全文获取类型
收费全文 | 1879篇 |
免费 | 108篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 10篇 |
综合类 | 2篇 |
化学工业 | 824篇 |
金属工艺 | 36篇 |
机械仪表 | 21篇 |
建筑科学 | 45篇 |
矿业工程 | 7篇 |
能源动力 | 38篇 |
轻工业 | 312篇 |
水利工程 | 9篇 |
石油天然气 | 9篇 |
无线电 | 71篇 |
一般工业技术 | 313篇 |
冶金工业 | 88篇 |
原子能技术 | 2篇 |
自动化技术 | 203篇 |
出版年
2024年 | 6篇 |
2023年 | 38篇 |
2022年 | 197篇 |
2021年 | 193篇 |
2020年 | 55篇 |
2019年 | 60篇 |
2018年 | 76篇 |
2017年 | 60篇 |
2016年 | 71篇 |
2015年 | 57篇 |
2014年 | 83篇 |
2013年 | 138篇 |
2012年 | 96篇 |
2011年 | 121篇 |
2010年 | 95篇 |
2009年 | 95篇 |
2008年 | 108篇 |
2007年 | 56篇 |
2006年 | 70篇 |
2005年 | 58篇 |
2004年 | 49篇 |
2003年 | 30篇 |
2002年 | 39篇 |
2001年 | 18篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 16篇 |
1997年 | 6篇 |
1996年 | 15篇 |
1995年 | 7篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1990年 | 2篇 |
1989年 | 5篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1978年 | 3篇 |
1977年 | 5篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1964年 | 1篇 |
1911年 | 2篇 |
排序方式: 共有1990条查询结果,搜索用时 15 毫秒
1.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
2.
Fernando J Beltrn F Javier Rivas Olga Gimeno 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(9):973-984
Photocatalytic ozonation (1O3 + VUV + TiO2), ozonation (O3), catalytic ozonation (O3 + TiO2), ozone photolysis (O3 + VUV), photocatalysis (TiO2 + VUV) and photolysis (VUV) have been compared in terms of formation of intermediates, extent of, mineralization (TOC, COD, chloride, nitrate) and kinetics in the aqueous treatment of three phenols (phenol, p‐chlorophenol and p‐nitrophenol). In all cases, photocatalytic ozonation led to lower degradation times for chemical oxygen demand and total organic carbon removal. Intermediates formed were similar in the different oxidation systems with some exceptions. They can be classified into three different types: polyphenols (resorcinol, catechol, hydroquinone), unsaturated carboxylic acids (maleic and fumaric acids) and saturated carboxylic acids (glyoxylic, formic and oxalic acids). First order kinetic equations have been checked for the oxidation processes studied in the case of the parent compound. Rate constants of these systems have also been calculated. Copyright © 2005 Society of Chemical Industry 相似文献
3.
Sandra Aparecida de Assis Pedro Fernandes Bruno Sommer Ferreira Joaquim MS Cabral Olga Maria Mascarenhas Faria Oliveira 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2004,79(3):277-280
A partially purified extract of pectinmethylesterase (PME) from acerola fruit was immobilized on various supports: glass, celite, chrysotile, agarose, concanavalin A Sepharose 4B, egg shell, polyacrylamide and gelatin. In addition, reticulation with glutaraldehyde was assessed, as well as the use of gelatin in the presence of celite, glass and silica. The highest immobilization yields were obtained when the pectinmethylesterase was immobilized in concanavalin A Sepharose 4B (81.7%) and in gelatin‐water (78.0%). Copyright © 2004 Society of Chemical Industry 相似文献
4.
