Stabilizing Redox-Active Hexaazatriphenylene in a 2D Conductive Metal–Organic Framework for Improved Lithium Storage Performance

Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g⁻¹ at 300 mA g⁻¹), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g⁻¹), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO₄ unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials.     

融合改进 YOLOv7 与 UNet 的编码点定位方法

针对编码点的定位存在误检率高和精准度差的问题,提出了一种融合改进 YOLOv7 与 UNet 的圆形编码点定位方 法。第1阶段使用改进的 YOLOv7 检测编码点的位置,改进的 YOLOv7 首先将DCN-v2 可变形卷积引入 ELAN 模块,提升 特征提取能力;其次把卷积块注意力模块(CBAM) 机制嵌入骨干网络使网络更关注目标特征;然后使用Focal-EloU Loss 提高 收敛速度;最后构建 OD-Cat 模块替换 ConCat 模块以提升网络检测精度。提取出每个圆形编码点的 ROI 后,第2阶段通过 UNet 分割出编码点的中心轮廓后,使用最小二乘法拟合出编码点的中心。实验结果表明,改进后的模型比原 YOLOv7 的精 确率提高了6.33%,平均精度均值(mAP) 提升了5.76%;提出的定位方法验证了在噪声、亮度不足或曝光等复杂环境下可以 准确定位出编码点的中心椭圆轮廓,在实际工业视觉测量中具备鲁棒性。     

Metal–Organic Gel‐Derived FexOy/Nitrogen‐Doped Carbon Films for Enhanced Lithium Storage

The development of cost‐effective and flexible electrodes is demanding in the field of energy storage. Herein, flexible Fe_xO_y/nitrogen‐doped carbon films (Fe_xO_y/NC‐MOG) are prepared by facile electrospinning of Fe‐based metal–organic gels (MOGs) followed by high‐temperature carbonization. This approach allows the even mixing of fragile coordination polymers with polyacrylonitrile into flexible films while reserving the structural characteristics of coordination polymers. After thermal treatment, Fe_xO_y/NC‐MOG films possess uniformly distributed Fe_xO_y nanoparticles and larger accessible surface areas than traditional Fe_xO_y‐NC films without MOG. Taking advantage of the unique structure, Fe_xO_y/NC‐MOG exhibits a superior rate performance (449.8 mA h g^?1 at 5000 mA g^–1) and long cycle life (629.3 mA h g^–1 after 500 cycles at 1000 mA g^–1) when used as additive‐free anodes in lithium‐ion batteries.     

基于命令流方法的液压机ANSYS有限元建模

介绍了命令流方法在液压机ANSYS有限元建模的起因和用途,并作了实例建模,最后指出对计算机应用软件的二次开发在液压机结构设计中的必要性.     

Up?Scalable Fabrication of -SnO2 with Multifunctional Interface for High Performance Perovskite Solar Modules

Tin dioxide -(SnO2) has been demonstrated as one of the promising electron transport layers for highefficiency perovskite solar cells (PSCs). However, scalable ...     

基于WinCC6．0及S7-200PLC的材料分拣监控系统设计

本文采用西门子s7-200系列PLC和winCC监控软件相结合的控制模式,实现了材料、分拣的全自动监视与控制。S7-200PLC和以WinCC为OPC客户端的监控软件之间的通讯采用s7—200PCACCESS作为OPC服务器实现。经过对材料分拣装置的实时监控,证明系统稳定性和准确度较好,能满足监控系统的需要。     

Achieving Rich and Active Alkaline Hydrogen Evolution Heterostructures via Interface Engineering on 2D 1T‐MoS2 Quantum Sheets

Large‐scale production of hydrogen from water‐alkali electrolyzers is impeded by the sluggish kinetics of hydrogen evolution reaction (HER) electrocatalysts. The hybridization of an acid‐active HER catalyst with a cocatalyst at the nanoscale helps boost HER kinetics in alkaline media. Here, it is demonstrated that 1T–MoS₂ nanosheet edges (instead of basal planes) decorated by metal hydroxides form highly active ${\text{edge}}_{{\text{1T‐MoS}}_{\text{2}}}$/ ${\text{edge}}_{\text{Ni}{(\text{OH})}_{\text{2}}}$ heterostructures, which significantly enhance HER performance in alkaline media. Featured with rich ${\text{edge}}_{{\text{1T‐MoS}}_{\text{2}}}$/ ${\text{edge}}_{\text{Ni}{(\text{OH})}_{\text{2}}}$ sites, the fabricated 1T–MoS₂ QS/Ni(OH)₂ hybrid (quantum sized 1T–MoS₂ sheets decorated with Ni(OH)₂ via interface engineering) only requires overpotentials of 57 and 112 mV to drive HER current densities of 10 and 100 mA cm^?2, respectively, and has a low Tafel slope of 30 mV dec^?1 in 1 m KOH. So far, this is the best performance for MoS₂‐based electrocatalysts and the 1T–MoS₂ QS/Ni(OH)₂ hybrid is among the best‐performing non‐Pt alkaline HER electrocatalysts known. The HER process is durable for 100 h at current densities up to 500 mA cm^?2. This work not only provides an active, cost‐effective, and robust alkaline HER electrocatalyst, but also demonstrates a design strategy for preparing high‐performance catalysts based on edge‐rich 2D quantum sheets for other catalytic reactions.