全文获取类型
收费全文 | 522篇 |
免费 | 25篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 5篇 |
化学工业 | 170篇 |
金属工艺 | 11篇 |
机械仪表 | 20篇 |
建筑科学 | 8篇 |
矿业工程 | 3篇 |
能源动力 | 11篇 |
轻工业 | 17篇 |
无线电 | 37篇 |
一般工业技术 | 84篇 |
冶金工业 | 12篇 |
自动化技术 | 170篇 |
出版年
2023年 | 3篇 |
2022年 | 17篇 |
2021年 | 19篇 |
2020年 | 7篇 |
2019年 | 10篇 |
2018年 | 11篇 |
2017年 | 5篇 |
2016年 | 23篇 |
2015年 | 15篇 |
2014年 | 22篇 |
2013年 | 31篇 |
2012年 | 29篇 |
2011年 | 38篇 |
2010年 | 30篇 |
2009年 | 27篇 |
2008年 | 14篇 |
2007年 | 26篇 |
2006年 | 20篇 |
2005年 | 21篇 |
2004年 | 15篇 |
2003年 | 18篇 |
2002年 | 24篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 12篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 7篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1963年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有548条查询结果,搜索用时 0 毫秒
1.
Michael Bratychak Mihailo Bratychak Witold Brostow Olena Shyshchak 《Materials Research Innovations》2002,6(1):24-30
Oligomers containing peroxy groups have been synthesized on the basis of epoxides reacting with tert–butylhydroperoxide in the presence of boron trifluoride etherate. Dependence of reaction rates upon the quantity of catalyst,
temperature and also nature of hydroperoxide has been investigated: A kinetic equation for the process has been formulated
and also a kinetic scheme for the reaction taking into account the presence of boron trifluoride etherate is proposed. Structures
of the synthesized peroxy oligomers have been confirmed by IR- and NMR-spectroscopy. The reaction initiating properties of
the oligomers so synthesized were studied using as the example the styrene polymerization reaction.
Electronic Publication 相似文献
2.
Gonzalo Martínez‐Barrera Enrique Vigueras‐Santiago Susana Hernndez‐Lpez Gonzalo Martínez‐Barrera Witold Brostow Carmina Menchaca‐Campos 《Polymer Engineering and Science》2005,45(10):1426-1431
Fiber reinforced concrete (FRC) contains fibers physically mixed with gravel, sand, cement, and water. So far, adequate mechanical performance of FRC has been obtained at high cost and using complex technologies; important here is the geometry and surface characteristics of the polymers. We have modified polymeric‐fiber surfaces by using gamma radiation. Irradiated polypropylene (PP) fibers were submitted to 0, 5, 10, 50, and 100 kGy of gamma irradiation dosages. First, tensile strength of PP fibers was evaluated, and then fibers blended at 0, 1.0, 1.5, and 2.0% in volume with Portland cement, gravel, sand, and water. The highest values of compressive strength were obtained with irradiated‐fibers at 10 kGy and 1.5% in volume of fiber. The result is 101 MPa, as compared to 35 MPa for simple concrete without fibers. POLYM. ENG. SCI., 45:1426–1431, 2005. © 2005 Society of Plastics Engineers 相似文献
3.
A review of literature about the effect of oil pockets on improvement of sliding elements tribological performance as well as about the changes of surface topography during “zero-wear” process is shown. The paper presents also the results of experimental investigations done in the Department of Manufacturing Processes and Production Organisation of Rzeszow University of Technology, connected with the creation of oil pockets on sliding surfaces. In order to simulate a deterministic surface a program for the visualisation of pits was written. The procedures for assessment of the oil pocket size of specific shape and oil pockets coverage are presented. The tendencies of changes of surface topography and oil pockets dimensions during “zero-wear” process are also described. 相似文献
4.
