Synthesis and luminescent properties of ternary complex Eu(UVA)3Phen in nano-TiO2

By introducing 2-hydroxy-4-methoxy-benzophenone(UVA) and 1,10-phenanthroline(Phen) as the ligands, the ternary rare earth complex of Eu(UVA)3Phen is synthesized, and it is characterized by elemental analysis, mass spectra(MS) and infrared(IR) and ultraviolet(UV) spectroscopy. Results show that the Eu(III) in complex emits strong red luminescence when it is excited by UV light, and it has higher sensitized luminescent efficiency and longer lifetime. The organic-inorganic thin film of complex Eu(UVA)3Phen doped with nano-Ti O2 is prepared, and the nano-Ti O2 is used in the luminescence layer to change the luminescence property of Eu(UVA)3Phen. It is found that there is an efficient energy transfer process between ligands and metal ions. Moreover, in an indium tin oxide(ITO)/poly(N-vinylcar-bazole)(PVK)/Eu(UVA)3Phen/Al device, Eu3+ can be excited by intramolecular ligand-to-metal energy transfer process. The main peak of emission at 613 nm is attributed to 5D0→7F2 transition of the Eu3+, and this process results in the enhanced red emission.     

利用数字图像关联技术评价固体材料的应变

为了研究基于数字图像关联技术(DIC)在材料应变测试中的精确度及使用范围,采用接触式引伸计、电阻应变片和DIC三种测试技术,分别对不锈钢、SiC/SiC复合材料和石墨弹性模量及在拉伸过程中的应变进行测试与评价.结果表明,三种测试技术测得的每种材料的弹性模量基本一致;但DIC在固体材料应变评价中的精度足以和引伸计相比,并...