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1.
M Fujimoto H Kanzaki H Nakayama T Higuchi H Hatayama M Iwai Y Kaneko T Mori J Fujita 《Canadian Metallurgical Quarterly》1996,137(3):1096-1101
Differentiation of endometrial stromal cells (decidualization) is essential for embryo implantation and maintenance of pregnancy. By sequential complementary DNA subtractive hybridization, one of the messenger RNAs (mRNA) induced by progesterone in human endometrial stromal cells decidualized in vitro was identified as that of a tissue transglutaminase type II (TGase). TGase mRNA was induced within 6 h after the addition of progesterone to the culture, and the effect was dose dependent. Both the TGase inhibitor monodansylcadaverine and oligodeoxynucleotide complementary to the TGase mRNA inhibited the decidualization, as assessed by PRL production and morphological transformation. Expression of TGase mRNA in human decidua and endometria exposed to high levels of progesterone in vivo was demonstrated by Northern blotting and in situ hybridization. These data suggest that TGase is necessary for the decidualization of human endometrial stromal cells and that clarification of the mechanism of action of TGase will facilitate further insight into the diagnosis and treatment of infertility. 相似文献
2.
Direct imaging of single-walled carbon nanotubes (SWNTs) suspended on pillar-patterned Si or SiO2 substrates is investigated using transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The suspended nanotubes are successfully observed by direct TEM imaging and it is seen that they have either individual or bundles of SWNTs. Low energy (< or =2 keV) SEM produces high contrast images of suspended SWNTs. On the contrary, when SWNTs contact a SiO2 substrate, they are imaged using electron-beam induced current. The image brightness depends on the length of SWNTs. 相似文献
3.
Kimoto T. Kosugi H. Suda J. Kanzaki Y. Matsunami H. 《Electron Devices, IEEE Transactions on》2005,52(1):112-117
Design and fabrication of lateral SiC reduced surface field (RESURF) MOSFETs have been investigated. The doping concentration (dose) of the RESURF and lightly doped drain regions has been optimized to reduce the electric field crowding at the drain edge or in the gate oxide by using device simulation. The optimum oxidation condition depends on the polytype: N/sub 2/O oxidation at 1300/spl deg/C seems to be suitable for 4H-SiC, and dry O/sub 2/ oxidation at 1250/spl deg/C for 6H-SiC. The average inversion-channel mobility is 22, 78, and 68 cm/sup 2//Vs for 4H-SiC(0001), (112~0), and 6H-SiC(0001) MOSFETs, respectively. RESURF MOSFETs have been fabricated on 10-/spl mu/m-thick p-type 4H-SiC(0001), (112~0), and 6H-SiC(0001) epilayers with an acceptor concentration of 1/spl times/10/sup 16/ cm/sup -3/. A 6H-SiC(0001) RESURF MOSFET with a 3-/spl mu/m channel length exhibits a high breakdown voltage of 1620 V and an on-resistance of 234 m/spl Omega//spl middot/cm/sup 2/. A 4H-SiC(112~0) RESURF MOSFET shows the characteristics of 1230 V-138 m/spl Omega//spl middot/cm/sup 2/. 相似文献
4.
Monodispersed spherical β-SiC powder was synthesized by heating spherical gel powder derived from the hydrolysis of a mixture of phenyltriethoxysilane and tetraethyl orthosilicate. The solution was prepared in a beaker and hydrolyzed by NH4 OH without stirring. The monodispersed spherical gel powder of submicrometer size was obtained when the added amount of NH4 OH was greater than 16 moles per mole of silane plus alkoxide, and it became monodispersed spherical β-SiC powder by heat-treating at 1500°C for 4 h in an Ar atmosphere. The SiC content of the powder was 92.6 wt%. 相似文献
5.
Yu-ichi Yoshizawa Kiyoshi Hirao Shuzo Kanzaki 《Journal of the American Ceramic Society》2004,87(11):2147-2149
The mechanical properties of a textured alumina made by high-temperature deformation of normal-purity sintered alumina have been investigated. The textured alumina shows very high bending strength and extremely high fracture toughness. Fracture toughness of more than 10 MPa·m1/2 was measured by the single-edge precracked beam method, and even using the single-edge V-notched beam method, toughness of over 8 MPa·m1/2 was obtained. This high fracture toughness was attributed to a large number of aligned small platelike grains of the textured structure enhancing the grain bridging effect. 相似文献
6.
