Vibration data-driven machine learning architecture for structural health monitoring of steel frame structures

A vibration data-based machine learning architecture is designed for structural health monitoring (SHM) of a steel plane frame structure. This architecture uses a Bag-of-Features algorithm that extracts the speeded-up robust features (SURF) from the time-frequency scalogram images of the registered vibration data. The discriminative image features are then quantised to a visual vocabulary using K-means clustering. Finally, a support vector machine (SVM) is trained to distinguish the undamaged and multiple damage cases of the frame structure based on the discriminative features. The potential of the machine learning architecture is tested for an unseen dataset that was not used in training as well as with some datasets from entirely new damages close to existing (i.e., trained) damage classes. The results are then compared with those obtained using three other combinations of features and learning algorithms—(i) histogram of oriented gradients (HOG) feature with SVM, (ii) SURF feature with k-nearest neighbours (KNN) and (iii) HOG feature with KNN. In order to examine the robustness of the approach, the study is further extended by considering environmental variabilities along with the localisation and quantification of damage. The experimental results show that the machine learning architecture can effectively classify the undamaged and different joint damage classes with high testing accuracy that indicates its SHM potential for such frame structures.     

Improving post irradiation stability of high density polyethylene by multi walled carbon nanotubes

Sterilization of implants and other clinical accessories is an integral part of any medical application. Although many materials are used as implants, polyethylene stands unique owing to its versatility. Carbon nanotubes are being used as a filler material to enhance the properties of polyethylene. However, the role of multi walled carbon nanotubes (MWCNTs) as an effective antioxidant and radical scavenger in resisting the deteriorating effects of sterilization is yet to be studied in detail. The present work is aimed to investigate the mechanical properties and oxidation stability of irradiated high density polyethylene (HDPE) reinforced by MWCNTs with various concentrations such as 0.25%, 0.50%, 0.75% and 1.00 wt.%. The composites were exposed to ⁶⁰Co source in air and irradiated at different dosage level starting from 25 to 100 kGy and then shelf aged for a period of 120 days prior to investigation. The loss in toughness, Young’s modulus and ultimate strength at 100 kGy for 1 wt.% MWCNTs composite were found to be 21.5%, 20.3% and 19.2%, respectively compared to that of unirradiated composite. FTIR and ESR studies confirmed the antioxidant and radical scavenging potentialities of MWCNTs with increased concentration and irradiation dosage. It was found that by the addition of 1 wt.% MWCNTs into virgin HDPE, the oxidation index of the composite at 100 kGy was decreased by 56.2%. It is concluded that the addition of MWCNTs into polyethylene not only limits the loss of mechanical properties but also improves its post irradiation oxidative stability.     

Study on the viscoelastic response of silk

Simple stress-strain characteristics of silk do not give sufficient information on the influence of the rate of testing in silk. A methodology is described to quantify individual components of viscoelasticity which clearly brings out the influence of the strain rate on the viscous component of the system. © 1996 John Wiley & Sons, Inc.     

Chemical composition dependence of exposure buildup factors for some polymers

Exposure buildup factors for some polymers such as poly-acrylo-nitrile (PAN), poly-methyl-acrylate (PMA), poly-vinyl-chloride (PVC), synthetic rubber (SR), tetra-fluro-ethylene (Teflon) have been computed using the G.P. fitting method in the energy range of 0.015–15.0 MeV, up to the penetration of 40 mean free paths (mfp). The variation of exposure buildup factors for all the selected polymers with incident photon energy at the fixed penetration depths has been studied, mainly emphasizing on chemical composition (equivalent atomic number) of the selected polymers. It has been observed that for the lower penetration depths (below 10 mfp), the exposure buildup factor decreases with the increase in equivalent atomic number of the selected polymers at all the incident photon energies. However, at the penetration depth of 10 mfp and incident photon energy above 3 MeV, the exposure buildup factor becomes almost independent of the equivalent atomic number of the selected polymers. Further, above the fixed penetration depth of 15 mfp of the selected polymers and above the incident photon energy of 3 MeV, reversal in the trend has been observed, i.e., the exposure buildup factor increases with the increase in equivalent atomic number.     

Effect of microwave heating on quality and mycoflora of sorghum grain

Sorghum (cv. Maldandi M35-1) was modified to 12, 14 and 16% moisture content (m.c.) and heat-treated with microwave energy at 3 levels, for 30 sec (=4.5, 9 and 18 kJ), and 60 sec (=9, 18 and 36 kJ). The effect of microwave heating on rise and subsequent fall in grain temperature, reduction in m.c. and quality characteristics including germination, seedling dry matter, free fatty acids (FFA) and contaminant fungi was determined. The temperature attained and the moisture loss in the sorghum grain was affected by grain m.c. and the time of exposure. At the lowest and highest microwave treatment level grain temperatures reached 30–40°C and 90–101°C, respectively. However, a 60-sec treatment at the highest energy level was lethal for the grain, particularly at 14 and 16% m.c. The FFA values were unaffected by microwave treatment. Statistical analyses showed that the microwave power level and time individually, and power level × time interactions were significant for most quality characteristics. The fungi present most abundantly on the sorghum grain were Eurotium spp., Aspergillus candidus, A. niger and Penicillium spp. Increasing m.c. and microwave heating resulted in elimination of most fungi after a 30-sec exposure time. With a 60-sec exposure period, practically all fungi were eliminated from the grain.     

