Quantum correlations at negative absolute temperatures

We study behavior of quantum discord, a kind of quantum correlation, in systems of dipole–dipole interacting spins in an external magnetic field in the whole temperature range ( \(-\infty ). It was shown that negative temperatures, which are introduced to describe inversions in the population in a finite level system, provide more favorable conditions for emergence of quantum correlations including entanglement. We show that at negative temperature, the correlations become more intense and discord exists between remote spins being in separated states.     

How entrepreneurial practices balance art and business: Insights into creative entrepreneurship in the European film industry

Relying on the literature on tensions and contradictions and the theory of practice, coupled with the literature on creative industries, this study uncovers how creative entrepreneurs balance the tension between art and business and respond to other challenges of creative entrepreneurship. The multiple case studies method is adopted by examining founders, cofounders and main employees of European film production companies. We reveal the perception of creative entrepreneurs towards the relationship between art and business. We explore different organizational and industry-level challenges experienced by creative entrepreneurs and uncover the organizational practices they adopt to deal with the identified challenges. The research contributes to the phenomenon of creative entrepreneurship by introducing the practice perspective, to the literature on paradox and contradiction by exploring the micro-foundations of tensions and paradox responses in high-intensity situations and to practice-based studies by investigating a domain-specific practice theory and highlighting the agency of creative entrepreneurs in adapting practices necessary to deal with conflicting demands of creative entrepreneurship.     

Airline planning benchmark problems—Part I:: Characterising networks and demand using limited data

This paper is the first of two papers entitled “Airline Planning Benchmark Problems”, aimed at developing benchmark data that can be used to stimulate innovation in airline planning, in particular, in flight schedule design and fleet assignment. While optimisation has made an enormous contribution to airline planning in general, the area suffers from a lack of standardised data and benchmark problems. Current research typically tackles problems unique to a given carrier, with associated specification and data unavailable to the broader research community. This limits direct comparison of alternative approaches, and creates barriers of entry for the research community. Furthermore, flight schedule design has, to date, been under-represented in the optimisation literature, due in part to the difficulty of obtaining data that adequately reflects passenger choice, and hence schedule revenue. This is Part I of two papers taking first steps to address these issues. It does so by providing a framework and methodology for generating realistic airline demand data, controlled by scalable parameters. First, a characterisation of flight network topologies and network capacity distributions is deduced, based on the analysis of airline data. Then a multi-objective optimisation model is proposed to solve the inverse problem of inferring OD-pair demands from passenger loads on arcs. These two elements are combined to yield a methodology for generating realistic flight network topologies and OD-pair demand data, according to specified parameters. This methodology is used to produce 33 benchmark instances exhibiting a range of characteristics. Part II extends this work by partitioning the demand in each market (OD pair) into market segments, each with its own utility function and set of preferences for alternative airline products. The resulting demand data will better reflect recent empirical research on passenger preference, and is expected to facilitate passenger choice modelling in flight schedule optimisation.     

The Role of Circulating Biomarkers in Peripheral Arterial Disease

Peripheral arterial disease (PAD) of the lower extremities is a chronic illness predominantly of atherosclerotic aetiology, associated to traditional cardiovascular (CV) risk factors. It is one of the most prevalent CV conditions worldwide in subjects >65 years, estimated to increase greatly with the aging of the population, becoming a severe socioeconomic problem in the future. The narrowing and thrombotic occlusion of the lower limb arteries impairs the walking function as the disease progresses, increasing the risk of CV events (myocardial infarction and stroke), amputation and death. Despite its poor prognosis, PAD patients are scarcely identified until the disease is advanced, highlighting the need for reliable biomarkers for PAD patient stratification, that might also contribute to define more personalized medical treatments. In this review, we will discuss the usefulness of inflammatory molecules, matrix metalloproteinases (MMPs), and cardiac damage markers, as well as novel components of the liquid biopsy, extracellular vesicles (EVs), and non-coding RNAs for lower limb PAD identification, stratification, and outcome assessment. We will also explore the potential of machine learning methods to build prediction models to refine PAD assessment. In this line, the usefulness of multimarker approaches to evaluate this complex multifactorial disease will be also discussed.     

Distribution of lengths in the breakage of fibres or linear polymers

The distribution of fiber or polymer lengths during breakage is considered. It is shown that under certain conditions the distribution of lengths is given by a self-preserving form which is independent of the initial distribution and is not explicitly dependent on time. Some self-preserving distributions are calculated. The theory is compared with an experiment on the breakage of glass fibres caused by milling.     

Poly(lactide)/cellulose nanocrystal nanocomposites by high-shear mixing

There is currently considerable interest in developing stiff, strong, tough, and heat resistant poly(lactide) (PLA) based materials with improved melt elasticity in response to the increasing demand for sustainable plastics. However, simultaneous optimization of stiffness, strength, and toughness is a challenge for any material, and commercial PLA is well-known to be inherently brittle and temperature-sensitive and to show poor melt elasticity. In this study, we report that high-shear mixing with cellulose nanocrystals (CNC) leads to significant improvements in the toughness, heat resistance, and melt elasticity of PLA while further enhancing its already outstanding room temperature stiffness and strength. This is evidenced by (i) one-fold increase in the elastic modulus (6.48 GPa), (ii) 43% increase in the tensile strength (87.1 MPa), (iii) one-fold increase in the strain at break (∼6%), (iv) two-fold increase in the impact strength (44.2 kJ/m²), (v) 113-fold increase in the storage modulus at 90°C (787.8 MPa), and (vi) 10³-fold increase in the melt elasticity at 190°C and 1 rad/s (∼10⁵ Pa) via the addition of 30 wt% CNC. It is hence possible to produce industrially viable, stiff, strong, tough, and heat resistant green materials with improved melt elasticity through high-shear mixing.     

Determination of the quality and purity characteristics of olive oils obtained from different regions of Turkey,depending on climatic changes

Virgin olive oils (VOOs) obtained from olives grown in different regions of Turkey under changing climatic conditions sometimes show different sensory and chemical properties. This study was planned to determine whether these deviations are due to climatic changes or not. For this purpose, five different olive varieties (Ayvalık, Memecik, Gemlik, Nizip Yağlık, Kilis Yağlık) of commercial importance were harvested from the provinces/districts (four different region) where cultivation is intense during the 2017/2018–2020/2021 harvest years. Every year, olive samples were collected from 3 orchards from 13 provinces/districts. One hundred and fifty-six samples were subjected to the purity, quality and sensory analysis. Basic climatic values (average, minimum and maximum temperature, humidity and precipitation) were examined for four consecutive years. All of the examined olive oil samples were determined within the legal limits in terms of fatty acid composition and fatty acid ethyl ester values. However, delta-7-stigmastenol value from the sterol composition was found to be above 0.5% in some samples in all the years studied (total 21 samples). Delta-7-stigmastenol values of olive oil samples varied between 0.16% and 1.14%. Multiple linear regression analysis was applied using a genetic algorithm-based inverse least squares method to determine whether there is a relationship between climate data and delta-7-stigmastenol values. According to this result, it has been determined that the delta-7-stigmastenol value is high when the annual average relative humidity is low and the annual average temperature is high. There is an urgent need to make forward-looking plans due to climate change.