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1.
2.
Dario Pasini Luigi Garlaschelli Elza Bontempi Laura E. Depero 《Fullerenes, Nanotubes and Carbon Nanostructures》2007,15(5):367-378
The synthesis of a series of polymers and cyclopolymers bearing crown ethers of differing structure and affinities towards primary ammonium ions is discussed. These polymers have been tested in their efficiency to form structurally homogeneous thin films when blended with an amphiphilic C60 compound containing a primary ammonium ion functional group. The X-ray reflectivity characterization of the films revealed that the polymer bearing the crown ether with the least affinity for primary ammonium ions, but having the highest degree of polymerization, is the most effective in forming structurally homogeneous thin films. 相似文献
3.
Chiara Damiani Dario Pescini Riccardo Colombo Sara Molinari Lilia Alberghina Marco Vanoni Giancarlo Mauri 《Natural computing》2014,13(3):321-331
Constraint-based modeling is largely used in computational studies of metabolism. We propose here a novel approach that aims to identify ensembles of flux distributions that comply with one or more target phenotype(s). The methodology has been tested on a small-scale model of yeast energy metabolism. The target phenotypes describe the differential pattern of ethanol production and O2 consumption observed in “Crabtree-positive” and “Crabtree-negative” yeasts in changing environment (i.e., when the upper limit of glucose uptake is varied). The ensembles were obtained either by selection among sampled flux distributions or by means of a search heuristic (genetic algorithm). The former approach provided indication about the probability to observe a given phenotype, but the resulting ensembles could not be unambiguously partitioned into “Crabtree-positive” and “Crabtree-negative” clusters. On the contrary well-separated clusters were obtained with the latter method. The cluster analysis further allowed identification of distinct groups within each target phenotype. The method may thus prove useful in characterizing the design principles underlying metabolic plasticity arising from evolving physio-pathological or developmental constraints. 相似文献
4.
Pierpaolo D’Urso Dario Di Lallo Elizabeth Ann Maharaj 《Soft Computing - A Fusion of Foundations, Methodologies and Applications》2013,17(1):83-131
Fuzzy clustering enables the simultaneous membership of objects in two or more clusters. This is particularly pertinent where time series are concerned, because very often patterns of time series change over time. Thus, a time series might belong to different clusters over different periods of time, in which case, crisp clustering is unable to capture this multi-cluster membership. In this paper, we adopt a Fuzzy C-Medoids approach to clustering time series based on autoregressive estimates of models fitted to the time series. We illustrate very good performance of this approach in a range of simulation studies. By means of two applications, we also show the usefulness of this clustering approach in the air pollution monitoring, by considering air pollution time series, i.e., CO time series, CO2 time series and NO time series monitored on world and urban scales. In particular, we show that, by considering in the clustering process, the autoregressive representation of these air pollution time series, we are able to detect possible information redundancy in the monitoring networks and then, decreasing the number of monitoring stations, to reduce the monitoring costs and then to increase the monitoring efficiency of the networks. 相似文献
5.
Cecilia Laschi Gioel Asuni Eugenio Guglielmelli Giancarlo Teti Roland Johansson Hitoshi Konosu Zbigniew Wasik Maria Chiara Carrozza Paolo Dario 《Autonomous Robots》2008,25(1-2):85-101
This paper presents a sensory-motor coordination scheme for a robot hand-arm-head system that provides the robot with the capability to reach an object while pre-shaping the fingers to the required grasp configuration and while predicting the tactile image that will be perceived after grasping. A model for sensory-motor coordination derived from studies in humans inspired the development of this scheme. A peculiar feature of this model is the prediction of the tactile image. The implementation of the proposed scheme is based on a neuro-fuzzy module that, after a learning phase, starting from visual data, calculates the position and orientation of the hand for reaching, selects the best-suited hand configuration, and predicts the tactile feedback. The implementation of the scheme on a humanoid robot allowed experimental validation of its effectiveness in robotics and provided perspectives on applications of sensory predictions in robot motor control. 相似文献
6.
Caleb Krouse Aaron A. Jennings Dario Gasparini 《Environmental Modelling & Software》2009,24(4):557-568
Consumer batteries littered on urban pavements release metals of environmental significance (Ag, Cd, Cr, Cu, Hg, Li, Mn, Ni, Pd, Ti, Zn) to stormwater runoff. Predicting the mass loading of any one metal is difficult because of the random composition of battery litter. However, when littering is modeled as a conditional filtered Poisson process, bounds may be estimated for the mean and variance of site mass loading for any metal if the site litter rate and battery product contributions are known. Site-specific data on the battery brand distribution in litter can improve load estimates, but statistics computed from 5500 littered batteries collected in the Cleveland area may be used to approximate the brand distribution. Zinc load calculations based on battery litter size, type and brand discretizations are implemented in a model titled BLML and illustrated for a case-study location. Results indicate that, at some urban sites, zinc released from battery litter can be the largest source of zinc in urban pavement runoff. 相似文献
7.
Foehn Philipp Brescianini Dario Kaufmann Elia Cieslewski Titus Gehrig Mathias Muglikar Manasi Scaramuzza Davide 《Autonomous Robots》2022,46(1):307-320
Autonomous Robots - This paper presents a novel system for autonomous, vision-based drone racing combining learned data abstraction, nonlinear filtering, and time-optimal trajectory planning. The... 相似文献
8.
