Thermal annealing effect on zinc nitride thin films deposited by reactive rf-magnetron sputtering process

Zinc nitride films were deposited by reactive radio-frequency magnetron sputtering using a zinc target in a nitrogen and argon plasma. The deposited films were annealed in either air or O₂ at 300 °C to investigate the annealing effect on the microstructure, optical properties, and electronic characteristics of zinc nitride films. It was found that the annealing process decreased the crystallinity of zinc nitride films. It was also found that the optical band gap decreased from 1.33 eV to 1.14 eV after annealing. The analysis of film composition suggested that the concentration of oxygen increased slightly after annealing. Although the conduction type of both as-deposited and annealed films were n-type, the annealed films exhibited a higher resistivity, lower carrier concentration and lower mobility than the as-deposited films. Also, it was found that the as-deposited films did not exhibit any photoconducting behavior whereas the annealed films exhibited a pronounced photoconducting behavior.     

A low-power 72.8-GHz static frequency divider in AlInAs/InGaAs HBTtechnology

We report a 72.8-GHz fully static frequency divider in AlInAs/InGaAs HBT IC technology. The CML divider operates with a 350-mV logic swing at less than 0-dBm input power up to a maximum clock rate of 63 GHz and requires 8.6 dBm of input power at the maximum clock rate of 72.8 GHz. Power dissipation per flip-flop is 55 mW with a 3.1-V power supply. To our knowledge, this is the highest frequency of operation for a static divider in any technology. The power-delay product of 94 fJ/gate is the lowest power-delay product for a circuit operating above 50 GHz in any technology. A low-power divider on the same substrate operates at 36 GHz with 6.9 mW of dissipated power per flip-flop with a 3.1-V supply. The power delay of 24 fJ/gate is, to our knowledge, the lowest power-delay product for a static divider operating above 30 GHz in any technology. We briefly review the requirements for benchmarking a logic family and examine the historical trend of maximum clock rate in high-speed circuit technology     

Tailoring of Electromagnetic Absorption in Substituted Hexaferrites from 8.2 GHz to 12.4 GHz

Journal of Electronic Materials - Microwave absorbers are an important topic of interest to mitigate electromagnetic interference. Here, we have investigated electromagnetic absorption properties...     

Conformal Band Notched Circular Monopole Antenna Loaded with Split Ring Resonator

This article presents the design and analysis of conformal circular monopole antenna with split ring resonator to get frequency notch characteristics in the wideband. Split ring resonators placed on one side of the substrate and complementary split ring resonators placed on the other side of the substrate at defected ground structure, which yields the frequency notch characteristics with respect to the microstrip feeding. Dual notch band characteristics are obtained between 4–4.3 and 7.3–8.1 GHz. The analyzed conformal characteristic of the antenna supports excellent constant reflection coefficient characteristics over the band at different angles. The impedance and radiation characteristics of the antenna model is analysed in simulation along with unit cell analysis of the SRR and the measured results are providing good agreement with them.     

Deformation and water loss from solvent filled microcapsules under compressive loads

Microcapsules filled with liquid solvents for CO₂ absorption can be easily deformed due to their elastic polymer shells. We present a combination of experiments and model predictions to demonstrate that modest compressive forces can lead to significant capsule deformation and performance issues for this enabling technology. Contrary to expectations based on Raoult's law, capsules containing aqueous carbonate solution were found to lose water to flows of humidified nitrogen in centimeter-scale packed beds. Water loss increased with gas velocity, suggesting compression was responsible for mass transfer, an interpretation supported by microscope images of deformed and broken capsules. A model for compression induced mass transfer under packed/fluidized bed operating conditions was developed and validated with the experimental data for a range of conditions (gas velocities, temperatures, humidities). Design criteria for future generations of microcapsules that will more effectively resist compression are evaluated.     

