KINETICS FOR LOW TEMPERATURE PYROLYSIS OF BLACK LIQUOR

A kinetic study of pyrolysis of dried black liquor was performed using a Netzsch 429 Thermogravimetric Analyzer. It was found that as conversion increases from 10 to 45% the apparent pyrolysis activation energy for black liquor increases from 77.20 to 112.74 KJ/mol. For black liquor the order of reaction was found to be first-order. The reaction rate constant was found to be 2.12×10⁹ min. These results are in agreement with the data reported by other investigators on biomass pyrolysis.     

Morphological changes in poly(?-caprolactone) in dense carbon dioxide

Morphological changes that take place in poly(?-caprolactone) upon exposure to carbon dioxide at high pressures have been explored as a function of pressure and temperature. SEM and DSC results point to a competition between CO₂-modulated crystallization and pressure-induced phase separation which leads to unique morphologies. At 293 K, exposure to CO₂ at pressures up to 45 MPa leads to recrystallization resulting in higher level of crystallinity and higher melting temperatures. Highest crystallinity levels along with distinct crystal morphology were observed after exposure to CO₂ at 308 K and 21 MPa. At a higher pressure at this temperature (308 K/34 MPa) polymer undergoes melting, and foaming is achieved during depressurization prior to solidification. At 323 K, the polymer is found to display unique crystal morphology with concave crystal geometry as well as porous domains. The results are discussed in terms of the crystallization and phase separation paths that are followed during exposure to CO₂ and the depressurization stages.     

Assessment of the effectiveness of the educational environment supported by computer aided presentations at primary school level

The objective of this study is to assess the effectiveness of the educational environment supported by computer aided presentations at primary school. The effectiveness of the environment has been evaluated in terms of students’ learning and remembering what they have learnt. In the study, we have compared experimental group and control group in terms of learning and recalling what has been learned regarding the effect which computer aided learning environment imposes. Data have been collected through the control grouped pretest–final test model. During the experiment, we have prepared an achievement test, which explains behaviors the students should acquire. According to the findings obtained, a computer aided educational environment has been observed to be more effective than that of conventional education in terms of learning. However, in terms of the permanence of what has been learned, no meaningful difference between the educational environment supported by computer aided presentations and that of conventional education has come out. According to the results of the follow-up tests performed, even though students in the test group have forgotten more of what they have learnt, it has been concluded that students in both groups have forgotten on the same level. Consequently, it has been observed that though the educational environment supported by computer aided presentations has positive contributions to learning activity, it does not have effects on the permanence of what has been learnt.     

Routing table updating by using intelligent agents

In a network, one of the important problems is making an efficient routing decision. Many studies have been carried out on making a decision and several routing algorithms have been developed. In a network environment, every node has a routing table and these routing tables are used for making routing decisions. Nowadays, intelligent agents are used to make routing decisions. Intelligent agents have been inspired by social insects such as ants. One of the intelligent agent types is self a cloning ant. In this study, a self cloning ant colony approach is used. Self cloning ants are a new synthetic ant type. This ant assesses the situation and multiplies through cloning or destroying itself. It is done by making a routing decision and finding the optimal path. This study explains routing table updating by using the self cloning ant colony approach. In a real net, this approach has been used and routing tables have been created and updated for every node.     

Fiber grating spectra

In this paper, we describe the spectral characteristics that can be achieved in fiber reflection (Bragg) and transmission gratings. Both principles for understanding and tools for designing fiber gratings are emphasized. Examples are given to illustrate the wide variety of optical properties that are possible in fiber gratings. The types of gratings considered include uniform, apodized, chirped, discrete phase-shifted, and superstructure gratings; short-period and long-period gratings; symmetric and tilted gratings; and cladding-mode and radiation-mode coupling gratings     

Predicting crack propagation with peridynamics: a comparative study

The fidelity of the peridynamic theory in predicting fracture is investigated through a comparative study. Peridynamic predictions for fracture propagation paths and speeds are compared against various experimental observations. Furthermore, these predictions are compared to the previous predictions from extended finite elements (XFEM) and the cohesive zone model (CZM). Three different fracture experiments are modeled using peridynamics: two experimental benchmark dynamic fracture problems and one experimental crack growth study involving the impact of a matrix plate with a stiff embedded inclusion. In all cases, it is found that the peridynamic simulations capture fracture paths, including branching and microbranching that are in agreement with experimental observations. Crack speeds computed from the peridynamic simulation are on the same order as those of XFEM and CZM simulations. It is concluded that the peridynamic theory is a suitable analysis method for dynamic fracture problems involving multiple cracks with complex branching patterns.     

Performance of a Tied-Arch Reinforced Concrete Railway Bridge: Rating, Safety Assessment, and Bond Length Evaluation

This study presents investigations regarding visual inspection, dynamic testing, and finite-element modeling of an approximately 80-year old reinforced concrete tied-arch railway bridge that is still in service in Turkey. Investigations were conducted as part of a systematic periodic inspection along Ankara-Zonguldak railway line. The bridge is subject to heavy freight trains with increasing axle loads. Field tests such as material tests and dynamic tests were used to calibrate the finite-element model of the bridge. Detailed information regarding testing and model updating procedure is given. Based on test results, computer model was refined. The calibrated model of the bridge structure was then used for structural assessment and evaluation. Despite sufficient overall safety, local details were found to be problematic. Due to insufficient bond length in hanger-to-arch connection, a strengthening scheme using steel channel sections was proposed.     

Filament-activated chemical vapour deposition of nitride thin films

We have applied the novel method of hot filament-activated chemical vapour deposition (HFCVD) for low-temperature deposition of a variety of nitride thin films. In this paper the results from our recent work on aluminium, silicon and titanium nitride have been reviewed. In the HFCVD method a hot tungsten filament (1500–1850°C) was utilised to decompose ammonia in order to deposit nitride films at low substrate temperatures and high rates. The substrate temperatures ranged from 245 to 600°C. The film properties were characterised by a number of analytical and optical methods. The effect of various deposition conditions on film properties was studied. All the films obtained were of high chemical purity and had very low or no detectable tungsten contamination from the filament metal.     

Influence of Growth Rate on Eutectic Spacing,Microhardness, and Ultimate Tensile Strength in the Directionally Solidified Al-Cu-Ni Eutectic Alloy

Metallurgical and Materials Transactions B - In this work, the mechanical properties of the Al-Cu-Ni eutectic alloy, Al-32.5 wt pct Cu-1 wt pct Ni, were investigated in terms of...