Pressure induced order-disorder transition in a diblock copolymer

Polymers are known to undergo order↔order and order↔disorder transitions, when subjected to a change of pressure, temperature, solvent, pH of the medium etc. The molecular processes, which alter the volume of the system, are found to be highly sensitive to the pressure. In the present communication Zimm and Bragg model of helix↔coil transition has been modified to interpret the experimental data of pressure induced phase transition in polystyrene-polybutadiene [PS-PB] at different pressurization rates, as reported by Migler and Han, utilizing the Birefringence and small angle neutron scattering technique. An expression for the degree of order is obtained from the grand partition function for the entire chain in terms of nucleation parameter, which controls the transition width. The nucleation parameter σ increases with the increase in the ODT temperatures of the system. The phenomenon of hysteresis has been discussed in relation to the pressurization rate, which increases/decreases with the corresponding increase/decrease in the pressurization rate. The theoretical transition curves are found to be in good agreement with experimental data.     

Scalable synthesis of aligned carbon nanotubes bundles using green natural precursor: neem oil

Practical application of aligned carbon nanotubes (ACNTs) would have to be determined by a matter of its economical and large-scale preparation. In this study, neem oil (also named Margoaa oil, extracted from the seeds of the neem--Azadirachta indica) was used as carbon source to fabricate the bundles of ACNTs. ACNTs have been synthesized by spray pyrolysis of neem oil and ferrocene mixture at 825°C. The major components of neem oil are hydrocarbon with less amount of oxygen, which provided the precursor species in spray pyrolysis growth of CNTs. The bundles of ACNTs have been grown directly inside the quartz tube. The as-grown ACNTs have been characterized through Raman spectroscopy, scanning and transmission electron microscopic (SEM/TEM) techniques. SEM images reveal that the bundles of ACNTs are densely packed and are of several microns in length. High-resolution TEM analysis reveals these nanotubes to be multi-walled CNTs. These multi-walled CNTs were found to have inner diameter between 15 and 30 nm. It was found that present technique gives high yield with high density of bundles of ACNTs.     

Guayule natural rubber composites: impact of fillers on their cure characteristics,dynamic and mechanical behavior

Guayule natural rubber (GNR) is an alternative resource of Hevea natural rubber (HNR) with 99.9% cis content in its 1,4-polyisoprene chemical backbone. In this study, compounds were formulated independently with four different reinforcing fillers such as carbon black (HAF), precipitated silica (VN3), fume silica (FUM) and nanofly ash (NFA) for the advancement of GNR based products. The cure characteristic, dynamic-mechanical performance and mechanical properties of GNR composite were studied with the reinforcing effect of different fillers on GNR. The cure characteristic results demonstrated that HAF and FUM silica filled compounds had more processing safety than VN3 and NFA filled compounds. Viscoelastic parameters of the vulcanizates were studied by dynamic mechanical analysis to estimate the glass transition characteristics and dynamic behavior. The higher storage modulus of FUM silica vulcanizate was an indication of superior filler reinforcing nature and improved rolling resistance than other filled systems. Additionally, HRTEM analysis also proved the better filler dispersion ability of FUM silica in GNR matrix. The mechanical properties were studied with a variation of each filler loading of 8, 16, and 32 phr in GNR vulcanizates. The tensile strength of each filled system increased with an increase of filler content from 8 to 32 phr. In comparison, FUM silica GNR vulcanizates exhibited better mechanical properties, therefore, it was considered as a better structure-performance composite than those of HAF, VN3 and NFA filled composites.

     

Phosphorylated cardanol prepolymer grafted guayule natural rubber: an advantageous green natural rubber

Natural rubber (HNR), produced from Hevea Brasiliensis, is being considered as the major source of 99.9% 1,4-cis-polyisoprene. Till date, this grade of natural rubber is not manufactured synthetically even using sophisticated solution polymerization techniques and utilizing the most advanced catalyst systems. Rubber industries have been continuously thriving for an alternative as well as an additional source of natural rubber to compensate for the reduction in production of Hevea natural rubber and to reduce the consumption of petroleum-based rubbers. The present study deals with chemical grafting of phosphorylated cardanol prepolymer (PCP) onto the main chain of guayule natural rubber (GNR), which could impart inherent multifunctional characteristics to the rubber. The grafting of PCP onto GNR was carried out successively using benzoyl peroxide as a free radical initiator in the solution stage and the grafting parameters have been optimized through the Taguchi method using grafting efficiency and percent grafting. Grafting of PCP onto GNR (PCP-g-GNR) was confirmed through UV–Visible, FTIR, NMR and GPC analysis. Thermal behavior of PCP-g-GNR indicates a significant increase in thermo-oxidative stability and it also displays a slight depression of glass transition temperature as compared to GNR. The viscoelastic characteristics of GNR also alter and cure characteristic improves drastically in giving rise to improved processability after grafting of the PCP. The unfilled PCP-g-GNR vulcanizates show approximately similar physico-mechanical properties with 5 phr processing oil as plasticized GNR vulcanizates. Therefore, PCP-g-GNR can be used in rubber industries as gum rubber materials as it reduces the usage of processing aids significantly.     

