Use of electrodialysis to remove silver ions frommodel solutions and wastewater

The feasibility of the removal of Ag⁺ ions in a model solution and a sample of rinse water provided from an industrial plating plantwas investigated in a batch electrodialysis system. The experiments were carried out using two different types of ion-exchange membranes. The effects of applied potential, pH value and initial silver concentration on the duration of electrodialysis and energy consumption were examined. Full removal of Ag+ ions was achieved from model solutions and the sample of rinse water. The most convenient applied voltage and energy consumption values to remove silver ions are reported. These results will be useful for designing and operating different capacities of electrodialysis plants for recovering Ag⁺ ions.     

Assessment of Water Quality Management in Turkey

Abstract

There has been a noticeable increase in the amount of pollution in water resources in Turkey in recent years. Negative environmental developments, such as industrialization, increasing urbanization, improper pesticide and fertilizer applications in agricultural lands, and the drainage of domestic and industrial wastewater into water resources without any waste treatment applications, cause rapid pollution of both surface and groundwater resources. Therefore, it is necessary to allocate more attention to water resources monitoring and evaluation studies to prevent the pollution of water resources, and to reclaim these resources.     

An improved tank in series model for PEMFC

This study presents an improved Tank in Series Reactor (TSR) Proton Exchange Membrane (PEM) fuel cell model with mass and energy balance equations accounting for evaporation and condensation in cathode channels. The TSR model includes the modified charge balance equation suitable for potentiostatic fuel cell operation mode. Polarization curves calculated with the improved model agree with experimental data from the literature. The developed TSR model is able to predict the limiting two-dimensional profiles in PEMFC. Simulation results illustrate the influence of co-current and counter current mode on PEM fuel cell performance.     

Comparative study of adsorption properties of Turkish fly ashes. II. The case of chromium (VI) and cadmium (II)

The purpose of the study described in this paper was to compare the removal of Cr(VI) and Cd(II) from an aqueous solution using two different Turkish fly ashes; Afsin-Elbistan and Seyitomer as adsorbents. The influence of four parameters (contact time, solution pH, initial metal concentration in solution and ash quality) on the removal at 20+/-2 degrees C was studied. Fly ashes were found to have a higher adsorption capacity for the adsorption of Cd(II) as compared to Cr(VI) and both Cr(VI) and Cd(II) required an equilibrium time of 2h. The adsorption of Cr(VI) was higher at pH 4.0 for Afsin-Elbistan fly ash (25.46%) and pH 3.0 for Seyitomer fly ash (30.91%) while Cd(II) was adsorbed to a greater extent (98.43% for Afsin-Elbistan fly ash and 65.24% for Seyitomer fly ash) at pH 7.0. The adsorption of Cd(II) increased with an increase in the concentrations of these metals in solution while Cr(VI) adsorption decreased by both fly ashes. The lime (crystalline CaO) content in fly ash seemed to be a significant factor in influencing Cr(VI) and Cd(II) ions removal. The linear forms of the Langmuir and Freundlich equations were utilised for experiments with metal concentrations of 55+/-2mg/l for Cr(VI) and 6+/-0.2mg/l for Cd(II) as functions of solution pH (3.0-8.0). The adsorption of Cr(VI) on both fly ashes was not described by both the Langmuir and Freundlich isotherms while Cd(II) adsorption on both fly ashes satisfied only the Langmuir isotherm model. The adsorption capacities of both fly ashes were nearly three times less than that of activated carbon for the removal of Cr(VI) while Afsin-Elbistan fly ash with high-calcium content was as effective as activated carbon for the removal of Cd(II). Therefore, there are possibilities for use the adsorption of Cd(II) ions onto fly ash with high-calcium content in practical applications in Turkey.     

Determination of selenium in garlic (Allium sativum) and onion (Allium cepa) by electro thermal atomic absorption spectrometry

A separation/enrichment procedure has been developed for the determination of selenium in garlic and onion samples by electrothermal atomic absorption spectrometry (ET-AAS) as a slurry sampling after preconcentration with 3,3-diaminobenzidine (DAB) reagent on the activated carbon. The influences of pH, time, amount of carbon and complexing reagent were outlined. The effect of acids used in the digestion of samples was also studied and compared. Selenium level was found to be 0.024 μg g⁻¹ for onion (n = 5; LOD – 0.5 μg L⁻¹; LOQ – 1.7 μg L⁻¹) and 0.015 μg g⁻¹ for garlic (n = 5; LOD – 1.3 μg L⁻¹; LOQ – 3.3 μg L⁻¹). Three different samples of garlic were analyzed by k₀-instrumental neutron activation analysis (k₀-INAA) at the Jozef Stefan Institute (JSI). The data obtained by k₀-INAA show that the content of selenium overlapped the results obtained by ET-AAS.     

