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排序方式: 共有217条查询结果,搜索用时 15 毫秒
1.
用羟基封端的聚二甲基硅氧烷改性环氧树脂,得到具有两相结构的改性树脂,其耐热性明显提高.环氧树脂/有机硅(20/80)共混物涂层有很低的表面能,主要的机械性能则变化不大,可作为一种疏水性防护徐层. 相似文献
2.
铝质材料的摩擦学表面改性 总被引:1,自引:0,他引:1
铝质材料阳极氧化膜系均匀、规则的微观多孔质结构,利用物理、化学或电化学的方法在其中沉积或原位合成润滑性物质,在保持阳极氧化膜质硬、耐磨特性的基础上,使其具有一定的白润滑性,是近十多年来铝质材料表面改性研究的热点领域之一,本文对该研究的基本原理和国内外发展概况进行了概述,并重点介绍了我们在这一方面研究中的一些最新进展和结果,分别介绍了三种新型体系的自润滑改性阳极氧化铝材料. 相似文献
3.
Micrometer and nanometer TiO2 particle‐filled poly(phthalazine ether sulfone ketone) (PPESK) composites with various filler volume fractions from 0.5 to 7.5 vol % were prepared by heating compression molding. The friction and wear behaviors of the PPESK composites were evaluated using the block‐on‐ring test rig by sliding PPESK‐based composite blocks against a mild carbon steel ring under dry friction conditions. The wear debris and the worn surfaces of the PPESK composites filled with micrometer and nanometer TiO2 particles were investigated by using a scanning electron microscope (SEM), while the structures of PPESK composites and wear debris were analyzed with IR spectra. Experimental results show that antiwear properties of the PPESK composites can be improved greatly by filling nanometer TiO2 particles, and the friction coefficient decreases when the filler volume fraction is below 2.5%, but when the filler volume fraction is above 2.5% the friction coefficient increases gradually with increasing filler volume fraction. In the case of micrometer TiO2 filler, wear rates increase with increasing filler volume fractions under identical test conditions, and the friction coefficients are less sensitive to the filler volume fraction. It was also found that the wear mechanism of micrometer TiO2 particle‐filled PPESK is mainly severe adhesion and abrasive wear, while that of nanometer TiO2 particle‐filled PPESK is mainly slight abrasive wear. In the former case, there are no transfer film formed on the surface of the counterpart steel, and wear debris are in the form of long and large ribbon. While in the latter case, the wear debris was granule and their size was about 10 μm. In case of 1 vol % nanometer TiO2 particle‐filled PPESK composites, the transfer film was fairly thinner and smoother, and the transfer film provided better coverage on the surface of steel ring, while that of 7.5 vol % was thicker and discrete. These account for the different friction and wear behavior of micrometer and nanometer TiO2 particle‐filled PPESK composite. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 906–914, 2004 相似文献
4.
Nanometre SiO2 filled-polyetheretherketone (PEEK) composite blocks with different filler proportions were prepared by compression moulding. Their friction and wear properties were investigated on a block-on-ring machine by running a plain carbon steel (AISI 1045 steel) ring against the composite block. The morphologies of the wear traces and the transfer film were observed by scanning electron microscopy (SEM). It was found that nanometre SiO2 filled-PEEK exhibited considerably lower friction coefficient and wear rate in comparison with pure PEEK. The lowest wear rate was obtained with the composite containing 7.5 wt.% SiO2. The SEM pictures of the wear traces indicated that with the frictional couple of carbon steel ring/composite block (fillec with 7.5 wt.% filler), a thin, uniform, and tenacious transfer film was formed on the ring surface. It was inferred that the transfer film contributed largely to the decreased friction coefficient and wear rate of the filled PEEK composites. 相似文献
5.
