulsions is determined by the aqueous phase of the emulsion. The concentrations of styrene in the vapor phases above the emulsions and yoghurts were also calculated and were found to be constant at the TRTC. This relationship probably resulted from the equilibrium of distribution of styrene between the respective phases. Commercial yoghurt packed in polystyrene beakers contained styrene levels in the range 2–11 g kg?1, much lower then the TRTC reported. 相似文献
4.
5.
Jozef Kula Magdalena Sikora Robert Dabrowski 《Journal of the American Oil Chemists' Society》1994,71(5):545-546
A one-step procedure is described for the synthesis of (E)-2-nonenal from commercial castor oil by ozonolysis in methanol, followed by reduction of the ozonide products with dimethyl
sulfide and exposure of the resulting intermediate product to dilute sulfuric acid. The developed process allows the production
of the aldehyde with a yield of 80% at a purity of 95%. The method has advantages over all those reported earlier, because
of inexpensive raw material and reducing agent, recycling of the solvent and its unusual simplicity. 相似文献
6.
A range of 18 diesel fuels and 21 kerosene fuels from mainly Australian petroleum and synthetic fuel sources, including coal, shale and peat, was investigated. Compositional details were defined as the weight per cent abundances of n-alkanes, branched plus cyclic saturates, single-ring aromatics, doublering aromatics and polynuclear aromatics, using both h.p.l.c. and 13C n.m.r. techniques. Relationships between fuel composition and a range of fuel properties were sought. Simple linear relationships between property values and compositional data were used. Explicit correlative expressions were derived using multiple linear regression analysis, with the coefficient of multiple determination, R2, indicating the quality of the fit between observed and calculated property values. In most cases good correlations were achieved. For diesels the properties investigated, with R2 values in parentheses, were: inverse specific gravity (0.99); 13C n.m.r. aromaticity (0.99); 1H n.m.r. aromaticity (0.88); cetane index (0.97); aniline point (0.96); diesel index (0.98); and FIA-measured aromatics content (0.77). For kerosenes the properties, with R2 values in parentheses, were: 13C n.m.r. aromaticity (0.98); 1H n.m.r. aromaticity (0.97); smoke point (0.88); and FIA-measured aromatics content (0.94). The results are shown to be of value in assessing the potential and limitations of hydrotreating as a process for upgrading synfuels. 相似文献
7.
Copper–graphite composite materials in the range of 0–10 vol% of carbon phase were prepared from the mixture of copper and graphite powders by hot isostatic pressing. The microstructure, mechanical (tensile strength, elongation to fracture) and physical (electrical and thermal conductivity) properties of composite samples were investigated, and the cross-property connections were calculated. It was shown that electrical and thermal conductivity cross-property (Lorenz number) is almost constant and increases only slightly (no more than 10 % increase was observed). This implies that in the investigated composition range the Lorenz number of a copper–graphite composite system behaves according to Franz–Wiedemann law for pure metals at constant temperature. On the contrary, the conductivity to tensile strength cross-property connections showed significant linear increase (over 200 % in the investigated composition range) for both electrical conductivity and thermal conductivity of composite materials. The cross-property connections of conductivity to the elongation to fracture exhibit a nonlinear dependence on the volume fraction of graphite. 相似文献
8.
9.
Slow and fast diffusion effects in image processing 总被引:3,自引:0,他引:3
A mathematical model for a nonlinear image multiscale analysis is studied. Processing of an image is based on a solution of
the strongly nonlinear parabolic partial differential equation, which can degenerate depending on values of the greylevel
intensity function. The governing PDE is a generalization of the regularized (in the sense of Catté, Lions, Morel and Coll)
Perona-Malik anisotropic diffusion equation. We present numerical techniques for solving the suggested initial-boundary value
problem and also existence and convergence results. Numerical experiments are discussed.
Received: 6 May 1998 / Accepted: 27 July 2000 相似文献
10.
Harri Tuomisto Petra Lundstrm Ritva Korhonen Jzsef Elter Milan Hladký Jozef Tomek Ludovít Fagula 《Nuclear Engineering and Design》2003,221(1-3):181
There are twelve operating VVER-440/213 reactors in the Czech Republic, Hungary and Slovakia. The plant owners have carried out extensive safety enhancement programmes, which have included measures to improve prevention, mitigation and control of design basis accidents. Recently, there have been a number of projects to study the Severe Accident Management aspects of these plants. The plant owners have also initiated Plant Life Management programmes. The objective of the VERSAFE Concerted Action is to create a network of the VVER-440/213 plant owners and operators, which aims at definition of the further research needs of severe accidents and plant ageing from the utilities’ viewpoint. The starting point is to formulate a general approach to severe accident management and plant life management and then proceed to define the needs for the additional information expected from the safety research. The role of national research institutes and organisations of the partner countries is of crucial importance in performing such research and, thus, creating and maintaining the expertise on the national level. The successful completion of the project will assist in establishing well-defined research projects that are oriented to the needs of the end-users and provide information that can be used to facilitate and support the negotiations of the EU applicant countries operating VVER-440 reactors. 相似文献