ABSTRACTIn this study, an Egyptian siliceous/calcareous sedimentary phosphorite was subjected to beneficiation by unsophisticated economic means. The mineralogical and chemical examination showed that the ore sample is a typical example for the East Mediterranean phosphorites with 21.80% P2O5, 10.93% acid insoluble and 16.61% loss on ignition. The primary crushed sample was classified into three size fractions without any milling and they were separately subjected to an integrated attrition scrubbing study. Screening and classification on the 2.30 mm and 0.071 mm sieves were sequentially introduced with the attrition process. The effect of solid%, attrition speed and time were studied and optimized for each size fraction. Results showed that three products were produced and could be categorized according to their P2O5 content into the coarse tailing (+2.30 mm), the attrition concentrate (?2.30 + 0.071 mm) and the phosphate fines (?0.071 mm). The P2O5 contents of these products reached 12.24%, 28.72% and 18.77%, with P2O5 distribution reached 6.74%, 51.75% and 41.51%, respectively. A global P2O5 of 28.72% was obtained with a recovery of about 52%. A tentative flow-sheet for the whole process was postulated. 相似文献
Thin PDMS films with complex microstructures are used in the manufacturing of dielectric electro active polymer (DEAP) actuators, sensors and generators, to protect the metal electrode from large strains and to assure controlled actuation. The current manufacturing process at Danfoss Polypower A/S produces films with a one-sided microstructured surface only. It would be advantageous to produce a film with both surfaces microstructured, as this increases the film’s performance efficiency. The new technique introduced herein produces bilaterally microstructured film by combining an embossing method with the existing manufacturing process. In employing the new technique, films with microstructures on both surfaces are successfully made with two different liquid silicone rubber (LSR) formulations: 1) pure XLR630 and 2) XLR630 with titanium dioxide (TiO2). The LSR films (~70 µm) are cast on a carrier web substrate using a coating blade. The carrier web, which has a sinusoidal corrugation with wave height of 7 µm and a wave period of 7 µm on its surface, imparts corrugations to the bottom surface of the film. The elastomer film on the carrier web is preheated to the gel point, where the elastomer film can retain an imprint made on it. The preheated film at gel point is embossed between the rolls of a gravure lab coater, which corrugates the top surface of the film. The films are then heated, in order to cure completely. For the LSR systems used in this process, the optimum conditions for preheating are 110°C for 4–7 s, while for embossing the temperature is 110°C with 25 psi pressure between the rolls at a speed of 1.4 rpm. Scanning electron microscope (SEM) images confirm the formation of microstructures on both the surfaces of the film. 相似文献
The enzymic hydrolysis of commercial wheat starch and freshly prepared wheat starch fractions was studied in batch and flow systems. Fresh starch was prepared by wet separation of wheat flour into starch milk and gluten, followed by processing the starch milk using a serially connected hydrocyclone system to produce underflow and overflow streams. The underflow stream consisted mainly of the larger (> 30 w m) granules, while the overflow stream contained only the smaller (< 10 w m) granules. In batch system, the hydrolysis behavior of wheat starch fractions was investigated under the action of Sigma f -amylase ( Bacillus licheniformis ), either as soon as they were prepared or after spray drying. The two fractions of fresh wheat starch showed different hydrolysis behavior, the difference getting larger as the separation improves. Underflow streams were found to be much more susceptible to hydrolysis than overflow streams, regardless of whether the hydrolysis was carried out right away or on dried samples, and also regardless of whether rinsing was applied. In flow system, dried underflow stream and commercialwheat starch were hydrolyzed using Orbamil-T ( Bacillus licheniformis ), Orbamil-BHT ( Bacillus stearothermophilus ), and Sigma f -amylase ( Bacillus licheniformis ). Hydrolysis of fresh starch was found to be significantly faster than commercial wheat starch. Commercial f -amylase Orbamil-T was found to be almost as effective as the purified Sigma f -amylase. 相似文献
This report explores the available curative molecules directed against hepatocellular carcinoma (HCC). Limited efficiency as well as other drawbacks of existing molecules led to the search for promising potential alternatives. Understanding of the cell signaling mechanisms propelling carcinogenesis and driven by cell proliferation, invasion, and angiogenesis can offer valuable information for the investigation of efficient treatment strategies. The complexity of the mechanisms behind carcinogenesis inspires researchers to explore the ability of various biomolecules to target specific pathways. Natural components occurring mainly in food and medicinal plants, are considered an essential resource for discovering new and promising therapeutic molecules. Novel biomolecules normally have an advantage in terms of biosafety. They are also widely diverse and often possess potent antioxidant, anti-inflammatory, and anti-cancer properties. Based on quantitative structure–activity relationship studies, biomolecules can be used as templates for chemical modifications that improve efficiency, safety, and bioavailability. In this review, we focus on anti-HCC biomolecules that have their molecular targets partially or completely characterized as well as having anti-cancer molecular mechanisms that are fairly described. 相似文献
