Reaction environment self-modification on low-coordination Ni2+ octahedra atomic interface for superior electrocatalytic overall water splitting

Large scale synthesis of high-efficiency bifunctional electrocatalyst based on cost-effective and earth-abundant transition metal for overall water splitting in the alkaline environment is indispensable for renewable energy conversion. In this regard, meticulous design of active sites and probing their catalytic mechanism on both cathode and anode with different reaction environment at molecular-scale are vitally necessary. Herein, a coordination environment inheriting strategy is presented for designing low-coordination Ni²⁺ octahedra (L-Ni-8) atomic interface at a high concentration (4.6 at.%). Advanced spectroscopic techniques and theoretical calculations reveal that the self-matching electron delocalization and localization state at L-Ni-8 atomic interface enable an ideal reaction environment at both cathode and anode. To improve the efficiency of using the self-modification reaction environment at L-Ni-8, all of the structural features, including high atom economy, mass transfer, and electron transfer, are integrated together from atomic-scale to macro-scale. At high current density of 500 mA/cm², the samples synthesized at gram-scale can deliver low hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) overpotentials of 262 and 348 mV, respectively.

     

A Versatile Theranostic Nanoemulsion for Architecture‐Dependent Multimodal Imaging and Dually Augmented Photodynamic Therapy

To design a clinically translatable nanomedicine for photodynamic theranostics, the ingredients should be carefully considered. A high content of nanocarriers may cause extra toxicity in metabolism, and multiple theranostic agents would complicate the preparation process. These issues would be of less concern if the nanocarrier itself has most of the theranostic functions. In this work, a poly(ethylene glycol)‐boron dipyrromethene amphiphile (PEG‐F₅₄‐BODIPY) with 54 fluorine‐19 (¹⁹F) is synthesized and employed to emulsify perfluorohexane (PFH) into a theranostic nanoemulsion (PFH@PEG‐F₅₄‐BODIPY). The as‐prepared PFH@PEG‐F₅₄‐BODIPY can perform architecture‐dependent fluorescence/photoacoustic/¹⁹F magnetic resonance multimodal imaging, providing more information about the in vivo structure evolution of nanomedicine. Importantly, this nanoemulsion significantly enhances the therapeutic effect of BODIPY through both the high oxygen dissolving capability and less self‐quenching of BODIPY molecules. More interestingly, PFH@PEG‐F₅₄‐BODIPY shows high level of tumor accumulation and long tumor retention time, allowing a repeated light irradiation after a single‐dose intravenous injection. The “all‐in‐one” photodynamic theranostic nanoemulsion has simple composition, remarkable theranostic efficacy, and novel treatment pattern, and thus presents an intriguing avenue to developing clinically translatable theranostic agents.     

The influence of cryogenic rolling on a transformation-induced plasticity steel

ABSTRACT

Here, a novel cryogenic rolling plus intercritical annealing process was applied to a transformation-induced plasticity (TRIP) steel with a low chemical composition of carbon and manganese. Compared with traditional cold rolling, obvious grain refinement was observed, due to a high amount of dislocations retained. In addition, austenite volume fraction was increased, because of a unique nucleation mechanism. Subjected to cryogenic rolling, strength and ductility were increased, due to the enhanced austenite stability, which provided continuous and active TRIP effect. Consequently, tensile strength was increased to 1030?MPa, and elongation was increased to 38.2%. Thus, a great mechanical combination was obtained in a steel with a relatively low chemical composition with carbon and manganese, only by cryogenic rolling process.     

几种配合料加水系统及特点

分析总结了几种常见配合料加水系统及其特点,并结合生产实际提出了不同系统的利弊和使用要点.     

槽波地震在东北地区的应用

介绍了槽波技术的原理及在东北地区几个矿的应用情况。     

大同矿区云冈沟K21砾岩层特征研究

就大同矿区K21砾岩层的分布范围、厚度变化、古河流冲刷现象、砾径变化、沉积相等进行了介绍。     

22305综采工作面地质评价

对22305工作面煤层厚度、结构、煤层顶底板地质构造、陷落柱、水文地质等进行了单项和综合评价，为更好地发挥综采优势提供了条件。     

回归方程在煤灰成分分析数理统计中的应用

在煤灰成分分析检测项目中有一些通常采用光电比色法进行检验.为了提高数据处理的准确度,采用一元线性回归方程对数据进行数理统计的方法,建立简单的数学模型,可快速、准确地获得计算结果.     

南翼轨道运输石门工作面突水“夹层”注浆堵水技术

根据矿井水文地质特征和突水原因,对突水通道和突水水源进行分析,采用引流式和压入式结合、井上下结合注浆堵水方法以及"夹层"注浆堵水技术,实现了快速封堵构造破碎带高压大流量突水。     

宜昌三峡机场灯光带滑坡特征及治理

三峡机场灯光带滑坡，属典型的人工加载“后推式”碎石土滑坡类型。该滑坡治理前，稳定系数仅１．０７，处于极限平衡状态，不仅严重阻碍机场灯光带导航系统的建设，且危及相距仅２００ｍ的汉宜高等级公路。该滑坡通过工程治理，达到了预期目的，收到了良好的社会和经济效益。