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排序方式: 共有615条查询结果,搜索用时 15 毫秒
1.
Anastasiya Rybak Patrice A. Fokou Michael A. R. Meier 《European Journal of Lipid Science and Technology》2008,110(9):797-804
Olefin metathesis, awarded with the Nobel Prize in Chemistry 2005 for Chauvin, Grubbs and Schrock, has emerged as a powerful tool for organic as well as polymer chemistry. In oleochemistry, this reaction is well known and has been applied for many decades. Examples include the functionalization of the double bonds of different oleochemicals or the (direct) polymerization of plant oils via metathesis. More recent developments, particularly the development of better and more robust catalysts, allow for highly efficient cross‐metathesis reactions opening new possibilities for the direct introduction of chemical functionalities. Within this contribution, the development of metathesis in oleochemistry will be discussed, covering self‐metathesis as well as more recent developments in the field of cross‐metathesis that lead to desired platform chemicals. 相似文献
2.
Carole E. Baddour Cedric L. Briens Serge Bordere Didier Anglerot Patrice Gaillard 《Chemical Engineering and Processing: Process Intensification》2008,47(12):2195-2202
Since their observation in 1976 and 1991, carbon nanotubes (CNTs) have generated much interest due to their properties and potential applications. CNTs are tubular carbon molecules with remarkable mechanical, electrical, chemical and thermal properties, which make them useful in various applications. Industries producing CNTs via the fluidized bed chemical vapor deposition technique face challenges related to the size of CNT bundles. The two main challenges are agglomeration and agglomerate size distribution control. A solution to these challenges involves the use of jet mills to grind the CNT agglomerates. The goal of this study was to determine whether the nanotubes could be ground with air jets using a commercial jet mill and apply a two-parameter model to describe the grinding process. The present study has indicated that air-jet grinding of CNTs is feasible with a typical commercial jet mill. This paper presents the effect of operational parameters on the arithmetic mean diameter of the ground product. Sonic velocity through the grinding nozzles was required to obtain reasonable grinding rates and relatively narrow particle size distributions. This occurs at high air to solids feedrate ratios. Additionally, a simple attrition model can describe the grinding process in the spiral jet mill. 相似文献
3.
A necessary and sufficient condition is given for a connected bipartite graph to be the incidence graph of a contact family
of segments and points. We deduce that any four-connected three-colorable plane graph is the contact graph of a family of
segments and that any four-colored planar graph without an induced C4 using four colors is the intersection graph of a family of straight line segments. 相似文献
4.
Arezki Tagnit-Hamou Mladenka Saric-Coric Patrice Rivard 《Cement and Concrete Research》2005,35(1):99-107
This paper presents research results on the causes of a severe concrete deterioration, which occurred in many building foundations approximately 2 years after construction. Concrete samples were investigated with X-ray diffraction (XRD) analysis, a scanning electron microscope (SEM) and a petrographic examination performed with a stereomicroscope. It was found that the early cracking of concrete stemmed from the oxidation of the pyrrhotite found in the anorthosite aggregates used to produce the concrete. The oxidation process led to the precipitation of iron hydroxides having a higher volume than the original pyrrhotite does. The presence of micas (biotite) close to the pyrrhotite seemed to promote and accelerate the oxidation process. 相似文献
5.
Patrice Le Boudec François Sanchez Pierre-Luc FranÇois Jean-François Bayon Guy Michel StÉphan 《电信纪事》1994,49(3-4):178-192
The dynamics of the erbium doped fiber laser is analysed both experimentally and theoretically. This laser operates spontaneously in self-pulsing, in sinusoidal or in CW regime. Experiments have allowed to determine the control parameters : the cavity losses, the pumping rate and the ion pairs concentration. An antiphase dynamics is observed when the laser operates simultaneously at 1.55 µn and 1.536 µm. The self-pulsing behavior is attributed to a fast energy transfer which occurs between two neighboring ions (pair induced quenching). A simple model considering the active medium as a mixture of isolated ions and ions pairs is developped and leads to a good qualitative agreement with the experimental results. 相似文献
6.
Vesa Halava Tero Harju Tomi Kärki Patrice Séébold 《Theoretical computer science》2009,410(8-10):943-948
We prove that there exist infinitely many infinite overlap-free binary partial words containing at least one hole. Moreover, we show that these words cannot contain more than one hole and the only hole must occur either in the first or in the second position. We define that a partial word is -overlap-free if it does not contain a factor of the form where the length of is at least . We prove that there exist infinitely many 2-overlap-free binary partial words containing an infinite number of holes. 相似文献
7.
Jean‐Eudes Marvie Cyprien Buron Pascal Gautron Patrice Hirtzlin Gaël Sourimant 《Computer Graphics Forum》2012,31(7):2087-2095
GPU Shape Grammars provide a solution for interactive procedural generation, tuning and visualization of massive environment elements for both video games and production rendering. Our technique generates detailed models without explicit geometry storage. To this end we reformulate the grammar expansion for generation of detailed models at the tesselation control and geometry shader stages. Using the geometry generation capabilities of modern graphics hardware, our technique generated massive, highly detailed models. GPU Shape Grammars integrate within a scalable framework by introducing automatic generation of levels of detail at reduced cost. We apply our solution for interactive generation and rendering of scenes containing thousands of buildings and trees. 相似文献
8.
Hugo Durou David Pech David Colin Patrice Simon Pierre-Louis Taberna Magali Brunet 《Microsystem Technologies》2012,18(4):467-473
In this paper a wafer-level process is proposed to fully integrate carbon-based micro-supercapacitor onto silicon substrate.
This process relies on the deposition of a paste containing carbon, PVDF and acetone into cavities etched in silicon. After
electrolyte deposition in a controlled atmosphere, a wafer-level encapsulation is realized. Cyclic voltammetry performed on
non-encapsulated micro-components showed specific energy of 257 mJ cm−2 for 336 μm deep cavities. The specific encapsulation process developed was tested separately and proved to be efficient in
terms of resistance to organic electrolytes and mechanical strength. 相似文献
9.
A fast and exact procedure for the numerical synthesis of stationary multivariate Gaussian time series with a priori prescribed and well controlled auto- and cross-covariance functions is proposed. It is based on extending the circulant embedding technique to the multivariate case and can be viewed as a modification and variation around the Chan and Wood algorithm proposed earlier to solve the same problem. The procedure is shown to yield time series possessing exactly the desired covariance structure, when sufficient conditions are satisfied. Such conditions are discussed theoretically and examined on several examples of multivariate time series models. Issues related to prescribing a priori the spectral structure rather than the covariance one are also discussed. Matlab routines implementing this procedure are publicly available at http://www.hermir.org. 相似文献
10.
Anna-Maria GabudeanFrederic Lerouge Thibault GallavardinMonica Iosin Soraya ZaibaOlivier Maury Patrice L. Baldeck Chantal AndraudStephane Parola 《Optical Materials》2011,33(9):1377-1381
Gold nanomaterials are promising objects for applications in optics and medicine because of their unique properties related to the Surface Plasmon Resonances (SPR) phenomena. It is possible to tune these properties with the control of the size and shape of the nanomaterials. Gold hollow spheres nanomaterials are an interesting concept for encapsulation of either dyes or drugs. The study of their properties and their behavior in a bio-environment still remains scarce and some phenomena are still to be explained in particular regarding local field enhancement effect or quenching of their photophysical properties. In this work we describe a process allowing inclusion of optical dyes in gold nanoshells and evaluate the optical properties. 相似文献