Pedrycz W Bargiela A 《IEEE transactions on systems, man, and cybernetics. Part B, Cybernetics》2012,42(3):582-590
Clustering forms one of the most visible conceptual and algorithmic framework of developing information granules. In spite of the algorithm being used, the representation of information granules-clusters is predominantly numeric (coming in the form of prototypes, partition matrices, dendrograms, etc.). In this paper, we consider a concept of granular prototypes that generalizes the numeric representation of the clusters and, in this way, helps capture more details about the data structure. By invoking the granulation-degranulation scheme, we design granular prototypes being reflective of the structure of data to a higher extent than the representation that is provided by their numeric counterparts (prototypes). The design is formulated as an optimization problem, which is guided by the coverage criterion, meaning that we maximize the number of data for which their granular realization includes the original data. The granularity of the prototypes themselves is treated as an important design asset; hence, its allocation to the individual prototypes is optimized so that the coverage criterion becomes maximized. With this regard, several schemes of optimal allocation of information granularity are investigated, where interval-valued prototypes are formed around the already produced numeric representatives. Experimental studies are provided in which the design of granular prototypes of interval format is discussed and characterized. 相似文献
5.
Kallwass Helmut K.W.; Surewicz Witold K.; Parris Wendy; Macfarlane Emma L.A.; Luyten Marcel A.; Kay Cyril M.; Gold Marvin; Jones J.Bryan 《Protein engineering, design & selection : PEDS》1992,5(8):769-774
Lactate dehydrogenases are of considerable interest as stereospecificcatalysts in the chemical preparation of enantiomerically pure-hydroxyacid synthons. For such applications in synthetic organicchemistry it would be desirable to have enzymes which tolerateelevated temperatures for prolonged reaction times, to increaseproductivity and to extend then applicability to poor substrates.Here, two examples are reported of significant thermostabilizations,induced by sitedirected mutagenesis, of an already thermostableprotein, the L-lactate dehydrogenase (EC 1.1.1.27
[EC]
, 35 kDa permonomer subunit) from Bacillus stearothermophilus. Thermal inactivationof this enzyme is accompanied by irreversible unfolding of thenative protein structure. The replacement of Argl71 by Tyr stabilizesthe enzyme against thermal inactivation and unfolding. Thisstabilizing effect appears to be based on improved interactionsbetween the subunits in the core of the active dimeric or tetramericforms of the enzyme. The thermal stability of L-lactate dehydrogenasevariants with an active site Arg residue, either in the 171(wild-type) or in the 102 position, is further increased bysulfate ions. The two stabilizing effects are additive, as foundfor the Argl71Tyr/ Gln1O2Arg double mutant, for which the stabilityof the protein in 100 mM sulfate solution reaches that of L-lactatedehydrogenases from extreme thermophiles. All mutant proteinsretain significant catalytic activity, both in the presenceand absence of stnhilfoing salts, and are viable catalysts inpreparative scale reactions. 相似文献
6.
Karolina Bukowska-Strakova Joanna Wodek Ewelina Pitera Magdalena Kozakowska Anna Konturek-Ciela Maciej Ciela Monika Goka Witold Nowak Aleksandra Wieczorek Katarzyna Pawiska-Wsikowska Alicja Jzkowicz Maciej Siedlar 《International journal of molecular sciences》2021,22(3)
Whilst the survival rates of childhood acute lymphoblastic leukemia (ALL) have increased remarkably over the last decades, the therapy resistance and toxicity are still the major causes of treatment failure. It was shown that overexpression of heme oxygenase-1 (HO-1) promotes proliferation and chemoresistance of cancer cells. In humans, the HO-1 gene (HMOX1) expression is modulated by two polymorphisms in the promoter region: (GT)n-length polymorphism and single-nucleotide polymorphism (SNP) A(−413)T, with short GT repeat sequences and 413-A variants linked to an increased HO-1 inducibility. We found that the short alleles are significantly more frequent in ALL patients in comparison to the control group, and that their presence may be associated with a higher risk of treatment failure, reflecting the role of HO-1 in chemoresistance. We also observed that the presence of short alleles may predispose to develop chemotherapy-induced neutropenia. In case of SNP, the 413-T variant co-segregated with short or long alleles, while 413-A almost selectively co-segregated with long alleles, hence it is not possible to determine if SNPs are actually of phenotypic significance. Our results suggest that HO-1 can be a potential target to overcome the treatment failure in ALL patients. 相似文献
7.