Yong-Seo Park Seong-Gook Kang Alma Leticia Martinez Ayala Olga Martín-Belloso Shela Gorinstein 《LWT》2006,39(7):748-755
Fresh persimmons were subjected to two different processes: sun-drying during 1 month and dehydration at 60 °C during 12 h. To assess the effect of this process on nutritional and health-related properties of persimmons dietary fibers, minerals, trace elements, polyphenols and the total radical scavenging activities (TRSAs) were determined before and after processing. It was found that the contents of dietary fibers, minerals and trace elements in fresh and dried persimmons fruits were comparable. Total polyphenols in fresh persimmons was higher than in dried fruits (1.3 vs. 0.9 and 0.8 mg/100 g FW, respectively) and percentage of inhibition was higher than in dried fruits (70% vs. 59% and 55% and 58% vs. 53% and 46% for 1,1-diphenyl-2-picrylhydrazyl (DPPH) and 2,2′-azino-bis (3-ethylbenzthiazoline-6-sulfonic acid) [ABTS] radicals, respectively (P>0.05 in all cases). In conclusion: (1) the differences in the contents of dietary fibers, minerals and trace elements in fresh and dried persimmons are not significant; (2) the contents of polyphenols and the level of the TRSA are higher in fresh persimmons than in dried fruits; however, both variables are also high in dried persimmons; (3) when fresh fruits are not available, proper dried persimmons could be used as a valuable substitute. 相似文献
5.
Olga Porembskaya Vsevolod Zinserling Vladimir Tomson Yana Toropova Eleonora A. Starikova Vitaliy V. Maslei Nika I. Bulavinova Olga V. Kirik Marina A. Syrtsova Leonid Laberko Maxim I. Galchenko Vyacheslav Kravchuk Sergey Saiganov Alexander Brill 《International journal of molecular sciences》2022,23(10)
Pulmonary embolism is a life-threatening condition, which can result in respiratory insufficiency and death. Blood clots occluding branches of the pulmonary artery (PA) are traditionally considered to originate from thrombi in deep veins (usually in legs). However, growing evidence suggests that occlusion of the vessels in the lungs can develop without preceding deep vein thrombosis (DVT). In this work, we used an inferior vena cava (IVC) complete ligation model of DVT in Wistar rats to explore the possibility and mechanisms of PA thrombosis under the conditions where all routes of thrombotic mass migration from peripheral veins are blocked. We demonstrate that rats both with normal and reduced neutrophil counts developed thrombi in the IVC, although, neutropenia caused a substantial decrease in thrombus size and a shift from fresh fibrin toward mature fibrin and connective tissue inside the thrombus. Massive fibrin deposition was found in the PA branches in the majority of DVT rats with normal neutrophil counts, but in none of the neutropenic animals. Neutrophil ablation also abolished macroscopic signs of lung damage. Altogether, the results demonstrate that thrombi in the lung vasculature can form in situ by mechanisms that require local neutrophil recruitment taking place in the DVT setting. 相似文献
6.
Aleksandra A. Kuznetsova Olga S. Fedorova Nikita A. Kuznetsov 《International journal of molecular sciences》2022,23(12)
DNA polymerases catalyze DNA synthesis during the replication, repair, and recombination of DNA. Based on phylogenetic analysis and primary protein sequences, DNA polymerases have been categorized into seven families: A, B, C, D, X, Y, and RT. This review presents generalized data on the catalytic mechanism of action of DNA polymerases. The structural features of different DNA polymerase families are described in detail. The discussion highlights the kinetics and conformational dynamics of DNA polymerases from all known polymerase families during DNA synthesis. 相似文献
7.
Matilde Ortiz-Gonzalez Ignacio Prez-Victoria Inmaculada Ramirez-Macias Nuria de Pedro Angel Linde-Rodriguez Víctor Gonzlez-Menndez Victoria Sanchez-Martin Jesús Martín Ana Soriano-Lerma Olga Genilloud Virginia Perez-Carrasco Francisca Vicente Jos Maceira Carlos A. Rodrígues-Poveda Jos María Navarro-Marí Fernando Reyes Miguel Soriano Jose A. Garcia-Salcedo 《International journal of molecular sciences》2022,23(11)
8.