Yu-Ping Zeng Jian-Feng Yang Naoki Kondo Tatsuki Ohji Hideki Kita Shuzo Kanzaki 《Journal of the American Ceramic Society》2005,88(6):1622-1624
The fracture energies of the tape-cast silicon nitride with and without 3 wt% rod-like β-Si3 N4 seed addition were investigated by a chevron-notched-beam technique. The material was doped with Lu2 O3 –SiO2 as sintering additives for giving rigid grain boundaries and good heat resistance. The seeded and tape-cast silicon nitride has anisotropic microstructure, where the fibrous grains grown from seeds were preferentially aligned parallel to the casting direction. When a stress was applied parallel to the fibrous grain alignment direction, the strength measured at 1500°C was 738 MPa, which was almost the same as room temperature strength 739 MPa. The fracture energy of the tape-cast Si3 N4 without seed addition was 109 and 454 J/m2 at room temperature and 1500°C, respectively. On the contrary, the fracture energy of the seeded and tape-cast Si3 N4 was 301 and 781 J/m2 at room temperature and 1500°C, respectively, when a stress was applied parallel to the fibrous gain alignment. The large fracture energies were attributable primarily to the unidirectional alignment fibrous Si3 N4 grains. 相似文献
7.
Further Improvement in Mechanical Properties of Highly Anisotropic Silicon Nitride Ceramics 总被引:1,自引:0,他引:1
Hisayuki Imamura Kiyoshi Hirao Manuel E. Brito Motohiro Toriyama Shuzo Kanzaki 《Journal of the American Ceramic Society》2000,83(3):495-500
Si3 N4 ceramics were fabricated by tape casting of a raw-powder slurry seeded with three types of rodlike β-Si3 N4 particles. The effects of seed size on the microstructure and mechanical properties of the sintered specimens were investigated. All the seeded and tape-cast silicon nitrides presented an anisotropic microstructure, where the elongated grains grown from seeds were preferentially oriented parallel to the casting direction. The orientation degree of these grains, f 0 , was affected by seed size, and small-seed addition led to the highest f 0 value. This material exhibited high bending strength (∼1.4 GPa) and high fracture toughness (∼12 MPa. m1/2 ) in the direction normal to the grain alignment, which were attributed to the highly anisotropic and fine microstructure. 相似文献
8.
Yoshiaki Inagaki Tatsuki Ohji Shuzo Kanzaki Yasuhiro Shigegaki 《Journal of the American Ceramic Society》2000,83(7):1807-1809
The fracture energy of a porous silicon nitride with aligned fibrous grains was investigated, using a chevron-notched-beam technique. A crack was constrained to propagate normal to the grain alignment. The obtained fracture energy was ∼500 J/m2 , which was ∼7 times larger than that of a dense silicon nitride with randomly oriented fibrous grains. The large fracture energy was attributable primarily to the sliding resistance associated with interlocking grains. 相似文献
9.
Abrasive jet machining (AJM), a specialized form of shot blasting using fine-grained abrasives, is an attractive micro-machining method for ceramic materials. In this paper, the machinability during the AJM process is compared to that given by the established models of solid particle erosion, in which the material removal is assumed to originate in the ideal crack formation system. However, it was clarified that the erosion models are not necessarily applicable to the AJM test results, because the relative hardness of the abrasive against the target material, which is not taken into account in the models, is critical in the micro-machining process. In contrast to conventional erosion by large-scale particles, no strength degradation occurs for the AJM surface, which is evidence that radial cracks do not propagate downwards as a result of particle impacts. 相似文献
10.
Taigo Onodera Shuichi SuzukiTakaaki Mizukami Hisao Kanzaki 《Journal of power sources》2011,196(19):7994-7999
An improved synthesis scheme of non-precious metal N-doped carbon catalysts for oxygen reduction reaction is reported. The non-precious metal N-doped carbon catalysts were prepared by pyrolysis of the mixture (phenol resin, Ketjen black carbon support and cobalt phenanthroline complex). The drastic improvement of distribution state of Ketjen black supported non-precious metal N-doped carbon catalysts was observed by means of transmission electron microscopy (TEM). In addition, the non-precious metal N-doped carbon catalyst synthesized with Ketjen black carbon support showed much higher oxygen reduction reaction (ORR) activity relative to unsupported non-precious metal N-doped carbon catalyst in O2-saturated 0.5 mol l−1 H2SO4 at 35 °C. Moreover, the highest ORR activity was obtained with addition of optimum amount of Ketjen black carbon support was thirtyfold compared to unsupported non-precious metal N-doped carbon catalyst at 0.7 V. Similarly, the performance of a polymer electrolyte fuel cell (PEFC) using the non-precious metal N-doped carbon catalyst as the cathode electrode catalyst was obviously better than that of the non-precious metal N-doped carbon catalyst before optimization. Microstructure, specific surface area and surface composition of the non-precious metal N-doped carbon catalysts were analyzed by XRD, XPS and BET measurement with nitrogen physisorption, respectively. 相似文献