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排序方式: 共有228条查询结果,搜索用时 46 毫秒
1.
Uzun İlhan Orak İkram Yağmur Hatice Karaer Karakaplan Mehmet Yalman Murat 《SILICON》2021,13(12):4703-4713
Silicon - 5-(2,4-dichlorophenyl)-2-furoic acid and anthraquinone-2-carboxylic acid were reacted separately with chitin. The synthesized products were characterized by various spectroscopic methods... 相似文献
2.
In the present study, the effects of charge‐transfer complex formation and intramolecular fragmentation (side‐chain lactonization) in radical copolymerization of tert‐butyl vinyl ether (t‐BVE) with anhydrides of maleic (MA) and citraconic (CA) acids and the structure–thermal behavior relationships of the resulting copolymers were examined using the 1H‐NMR, FTIR, DSC, and TGA analysis methods. It was shown that copolymerization under the chosen conditions proceeded through intramolecular fragmentation with the formation of γ‐lactone units. Side‐chain fragmentation of t‐BVE–MA and t‐BVE–CA copolymers also was confirmed by TGA and DSC analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2455–2463, 2006 2006 相似文献
3.
Hatice Kaplan Can A. Lale Doan Zakir M. O. Rzaev Ayegül Hasegeli Uner Ali Güner 《应用聚合物科学杂志》2006,100(5):3425-3432
The ternary copolymerization of maleic anhydride (MA), vinyl acetate (VA), and acrylic acid (AA) [P(MA‐co‐VA‐co‐AA)], which is considered to be an acceptor–donor–acceptor system, was carried out in 1,4‐dioxane with benzoyl peroxide as an initiator at 70°C under a nitrogen atmosphere. Constants of complex formation for the monomer systems in the study were determined by UV–visible (hydrogen‐bonding complex) and 1H‐NMR (charge transfer complex) methods, respectively. The results show that polymerization of the P(MA‐co‐VA‐co‐AA) system proceeds by an alternating terpolymerization mechanism. It is shown that the synthesized copolymers have typical polyelectrolyte behavior, ability for reversible hydrolysis–anhydrization reactions, and semicrystalline structures. In these cases, including radical polymerization, and formation of semicrystalline structures, the hydrogen‐bonding effect plays a significant role. The in vitro cytotoxicities of the synthesized terpolymer and alternating copolymer were evaluated using Raji cells (human Burkitt lymphoma cell line). The antitumor activities of prepared anion‐active copolymers were studied using methyl–thiazol–tetrazolium colorimetric assay and 50% of the cytotoxic dose of each copolymer and terpolymer were calculated. Hydrolyzed P(MA‐co‐VA‐co‐AA) and P(MA‐alt‐AA) copolymers have sufficiently high antitumor activity, which depends on the amount of hydrogen‐bonding carboxylic groups and their regular distribution in the side chain of functional macromolecules. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3425–3432, 2006 相似文献
4.
Hub location problems deal with finding the location of hub facilities and with the allocation of demand nodes to these located hub facilities. In this paper, we study the single allocation hub covering problem over incomplete hub networks and propose an integer programming formulation to this end. The aim of our model is to find the location of hubs, the hub links to be established between the located hubs, and the allocation of non-hub nodes to the located hub nodes such that the travel time between any origin–destination pair is within a given time bound. We present an efficient heuristic based on tabu search and test the performance of our heuristic on the CAB data set and on the Turkish network. 相似文献
5.
Sylvain Grosjean Mirella Wawryszyn Hatice Mutlu Stefan Brse Joerg Lahann Patrick Theato 《Advanced materials (Deerfield Beach, Fla.)》2019,31(26)
Bioinspiration has emerged as an important design principle in the rapidly growing field of materials science and especially its subarea, soft matter science. For example, biological cells form hierarchically organized tissues that not only are optimized and designed for durability, but also have to adapt to their external environment, undergo self‐repair, and perform many highly complex functions. Being able to create artificial soft materials that mimic those highly complex functions will enable future materials applications. Herein, soft matter technologies that are used to realize bioinspired material structures are described, and potential pathways to integrate these into a comprehensive soft matter research environment are addressed. Solutions become available because soft matter technologies are benefitting from the synergies between organic synthesis, polymer chemistry, and materials science. 相似文献
6.
Esra Bozkır Nurşen Sarı Hatice Öğütcü 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(5):1146-1155
An investigation of antimicrobial properties of 12 novel modified polymer derived from the condensation reaction of (aminomethyl)polystyrene and four substitute salicylaldehyde (2-hydroxy benzaldehyde, 5-fluoro-2 hydroxy benzaldehyde, 5-fluoro-3-chloro-salicylaldehyde and 5-fluoro-3-methyl-salicylaldehyde) has been carried out and Cr(III) and Ni(II) complexes have been prepared. Modified polymers were characterized by magnetic susceptibility, elemental analyses, and spectral studies. The 1H NMR and 13C NMR spectra analysis of the polymeric carbinolamine/azomethine were determined. In addition, surface morphology and composition were determined by SEM/EDX. Thermo gravimetric analyses of polymers were carried out in nitrogen atmosphere. Antibacterial activities of the polymers attached carbinolamine/azomethine and their complexes were studied by the well-diffusion method against Listeria monocytogenes 4b, Staphylococcus aureus, Escherichia coli, Salmonella typhi H, Brucella abortus, Staphylococcus epidermis sp., Micrococcus luteus, Shigella dysenteria type 10, Bacillus cereus, Pseudomonas putida and antifungal activity against Candida albicans. 相似文献
7.