Effect of ultraviolet and far infrared radiation on microbial decontamination and quality of cumin seeds

Abstract: Cumin seeds might be exposed to a high level of natural bacterial contamination, and this could potentially create a public health risk besides leading to problems in exportation. Ultraviolet (UVC) and far infrared (FIR) radiation has low penetration power, and due to that, there might be no detrimental defects to the products during a possible decontamination process. Therefore, the objective of this study was to determine the effect of UVC and FIR treatment on microbial decontamination and quality of cumin seeds. For this purpose, FIR treatment at different exposure times and temperatures were applied followed by constant UVC treatment with an intensity of 10.5 mW/cm² for 2 h. Total mesophilic aerobic bacteria of the cumin seeds were decreased to the target level of 10⁴ CFU/g after 1.57, 2.8, and 4.8 min FIR treatment at 300, 250, and 200 °C, respectively, following a 2 h UVC treatment. Under the given conditions, a complete elimination for total yeast and molds were obtained while there were no significant changes in volatile oil content and color of the cumin seeds. Consequently, combined UVC and FIR treatment was determined to be a promising method for decontamination of the cumin seeds. Practical Application: This research attempts to apply UVC and far infrared (FIR) radiation for pasteurization of cumin seeds. The data suggested that combined UVC and FIR radiation treatments can become a promising new method for pasteurization of cumin seeds without causing any detrimental defect to the quality parameters. The results of this industry partnered (Kadioglu Baharat, Mersin, Turkey— http://www.kadioglubaharat.com ) study were already applied in industrial scale production lines.     

Current density measurements in direct methanol fuel cells

The current density in the fuel cell is the direct consequence of reactions taking place over the active surface area. Thus, measurement of its distribution will lead to identification of the location and nature of reactions and will give opportunity to improve the overall efficiency of fuel cells. Within this study, the current density distribution in a direct methanol fuel cell was analyzed by segmenting the current collector into nine sections. Besides, the effect of the different operating parameters such as molarity, flow rate and reactant gas on the current density distribution was analyzed.     

Chemical characterization of the mutagenic neutral aromatic polar fractions of petroleum substitutes

The constituents of the neutral aromatic polar subfractions of two coal-derived oils, a shale-derived oil and a petroleum oil were analysed and compared. Chemical ionization mass spectra, using methanol and ammonia as reagent gases, were used to characterize the oxygen-and nitrogen-containing constituents, respectively. The compositions of the petroleum substitutes were found to differ from those of petroleum in containing primary polycyclic aromatic amines, azaarenes, polycyclic hydroxyaromatics and, in one case, aromatic ketones.     

Performance of energy-efficient rice mills

ABSTRACT

This study reports the energy-efficient performance of three different brands of rice polisher machines operating at different rice mills. The observations of feed screws, sieves and cams have been recorded and we have analysed the chemical composition, microstructure, hardness of cams of different rice mills and given solutions for the performance enhancement of cams. Our objective is to enhance the production of rice variety with quality characteristics and general appearance as required by the consumers.     

A novel differential evolution application to short-term electrical power generation scheduling

This paper proposes a new way of applying a differential evolution algorithm to short-term electrical power generation scheduling. Traditionally, the problem is divided into two subproblems. An evolutionary algorithm, which works with binary decision variables, is applied to the first subproblem to find a low cost scheduling of power generators, satisfying some operational constraints. Then, the lambda-iteration method, is used to calculate the power generated by the online generators. In this study, the problem is treated as a whole for the first time in literature and an application of a real-valued differential evolution algorithm is proposed. This approach eliminates the use of an iterative local search technique such as lambda-iteration in all solution evaluations. Through comparisons with results from literature, it is shown that the proposed method achieves a similar solution quality to existing methods, without needing the time consuming lambda-iteration step. Finally, the new approach is applied to real-world data from the Turkish interconnected power network.