A spectrophotometric investigation has been applied to study the kinetics of oxidation of poly (ethylene glycol) (PEG) as a synthetic polymer by alkaline permanganate at a constant ionic strength of 1.0 mol.dm?3. The reaction was found to proceed through two distinct measurable stages. The first stage was relatively fast and corresponding to the formation of coordination polymer intermediate complexes involving blue hypomanganate (V) and/or green manganate (VI) transient species. The influence of variable factors on the oxidation rates such as the concentration of permanganate ion and PEG substrate concentrations as well as the pH and ionic strength have been examined. Under the pseudo-first-order reaction conditions of [PEG] ? [MnO4?], the experimental results showed a first-order dependence in [MnO4?] and fractional first-order kinetics in each of [PEG] and alkali concentration. The oxidation process was of base-catalyzed nature where the oxidation rates were increased with increasing the alkali concentration. The observed first-order rate constant was found to be 1.1 ×10?3 s?1 with deprotonation constant of 0.72 dm3 mol?1 at 45 °C. Blue hypomanganate (V) was detected for the first time by using a conventional spectrophotometer. The oxidation process has proceeded without the intervention of a free-radical mechanism. Colloidal manganese (IV) and the acid derivatives of PEG were identified as final oxidation products. The activation parameters of the second-order reaction have been calculated and found to be ΔH≠ = 40.66 kJmol?1; ΔS≠ = ? 145.41 Jmol?K?1 and ΔG≠ = 83.99 kJmol?1. A plausible reaction mechanism for oxidation based on the evaluated activation parameters and in good consistent with the observed kinetic data was suggested and discussed. 相似文献
In this paper, we consider the problem of spectrum sharing in CRAHNs and propose a distributed channel selection scheme. The key functionality of our proposal, best-fit channel selection (BFC) is that it accounts both the primary channel traffic activity and CR traffic activity in channel selection. We assume CR nodes have the capability of estimating the primary channel traffic activities. In BFC, each CR selects a channel among the primary user (PU) channels for transmission that best fits to its transmission time requirement. We compare the performance of BFC to the widely known longest idle time channel selection (LITC) scheme. In LITC, a CR selects the channel that has the longest expected idle time independent of its transmission needs. In a multi-user CRN, this may degrade the network performance compared to the non-selfish BFC approach. LITC is considered selfish since each CR aims to maximize its own benefit and thus wastes resources that may be utilized by other nodes in the network. BFC providing an efficient spectrum sharing mechanism implicitly mitigates the effect of spectrum fragmentation which is a significant issue degrading the CR spectrum utilization. In CRNs, spectrum may be fragmented in various dimensions, e.g. time and frequency, such that some parts of the spectrum can not be used although being idle. Our proposal provides a solution to the spectrum fragmentation issue in time dimension at the medium access control (MAC) layer. By a set of simulations, we highlight the performance improvement by BFC over the conventional LITC under various CR/PU traffic, number of CRs, estimation accuracy and buffering capability. Simulation results show that the performance of the proposed BFC is significantly superior to that of LITC in terms of probability of successful transmission, spectrum opportunity utilization and fragmentation. 相似文献
In this study, the aim was to produce tissue-engineered bone using osteoblasts and a novel matrix material, poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid) (PHBV). In order to prepare a porous PHBV matrix with uniform pore size, sucrose crystals were loaded in the foam and then leached leaving pores behind. The surface of the PHBV matrix was treated with rf-oxygen plasma to increase the surface hydrophilicity. SEM examination of the PHBV matrices was carried out. Stability of PHBV foams in aqueous media was studied. The pH decrease is an indication of the degradation extent. The weight and density were unchanged for a period of 120 days but then a significant decrease was observed for the rest of the study. Osteoblast cells were then isolated from rat bone marrow and seeded onto PHBV matrices. The metabolization and proliferation on the foams was determined with MTS assay which showed that osteoblasts proliferated on PHBV. It was also found that cells proliferated better on large pore size foams (300–500 m) than on the small pore size foams (75–300 m). Production of ALP was measured spectrophotometrically. The present study demonstrated that PHBV matrices are suitable substrates for osteoblast proliferation and differentiation. 相似文献
The aim of this in vitro study was to evaluate the effects of chlorhexidine gluconate (2%), sodium hypochloride (2.5%), ozone gas, and boric acid at different concentrations (1%, 3%, 5%, and 7%) on microleakage from composite restorations.
In a total of 80 extracted human canine teeth, a class V cavity was opened on the buccal surface and the samples were separated into eight groups. In the control group, no procedure was applied for cavity disinfection, then composite restoration (Z250, 3M) was made using single-stage, self-etch adhesive (Single Bond 3M). In the other groups, seven different disinfectants were used, then the cavity was restored. The teeth were split into two in the buccolingual direction, parallel to the long axes. Stain penetration was examined under stereomicroscope and scored. Examination with SEM was made on one sample from each group, selected at random. Statistical evaluations were made using Dunnett C Post Hoc Comparison and Kruskal–Wallis H tests.
In the occlusal region evaluation, the groups with the lowest level of leakage were the 3% and 5% boric acid groups, and the highest levels of microleakage were determined in the chlorhexidine group and the 1% boric acid group. In the gingival region, the lowest level of microleakage was in the 5% boric acid group and the highest levels were determined in the 1% and 7% boric acid groups.
Boric acid disinfectants used at suitable concentrations were not seen to create a risk in respect of microleakage. 相似文献