Dario Campagna 《Theoretical computer science》2010,411(20):2037-2051
Hybrid automata are a powerful formalism for the representation of systems evolving according to both discrete and continuous laws. Unfortunately, undecidability soon emerges when one tries to automatically verify hybrid automata properties. An important verification problem is the reachability one that demands to decide whether a set of points is reachable from a starting region.If we focus on semi-algebraic hybrid automata the reachability problem is semi-decidable. However, high computational costs have to be afforded to solve it. We analyse this problem by exploiting some existing tools and we show that even simple examples cannot be efficiently solved. It is necessary to introduce approximations to reduce the number of variables, since this is the main source of runtime requirements. We propose some standard approximation methods based on Taylor polynomials and ad hoc strategies. We implement our methods within the software SAHA-Tool and we show their effectiveness on two biological examples: the Repressilator and the Delta-Notch protein signaling. 相似文献
9.
Dario Alfè 《Computer Physics Communications》2009,180(12):2622-2633
The program phon calculates force constant matrices and phonon frequencies in crystals. From the frequencies it also calculates various thermodynamic quantities, like the Helmholtz free energy, the entropy, the specific heat and the internal energy of the harmonic crystal. The procedure is based on the small displacement method, and can be used in combination with any program capable to calculate forces on the atoms of the crystal. In order to examine the usability of the method, I present here two examples: metallic Al and insulating MgO. The phonons of these two materials are calculated using density functional theory. The small displacement method results are compared with those obtained using the linear response method. In the case of Al the method provides accurate phonon frequencies everywhere in the Brillouin Zone (BZ). In the case of MgO the longitudinal branch of the optical phonons near the centre of the BZ is incorrectly described as degenerate with the two transverse branches, because the non-analytical part of the dynamical matrix is ignored here; however, thermodynamic properties like the Helmholtz free are essentially unaffected.
Program summary
Program title: PHONCatalogue identifier: AEDP_v1_0Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEDP_v1_0.htmlProgram obtainable from: CPC Program Library, Queen's University, Belfast, N. IrelandLicensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.htmlNo. of lines in distributed program, including test data, etc.: 19 580No. of bytes in distributed program, including test data, etc.: 612 193Distribution format: tar.gzProgramming language: Fortran 90Computer: Any Unix, LinuxOperating system: UnixRAM: Depends on super-cell size, but usually negligibleClassification: 7.8External routines: Subprograms ZHEEV and DSYEV (Lapack); needs BLAS. A tutorial is provided with the distribution which requires the installation of the quantum-espresso package (http://www.quantum-espresso.org)Nature of problem: Stable crystals at low temperature can be well described by expanding the potential energy around the atomic equilibrium positions. The movements of the atoms around their equilibrium positions can then be described using harmonic theory, and is characterised by global vibrations called phonons, which can be identified by vectors in the Brillouin zone of the crystal, and there are 3 phonon branches for each atom in the primitive cell. The problem is to calculate the frequencies of these phonons for any arbitrary choice of q-vector in the Brillouin zone.Solution method: The small displacement method: each atom in the primitive cell is displaced by a small amount, and the forces induced on all the other atoms in the crystal are calculated and used to construct the force constant matrix. Supercells of ∼100 atoms are usually large enough to describe the force constant matrix up to the range where its elements have fallen to negligibly small values. The force constant matrix is then used to compute the dynamical matrix at any chosen q-vector in the Brillouin zone, and the diagonalisation of the dynamical matrix provides the squares of the phonon frequencies. The PHON code needs external programs to calculate these forces, and it can be used with any program capable of calculating forces in crystals. The most useful applications are obtained with codes based on density functional theory, but there is no restriction on what can be used.Running time: Negligible, typically a few seconds (or at most a few minutes) on a PC. It can take longer if very dense meshes of q-points are needed, for example, to compute very accurate phonon density of states. 相似文献10.
OBJECTIVE: This paper introduces a robust, real-time system for detecting driver lane changes. Background: As intelligent transportation systems evolve to assist drivers in their intended behaviors, the systems have demonstrated a need for methods of inferring driver intentions and detecting intended maneuvers. METHOD: Using a "model tracing" methodology, our system simulates a set of possible driver intentions and their resulting behaviors using a simplification of a previously validated computational model of driver behavior. The system compares the model's simulated behavior with a driver's actual observed behavior and thus continually infers the driver's unobservable intentions from her or his observable actions. RESULTS: For data collected in a driving simulator, the system detects 82% of lane changes within 0.5 s of maneuver onset (assuming a 5% false alarm rate), 93% within 1 s, and 95% before the vehicle moves one fourth of the lane width laterally. For data collected from an instrumented vehicle, the system detects 61% within 0.5 s, 77% within 1 s, and 84% before the vehicle moves one-fourth of the lane width laterally. CONCLUSION: The model-tracing system is the first system to demonstrate high sample-by-sample accuracy at low false alarm rates as well as high accuracy over the course of a lane change with respect to time and lateral movement. APPLICATION: By providing robust real-time detection of driver lane changes, the system shows good promise for incorporation into the next generation of intelligent transportation systems. 相似文献