Highly selective homogeneous ethylene epoxidation in gas (ethylene)‐expanded liquid: Transport and kinetic studies

Recently a homogeneous liquid‐phase ethylene oxide (EO) process with nearly total EO selectivity, catalyzed by methyltrioxorhenium with H₂O₂ as an oxidant, was reported. Fundamental mass transfer and kinetic studies of this reaction are reported in the present work. Volumetric expansion studies revealed that the liquid reaction phase (methanol + H₂O₂/H₂O) is expanded by up to 12% by compressed ethylene in the 20–40^°C range and up to 50 bars. This represents an increase in ethylene solubility by approximately one‐order of magnitude, attributed to the unique exploitation of near‐critical ethylene (P_c = 50.76 bar; T_c = 9.5^°C). Interphase mass‐transfer coefficients for ethylene dissolution into the liquid phase were obtained experimentally. Operating at conditions that enhanced the ethylene solubility and eliminated interphase mass‐transfer limitations maximized the EO productivity (1.61–4.97 g EO/h/g cat), rendering it comparable to the conventional process. Intrinsic kinetic parameters, estimated from fixed‐time semibatch reactor studies, disclosed the moderate activation energy (57 ± 2 kJ/mol). © 2012 American Institute of Chemical Engineers AIChE J, 59: 180–187, 2013     

Reinforced Stone Columns in Weak Deposits: Laboratory Model Study

This paper investigates the performance of stone columns in a weak deposit such as peat. It evaluates the effects of reinforcing stone columns by jacketing with a tubular wire mesh and bridging reinforcement with a metal rod and a concrete plug. A series of plate loading tests was conducted on isolated stone columns installed in a soil bed consisting of a peat layer sandwiched between two layers of sand. The load–displacement characteristics of footings supported by stone columns were investigated by applying load to a circular plate supported on: (a) untreated soil; (b) soil treated with stone columns; and (c) soil treated with stone columns reinforced with the above reinforcing techniques. The work has shown that the settlement characteristics of the soil can be improved by installing stone columns and that a significant enhancement in the load–settlement response is achieved when the columns are reinforced by the various methods.     

Scheduling on Unrelated Machines under Tree-Like Precedence Constraints

We present polylogarithmic approximations for the R|prec|C _max and R|prec|∑ _j w _j C _j problems, when the precedence constraints are “treelike”—i.e., when the undirected graph underlying the precedences is a forest. These are the first non-trivial generalizations of the job shop scheduling problem to scheduling with precedence constraints that are not just chains. These are also the first non-trivial results for the weighted completion time objective on unrelated machines with precedence constraints of any kind. We obtain improved bounds for the weighted completion time and flow time for the case of chains with restricted assignment—this generalizes the job shop problem to these objective functions. We use the same lower bound of “congestion + dilation”, as in other job shop scheduling approaches (e.g. Shmoys, Stein and Wein, SIAM J. Comput. 23, 617–632, 1994). The first step in our algorithm for the R|prec|C _max problem with treelike precedences involves using the algorithm of Lenstra, Shmoys and Tardos to obtain a processor assignment with the congestion + dilation value within a constant factor of the optimal. We then show how to generalize the random-delays technique of Leighton, Maggs and Rao to the case of trees. For the special case of chains, we show a dependent rounding technique which leads to a bicriteria approximation algorithm for minimizing the flow time, a notoriously hard objective function. A preliminary version of this paper appeared in the Proc. International Workshop on Approximation Algorithms for Combinatorial Optimization Problems (APPROX), pages 146–157, 2005. V.S. Anil Kumar supported in part by NSF Award CNS-0626964. Part of this work was done while at the Los Alamos National Laboratory, and supported in part by the Department of Energy under Contract W-7405-ENG-36. M.V. Marathe supported in part by NSF Award CNS-0626964. Part of this work was done while at the Los Alamos National Laboratory, and supported in part by the Department of Energy under Contract W-7405-ENG-36. Part of this work by S. Parthasarathy was done while at the Department of Computer Science, University of Maryland, College Park, MD 20742, and in part while visiting the Los Alamos National Laboratory. Research supported in part by NSF Award CCR-0208005 and NSF ITR Award CNS-0426683. Research of A. Srinivasan supported in part by NSF Award CCR-0208005, NSF ITR Award CNS-0426683, and NSF Award CNS-0626636.