Joanna ebrowska Olga onierkiewicz Magorzata Ponikowska Micha Puchalski Natalia Krawczun Joanna Makowska Piotr Skowron 《International journal of molecular sciences》2022,23(14)
The obligatory step in the life cycle of a lytic bacteriophage is the release of its progeny particles from infected bacterial cells. The main barrier to overcome is the cell wall, composed of crosslinked peptidoglycan, which counteracts the pressure prevailing in the cytoplasm and protects the cell against osmotic lysis and mechanical damage. Bacteriophages have developed two strategies leading to the release of progeny particles: the inhibition of peptidoglycan synthesis and enzymatic cleavage by a bacteriophage-coded endolysin. In this study, we cloned and investigated the TP84_28 endolysin of the bacteriophage TP-84, which infects thermophilic Geobacillus stearothermophilus, determined the enzymatic characteristics, and initially evaluated the endolysin application as a non-invasive agent for disinfecting surfaces, including those exposed to high temperatures. Both the native and recombinant TP84_28 endolysins, obtained through the Escherichia coli T7-lac expression system, are highly thermostable and retain trace activity after incubation at 100 °C for 30 min. The proteins exhibit strong bacterial wall digestion activity up to 77.6 °C, decreasing to marginal activity at ambient temperatures. We assayed the lysis of various types of bacteria using TP84_28 endolysins: Gram-positive, Gram-negative, encapsulated, and pathogenic. Significant lytic activity was observed on the thermophilic and mesophilic Gram-positive bacteria and, to a lesser extent, on the thermophilic and mesophilic Gram-negative bacteria. The thermostable TP84_28 endolysin seems to be a promising mild agent for disinfecting surfaces exposed to high temperatures. 相似文献
9.
Karolina Dydak Adam Junka Grzegorz Nowacki Justyna Paleczny Patrycja Szymczyk-Zikowska Aleksandra Grzyska Olga Anioek Marzenna Bartoszewicz 《International journal of molecular sciences》2022,23(9)
Hernia repairs are the most common abdominal wall elective procedures performed by general surgeons. Hernia-related postoperative infective complications occur with 10% frequency. To counteract the risk of infection emergence, the development of effective, biocompatible and antimicrobial mesh adjuvants is required. Therefore, the aim of our in vitro investigation was to evaluate the suitability of bacterial cellulose (BC) polymer coupled with gentamicin (GM) antibiotic as an absorbent layer of surgical mesh. Our research included the assessment of GM-BC-modified meshes’ cytotoxicity against fibroblasts ATCC CCL-1 and a 60-day duration cell colonisation measurement. The obtained results showed no cytotoxic effect of modified meshes. The quantified fibroblast cells levels resembled a bimodal distribution depending on the time of culturing and the type of mesh applied. The measured GM minimal inhibitory concentration was 0.47 µg/mL. Results obtained in the modified disc-diffusion method showed that GM-BC-modified meshes inhibited bacterial growth more effectively than non-coated meshes. The results of our study indicate that BC-modified hernia meshes, fortified with appropriate antimicrobial, may be applied as effective implants in hernia surgery, preventing risk of infection occurrence and providing a high level of biocompatibility with regard to fibroblast cells. 相似文献
10.
Various shielding approaches to protect lunar habitats from micrometeoroid and radiation hazards present major trade-off considerations. Popular scenarios that envision covering modules with in situ regolith will necessitate means to excavate and move large amounts of material; will complicate evolutionary outpost growth; and may require long tunnels between connecting pressurized elements. Strategies that incorporate shielding materials into module structures or internal shelters add very substantial launch mass penalties. Utilization of water bladders can make efficient use of consumable/recyclable supplies, but may impose excess capacity deliveries at early development stages. This paper addresses these different shielding approaches from a top-level application perspective, highlighting pros and cons of each. Examples draw upon research and design investigations undertaken by the Sasakawa International Center for Space Architecture in support of separate National Aeronautics and Space Administration (NASA) contracts awarded to teams headed by Boeing and ILC-Dover for a “Minimum Functionality Habitation Systems Concept Study.” Comprehensive team study results were presented to NASA in February 2009, and have been released as public information. 相似文献