Many problems in machine learning and computer vision consist of predicting multi-dimensional output vectors given a specific set of input features. In many of these problems, there exist inherent temporal and spatial dependencies between the output vectors, as well as repeating output patterns and input–output associations, that can provide more robust and accurate predictors when modeled properly. With this intrinsic motivation, we propose a novel Output-Associative Relevance Vector Machine (OA-RVM) regression framework that augments the traditional RVM regression by being able to learn non-linear input and output dependencies. Instead of depending solely on the input patterns, OA-RVM models output covariances within a predefined temporal window, thus capturing past, current and future context. As a result, output patterns manifested in the training data are captured within a formal probabilistic framework, and subsequently used during inference. As a proof of concept, we target the highly challenging problem of dimensional and continuous prediction of emotions, and evaluate the proposed framework by focusing on the case of multiple nonverbal cues, namely facial expressions, shoulder movements and audio cues. We demonstrate the advantages of the proposed OA-RVM regression by performing subject-independent evaluation using the SAL database that constitutes naturalistic conversational interactions. The experimental results show that OA-RVM regression outperforms the traditional RVM and SVM regression approaches in terms of accuracy of the prediction (evaluated using the Root Mean Squared Error) and structure of the prediction (evaluated using the correlation coefficient), generating more accurate and robust prediction models. 相似文献
8.
Hatice Bayrakçeken Jale Naktiyok A. Kadir Özer 《Chemical Engineering Communications》2017,204(8):916-925
In this study, polypyrrole (PPy)/carbon nanotube (CNT) composites were synthesized by in situ chemical oxidative polymerization of a pyrrole monomer on CNT. Two different types of CNT having different structural properties were used. The composites were characterized using BET surface area analysis, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA) techniques. Thermal decomposition kinetics of PPy/CNT composites was studied by thermal gravimetric analysis techniques (TG/DTG (differential thermal gravimetric)) at different heating rates (2.5, 5, 7.5, and 10?K min?1). Kinetic parameters of the composites were obtained from the TG and DTG curves using the Kissinger–Akahira–Sunose (KAS) and Flynn–Wall–Ozawa (FWO) models. The electrochemical capacitive properties of the composites were investigated by the cyclic voltammetry (CV) technique. Pt nanoparticles were decorated on the plain CNTs and composite materials via the microwave irradiation method. 相似文献
9.
Ring Opening of Epoxidized Soybean Oil with Compounds Containing Two Different Functional Groups
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Kemal Karadeniz Hatice Akı Mustafa Yasin Sen Yakup Çalıkoğlu 《Journal of the American Oil Chemists' Society》2015,92(5):725-731
Epoxidized vegetable oils are desirable chemicals due to their eco‐friendly characteristics and their being a major source of many green products. Ring opening is one of the ways to convert these epoxidized oils to some new intermediates. The use of mono‐functional amines, alcohols, acid anhydrides and thioethers for epoxy ring opening has been reported in the literature. In this study, thioglycolic acid (TGA) bearing thiol and carboxylic acid as two different functional groups and methyl ester of thioglycolic acid (TGAME) were used. Currently, there is no reported literature describing epoxy ring opening using chemicals bearing two different functional groups simultaneously. In this way, two new polyols were synthesized, one with TGA (polyol 1) and one with TGAME (polyol 2). FTIR and 1H‐ and 13C‐NMR spectroscopy confirmed that the ring was opened by the carboxylic acid group of TGA, and the thiol group was not involved in the ring opening whereas the ring was opened by the thiol group in the case of TGAME. 相似文献
10.
Karolina Mazur Raminder Singh Ralf P. Friedrich Hatice Gen Harald Unterweger Kamila Saasiska Rafa Bogucki Stanisaw Kuciel Iwona Cicha 《大分子材料与工程》2020,305(9)
The composites based on polylactide (PLA) and poly (3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) (PHBV) with the addition of antibacterial particles: silver (Ag) and copper oxide (CuO) are characterized. Basic mechanical properties and biodegradation processes, as well as biocompatibility of materials with human cells are determined. The addition of Ag or CuO to the polymers do not significantly affect their mechanical properties, flammability, or biodegradation rate. However, several differences between the base materials are observed. PLA‐based composites have higher tensile and impact strength values, while PHBV‐based ones have a higher modulus of elasticity, as well as better mechanical properties at elevated temperatures. Concerning biocompatibility, each of the tested materials support the growth of fibroblasts over time, although large differences are observed in the initial cell attachment. The analysis of hydrolytic degradation effects on the structure of materials shows that PHBV degrades much faster than PLA. The results of this study confirm the good potential of the investigated biodegradable polymer composites with antibacterial particles for future biomedical applications. 相似文献