ABSTRACT The effect of chloride ions on the copper extraction equilibria, the rate of extraction, copper/iron selectivity, and chloride extraction was studied for organic phases containing pure ketoxime (LIX 84-IC) and pure nonylaldoxime (LIX 860N-IC). In these systems, the used aqueous phase contained total chloride concentrations from 0 to 110 g/l. It was determined that the chloride ions in the aqueous solution had a large negative effect on the extraction equilibria for LIX 84-IC and a small effect for LIX 860N-IC. This deleterious effect is attributed to an increase in the hydrogen ion activity coefficient in the presence of chloride ions. The chloride accelerated the rate of copper extraction even though the reaction was fast in all the tested conditions. An increase in the temperature from 25°C to 35°C affected positively the extraction equilibria for LIX 84-IC. 相似文献
This study analysed the influence of the codeposition of SiC particles with different sizes: 50 nm, 500 nm and 5 μm, and the type of bath agitation (stirring or ultrasonic) on the electrocrystallisation of nickel coatings. The composites matrix microstructure was analysed by means of SEM, EBSD and XRD, to evaluate the grain size, crystal orientation, and internal stresses and was benchmarked against pure nickel samples electrodeposited in equivalent conditions. The codeposition of nano- and microsize particles with an approximate content of 0.8 and 4 vol.%, respectively, caused only a minor grain refinement and did not vary the dominant?<?100?>?crystal orientation observed in pure Ni. The internal stress was, however, increased by particles codeposition, up to 104 MPa by nanoparticles and 57 MPa by microparticles, compared to the values observed in pure nickel (41 MPa). The higher codeposition rate (11 vol.%) obtained by the addition of submicron-size particles caused a change in the grain growth from columnar to equiaxial, resulting in deposits with a fully random crystal orientation and pronounced grain refinement. The internal stress was also increased by 800% compared to pure nickel. The ultrasound (US) agitation during the deposition caused grain refinement and a selective particle inclusion prompting a decrease in the content of the particles with the larger particles. The deposits produced under US agitation showed an increase in the internal stresses, with double values compared to stirring. The increase in the deposits microhardness, from 280 HV in pure Ni to 560 HV in Ni/SiC submicron-US, was linked to the microstructural changes and particles content.
The values of horizontal tectonic stresses are estimated up to depth of 11 500 m by the measurement of velocities of longitudinal and transverse waves in rock samples extracted from various depths when drilling Kola Ultradeep Well. 相似文献
An analysis and estimate are performed for possible schemes of spatial distribution of gas-dynamic phenomena in potash deposits by the methods of mathematical statistics. The problem stated is solved by comparing the numerical characteristics of the events observed and those obtained on the basis of the theoretical model developed. 相似文献
The study outlines the effects of surface and underground subsidence patterns on the spatial distribution of in-situ permeability and its effects on groundwater inflow. The behaviour of strata surrounding a longwall face where limited knowledge exists has been outlined. The effects of mining subsidence on the surface flow pattern have been described with the remedial solutions. The mechanism of formation of sinkholes in certain chemical rockmass has been described. Factors affecting mine water inflow have been described in detail with the aid of a simplified conceptual model and case studies. Practical examples of undersea workings and those under a large accumulation of water are given, both in the United Kingdom and worldwide. 相似文献