采用高温固相扩散法合成了La0.96 Tb0.01 Dy0.03BO3荧光粉,用X射线粉末衍射及光电子能谱法等研究了γ射线辐照对其发光性能的影响.氧化物中的Tb3+与Dy3+离子转变成硼酸盐形态后,其4d电子结合能发生变异,Tb3+、Dy3+离子4d电子结合能趋于一致.在1.5104Gy辐照时, La0.96 Tb0.01 Dy0.03BO3荧光粉的发光强度增至最大.γ射线辐照使La0.96 Tb0.01 Dy0.03BO3晶粒细化和Tb3+、Dy3+离子4d电子结合能峰面积改变,结合能峰面积的变化与辐照剂量对发光强度的影响结果是一致的. 相似文献
6.
Cerium (III) fluoride as an antiwear or extreme pressure additive has been used in grease and bonded solid film lubricant, but its action mechanism has not been clarified. In this paper, the tribological characteristics of lithium grease containing CeF3, CaF2, SbF3, CeO2 and graphite fluoride ((CF)n) were evaluated with an SRV tester. The results show that pastes containing CaF2 and (CF)n give good antiwear and anti-friction performance, but do not possess extreme pressure properties. Adding CeO2 to grease offers no benefit to the antiwear and anti-friction performance of the paste. Paste containing SbF3 has poor lubricating properties. XPS analysis shows that the good antiwear and extreme pressure properties of paste containing CeF3 can be attributable to the formation of a physically adherent film and a chemical reaction film on the rubbing surface. Thermogravimetry shows that CeF3 acts as an agent for the slow release of the fluorine element. 相似文献
7.
凝胶丁腈共聚弹性体增韧聚甲醛的加工流变行为及力学性能 总被引:5,自引:0,他引:5
研究了聚甲醛(POM)/凝胶丁腈共聚弹性体(GNBE)共混物的熔体流动指数(MFI)、高压毛细管流变行为和力学性能。结果表明,共混物MFI随GNBE用量的增加下降较大。聚酰胺(PA)对POM/GNBE共混体系的MFI影响较小,而热塑性酚醛树脂(PFR)的影响显著。当PFR的质量份为4时,POM共混物的MFI达最小值(0.053g/min),约为未加增容剂POM共混物MFI的1/6。随着剪切速率的提高,共混物剪切黏度迅速与POM接近。这种黏度变化行为说明共混物比GNBE对剪切速率更敏感,共混物的黏度受POM的影响较大。随着剪切速率的提高,POM与GNBE的黏度比迅速减小,并接近1,说明POM和GNBE在高剪切速率下共混时,GNBE的液滴能够在POM连续相中分散达到最小。含20份GNBE的POM共混物在高剪切速率下的熔体表观黏度与POM相当;在PFR质量份为6时,POM共混物的缺口冲击强度达到21.6kJ/m2,超过了GNBE质量份为40的POM共混物。当PFR质量份为4时,共混物的缺口冲击强度为对应的不加增容剂共混物的冲击强度的2倍多,扯断伸长率提高了55.4%。 相似文献
8.
9.
The antiwear (AW) and extreme pressure (EP) properties of chlorine, sulphur, phosphorus-containing organic compounds and zinc dialkyldithiophosphate (ZDDP) oil additives are affected greatly by their reactive ability to the metal surface, as well as by the chemical composition, chemical state, physical and mechanical properties of the protective films formed. Over four decades, research has taken place on boundary lubrication, and a much better understanding of the AW and EP action mechanism of one additive by itself in base oil has been obtained, and much more knowledge on the relationship between wear and decomposition of additives, adsorption and reaction of the additive or its decomposed products with metal, has been gained. A series of analytical methods and a great number of modern surface analytical tools have been set up and used for research in this area. The problems and some suggestions for the future study on boundary lubrication of oil additive are proposed. 相似文献
10.
The influence of different pairs on the energy dissipation of a given hard coating during fretting has been discussed. Based
on the view of the competition between the elastic and plastic deformations in a fretting experiment, it suggests that the
energy dissipation rate is proportional to the elastic energy density of pairs. This trend is in agreement with the reported
experimental data. For comparison, hardness of pairs is used as the index to relate the antiwear properties of a DLC film
against different pairs. It is obvious that the elastic energy density of pairs is more appropriate to predict the antiwear
properties of the DLC film against different pairs. 相似文献