Green synthetic route of carbon quantum dot-reinforced graphene oxide-poly(vinylidene fluoride-co-hexa fluoropropylene) nanocomposites: Toward high dielectric constant and suppressed loss

A simple and green method was developed to fabricate carbon quantum dot@ graphene oxide filled poly (vinylidene fluoride-co-hexa-fluoropropylene) [CQD@GO-P(VDF-HFP)] nanocomposite films via solution casting technique. The synthetic approach was to bring CQD from bilva leafs, a renewable and sustainable resource. The effect of CQD on dielectric properties, dielectric constant, and dielectric loss in the presence of GO along with P (VDF-HFP) matrix were investigated. The result showed that the nanocomposites having 1.5 wt % of CQD@GO-P(VDF-HFP) with higher dielectric constant (≈144) at 100 Hz and suppressed loss (<1) at 1000 Hz, which is well supported by field emission scanning electron microscopy (FESEM) study. The FESEM study shows a river iceland morphology with a channel-like structure along with voids and pores that may provide a conducting network, which tends to have Maxwell Wagner-Sillars or interfacial polarization results in a high-end properties outcome. Furthermore, the suppressed loss enhanced the possibility of end use performance of CQD@GO-P(VDF-HFP) matrix with a referral memorandum of percolation theory. Thus, the present work demonstrated a new approach to develop high dielectric constant and negligible loss materials in the field of embedded devices for electronic industries through green synthetic approach. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47850.     

Insulating and Other Physical Properties of CoO‐Doped Zinc Oxyfluoride‐Borate Glass‐Ceramics

Zinc oxy fluoro borate glasses mixed with different concentrations of CoO (ranging from 0 to 2.0 mol%) are synthesized and subsequently crystallized. The scanning electron microscopy pictures have exhibited crystallinity. Differential scanning calorimetric studies have indicated that the prepared samples consist of multiple crystal phases. The X‐ray diffraction patterns have indicated that the glass‐ceramic samples are composed of αZn(BO₂)_2, (Zn)₃(BO₃)_2, CoF₂, CoF₃, Co₃FB₇O₁₃, ZnCo₂O₄, Co₃O₄ crystalline phases. The optical absorption and photoluminescence studies have indicated that there is a gradual increase of tetrahedral cobalt ion concentration with increase of CoO concentration in the glass network. IR spectroscopic studies have pointed out increased degree of polymerization of the zinc oxy fluoro borate glass network with increase of CoO content. The analysis of results of dielectric properties indicated increase of insulating strength of the glass‐ceramics with increase of CoO content. Finally, the dielectric breakdown strength of the samples is measured at room temperature in air medium and it is found to increase from 12.9 to 19.2 kV/cm with increase of CoO from 0.2 to 2.0 mol%. The reasons for such increase of breakdown strength are discussed quantitatively in terms of dielectric parameters with aid of data on spectroscopic properties.     

Increased Uptake of Chelated Copper Ions by Lolium perenne Attributed to Amplified Membrane and Endodermal Damage

The contributions of mechanisms by which chelators influence metal translocation to plant shoot tissues are analyzed using a combination of numerical modelling and physical experiments. The model distinguishes between apoplastic and symplastic pathways of water and solute movement. It also includes the barrier effects of the endodermis and plasma membrane. Simulations are used to assess transport pathways for free and chelated metals, identifying mechanisms involved in chelate-enhanced phytoextraction. Hypothesized transport mechanisms and parameters specific to amendment treatments are estimated, with simulated results compared to experimental data. Parameter values for each amendment treatment are estimated based on literature and experimental values, and used for model calibration and simulation of amendment influences on solute transport pathways and mechanisms. Modeling indicates that chelation alters the pathways for Cu transport. For free ions, Cu transport to leaf tissue can be described using purely apoplastic or transcellular pathways. For strong chelators (ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA)), transport by the purely apoplastic pathway is insufficient to represent measured Cu transport to leaf tissue. Consistent with experimental observations, increased membrane permeability is required for simulating translocation in EDTA and DTPA treatments. Increasing the membrane permeability is key to enhancing phytoextraction efficiency.     

Structural,thermal, dielectric and ac conductivity properties of lithium fluoro-borate optical glasses

Transparent and stable glasses in the chemical composition of Li₂O–LiF–B₂O₃–MO (M = Zn and Cd) have been prepared by a conventional melt quenching method. For these glasses, absorption spectra, structural (XRD, FT-IR, and Raman spectra), thermal (TG–DTA and DSC), dielectric (?′, ?″, tan δ), ac conductivity (σ_ac), and electric modulus (M′ and M″) have been investigated. Amorphous nature of these glasses has been confirmed from their XRD profiles. The LFB glasses with the presence of ZnO or CdO an extended UV-transmission ability has been achieved. The measured FT-IR and Raman spectra have exhibited the vibrational bands of B–O from [BO₃] and [BO₄] units and Li–O. The dielectric properties (tan δ, dielectric constant (?′), dielectric loss (?″)), electrical modulus and electrical conductivity (σ_ac) of these glasses have also been studied from 100 Hz to 1 MHz at the room temperature. Based on the trends noticed in the ac conductivities, the present glasses could be found useful as battery cathode materials.