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Frédéric Gaschet 《Papers in Regional Science》2002,81(1):63-81
This article examines the relationships between the employment suburbanisation from central cities towards their suburbs,
and the process of intra-urban specialisation that occurred simultaneously in the fifty largest French metropolitan areas.
A methodology is proposed to identify urban subcentres and to analyse the effects of the intra-urban specialisations on suburbanisation
patterns. We conclude that the specialisation of both subcentres and central cities has a significant effect on suburbanisation
rates. Lastly, an intra-metropolitan shift/share analysis provides additional insights into the employment dynamics of central
cities and suburbs during the last twenty years.
Received: 25 July 2000 / Accepted: 29 May 2001 相似文献
5.
M. D. Kannan Sa. K. Narayandass C. Balasubramanian D. Mangalaraj 《Journal of Materials Science》1992,27(18):5040-5044
Aluminium-neodymium oxide-aluminium thin film capacitors have been prepared by thermal evaporation and the d.c. conduction properties of these films have been studied. The thicknesses of the films have been determined by a multiple beam interferometer. The current-voltage power-law dependence showed that the conduction in these films is space-charge limited. The linear dependence of the current density on the square root of the applied field confirmed the exponential trap distribution. The trap density has been found to be of the order of 1026 m–3. It has also been observed that the Schottky type of conduction is predominant in the high-field region and the height of the Schottky barrier has been determined. It is seen that the conduction mechanism is an activated process with the activation energy decreasing with increasing field. 相似文献
6.
An algorithm is presented for computer distance relaying. It is based on modal Kalman filtering (MKF) to estimate fundamental phasors, MKF exploits all the measurement information available from a three-phase line and is founded on enhanced models of the electromagnetic transients noise. To support the modeling of noise for different faults, a study of nontrivial electrical networks with accurate electromagnetic transients modeling is made for 400 kV transmission lines. MKF fits the behavior of the different modal noise for the Clarke phasors, but it is invariant for each type of fault, assuring robustness and minimum error variance. To computer distance, Clarke αB phasors are transformed to +/- symmetrical components, and then a well-known expression is used to computer the positive impedance. Statistical analysis if presented to assess observation time versus estimation accuracy for the different types of line faults 相似文献
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Renato Cataluña Rosângela da Silva Eliana Weber de Menezes Ricardo Boeira Ivanov 《Fuel》2008,87(15-16):3362-3368
Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline. 相似文献
9.
Zakaria Chajar Michel Primet Hélène Praliaud Michèle Chevrier Catherine Gauthier Frédéric Mathis 《Catalysis Letters》1994,28(1):33-40
The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO2 and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C3H8 does not differ significantly from that of NO2. In the absence of oxygen, the reduction of NO2 by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO2 formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process. 相似文献
10.
Catalytic chlorination of methane was studied over SO
4
2–
/ZrO2, Pt/SO
4
2–
/ZrO2, and Fe/Mn/SO
4
2–
/ZrO2 solid superacid catalysts. The reactions were carried out in a continuous flow reactor under atmospheric pressure, at temperatures below 240°C, with a gaseous hourly space velocity of 1000 ml/g h and a methane to chlorine ratio of 4 to 1. At 200°C with 30% chlorine converted the selectivity in methyl chloride exceeds 90%. At more elevated temperatures, the selectivity decreases but stays above 80% in methyl chloride at 225°C using the sulfated zirconia catalysts. The selectivity can be enhanced by adding platinum to sulfated zirconia catalysts. An iron and manganese-doped catalyst exhibited excellent selectivities at somewhat lower conversions. Methyl chloride is obtained at 235°C in selectivities greater than 85%. No chloroform or carbon tetrachloride is formed. The electrophilic insertion involves electron-deficient metal-coordinated chlorine into the methane C-H bond.Catalysis by solid superacids, 29. For part 28 see ref. [14]. 相似文献