A study on measuring surface deformation of the L’Aquila region using the StaMPS technique

This research compares two time-series interferometric synthetic aperture radar (InSAR) methods, namely persistent scatterer SAR interferometry (PS-InSAR) and small baseline subset (SBAS) to retrieve the deformation signal from pixels with different scattering characteristics. These approaches are used to estimate the surface deformation in the L’Aquila region in Central Italy where an earthquake of magnitude Mw 6.3 occurred on 6 April 2009. Fourteen Environmental Satellite (ENVISAT) C-band Advanced Synthetic Aperture Radar (ASAR) images, covering the pre-seismic, co-seismic, and post-seismic period, are used for the study. Both the approaches effectively extract measurement pixels and show a similar deformation pattern in which the north-west and south-east regions with respect to the earthquake epicentre show movement in opposite directions. The analysis has revealed that the PS-InSAR method extracted more number of measurement points (21,103 pixels) as compared to the SBAS method (4886 pixels). A comparison of velocity estimates shows that out of 833 common pixels in both the methods, about 62% (517 pixels) have the mean velocity difference below 3 mm year^?1 and nearly 66% pixels have difference below 5 mm year^?1. It is concluded that StaMPS-based PS-InSAR method performs better in terms of extracting more number of measurement pixels and in the estimation of mean line of sight (LOS) velocity as compared to SBAS method.     

Modeling finite buffer effects on TCP traffic over an IEEE 802.11 infrastructure WLAN

The network scenario is that of an infrastructure IEEE 802.11 WLAN with a single AP with which several stations (STAs) are associated. The AP has a finite size buffer for storing packets. In this scenario, we consider TCP-controlled upload and download file transfers between the STAs and a server on the wireline LAN (e.g., 100 Mbps Ethernet) to which the AP is connected. In such a situation, it is well known that because of packet losses due to finite buffers at the AP, upload file transfers obtain larger throughputs than download transfers. We provide an analytical model for estimating the upload and download throughputs as a function of the buffer size at the AP. We provide models for the undelayed and delayed ACK cases for a TCP that performs loss recovery only by timeout, and also for TCP Reno. The models are validated in comparison with NS2 simulations.     

Dispersal and sink pathways of suspended particulate matter from the orographically enhanced SWM regime of the SE Arabian Sea

The magnitude of precipitation plays an important role in the yield and supply of terrigenous matter into the sea through fluvial supply. The influence of climate on the influx of total suspended matter (TSM) into the continental margin of the SE Arabian Sea has been evaluated from subweekly synoptic variations in TSM and its advection rates, currents and winds during the southwest monsoon (SWM) and postmonsoon season. Our study endorses the high influx of TSM during the SWM (>82 mg l^?1; advection 26–110 mg m^?2 s^?1), albeit that most of it is sequestered into the shallow coastal region. Over the mid-outer shelf, there is uniformly low TSM (12–24 mg l^?1) and a weak TSM advection (9–4 mg m^?2 s^?1) throughout the year. This trend is persistent also in areas having upwelling-induced high marine productivity. We therefore surmise that higher fluvial influx and primary production during the SWM do not necessarily enhance the supply of particulate matter into the deeper offshore regions of the SE Arabian Sea. We ascribe a vital role to the prevailing morphodynamic processes.     

Comparative performance analysis of cogeneration gas turbine cycle for different blade cooling means

The paper compares the thermodynamic performance of MS9001 gas turbine based cogeneration cycle having a two-pressure heat recovery steam generator (HRSG) for different blade cooling means. The HRSG has a steam drum generating steam to meet coolant requirement, and a second steam drum generates steam for process heating. Gas turbine stage cooling uses open loop cooling or closed loop cooling schemes. Internal convection cooling, film cooling and transpiration cooling techniques employing steam or air as coolants are considered for the performance evaluation of the cycle. Cogeneration cycle performance is evaluated using coolant flow requirements, plant specific work, fuel utilisation efficiency, power-to-heat-ratio, which are function of compressor pressure ratio and turbine inlet temperature, and process steam drum pressure. The maximum and minimum values of power-to-heat ratio are found with steam internal convection cooling and air internal convection cooling respectively whereas maximum and minimum values of fuel utilisation efficiency are found with steam internal convection cooling and closed loop steam cooling. The analysis is useful for power plant designers to select the optimum compressor pressure ratio, turbine inlet temperature, fuel utilisation efficiency, power-to-heat ratio, and appropriate cooling means for a specified value of plant specific work and process heating requirement.     

Recent Developments in Integrated Solar Combined Cycle Power Plants

Global concern for depleting fossil fuel reserves have been compelling for evolving power generation options using renewable energy sources. The solar energy happens to be a potential source for running the power plants among renewable energy sources. Integrated Solar Combined Cycle(ISCC) power plants have gained popularity among the thermal power plants. Traditional ISCC power plants use Direct Steam Generation(DSG) approach. However, with the DSG method, the ISCC plant’s overall thermal effici...