8.
Friction and wear resistance are two vital tribological properties of polymer-based materials but optimization of both is rarely attempted. We have investigated blends of 70 wt% poly(vinylidene fluoride) (PVDF)+30% ultra high molecular weight polyethylene, the latter either un-irradiated or else γ-irradiated. Each sample contained varying amounts of carbon black (CB) and also had a varied degree of crosslinking and irradiation dose. We have determined static and dynamic friction, scratch resistance, and sliding wear in multiple scratching tests. Effects of the irradiation dose and CB concentration have been quantified. The electric conductivity threshold is reflected in a drop of static friction; formation of a continuous phase of the lubricant affects tribology as well as electrical properties—both for irradiated and for un-irradiated samples. The scratch resistance as represented by the residual (healing) depth is affected by crosslinking, by the stage at which irradiation is applied (before or after blending) and by CB addition. Crosslinking by moderate amounts of irradiation provides shallower residual depths while higher doses cause adverse results. Similarly, the CB lubricant can either improve or worsen the scratch resistance. A combination of both approaches produces either better or else worse results than crosslinking alone. Lower friction seems accompanied by higher scratch resistance. A combination of a specific irradiation dose and an optimized CB concentration lowers the sliding wear significantly. Strain hardening in sliding wear determination takes place for all materials studied, irrespective of the extent or radiation-induced crosslinking and of the presence and concentration of carbon black. 相似文献
9.
Witold Brostow Ligia Gargallo Andrea Hormazabal Magdalena Jaklewicz Kevin P Menard Alejandra Opazo Deodato Radic 《Polymer International》2004,53(4):460-464
We have studied blends of a polymer liquid crystal (PLC) with poly(cyclohexylethyl methacrylate) (PCHEMA) or poly(cyclohexylpropyl methacrylate) (PCHPMA). The PLC is PET/0.6PHB where PET = poly(ethylene terephthalate), PHB = p-hydroxybenzoic acid and 0.6 is the mole fraction of the latter in the copolymer. The microstructure was studied by scanning electron microscopy (SEM). PCHEMA + PLC (20 wt% of the latter, blend E) has a fine texture with LC islands evenly distributed in the matrix and good adhesion between the phases resulting from their partial miscibility. The PCHPMA + PLC (20 wt% of the latter, blend P) shows only limited compatibility. The SEM results are confirmed by values of the glass transition temperatures Tg determined via thermal mechanical analysis. The Tg value of the blend E is shifted towards the Tg of PLC; Tg of blend P is practically equal to that of PCHPMA. The linear isobaric expansivity αL values for both blends are lower than the respective values for pure PCHPMA and PCHEMA. Thermal stabilities of the blends determined by thermogravimetry are also better than those of pure polymethacrylates. The temperature of 50% weight degradation for blend E is higher than that for pure PCHEMA by more than 60 K Copyright © 2004 Society of Chemical Industry 相似文献
10.
In this paper, a fuzzy c‐means clustering algorithm based on interval‐valued weights is proposed for improving clustering performance. In the proposed algorithm, the interval‐valued weights are first constructed by synergy of the ReliefF algorithm and the analytic hierarchy process (AHP) method, and then they are transformed into a constraint condition associating with each weight variable in the weighted clustering objective function. In the sequence, the weighted clustering objective function is solved by combining the Lagrange multiplier method with the gradient‐based iteration computation. In the whole process of algorithm iteration, a compulsion strategy with human–computer cooperation is adopted to ensure each weight variable satisfies interval constraint itself. Three well‐known data set are used to perform profound experiments. Experimental results clearly show that the proposed algorithm has better clustering performance than other the weighted fuzzy c‐means clustering algorithm. 相似文献