Time Decay of the Activity of the Reduction Reaction of NO by CO on a Pd/Al2O3 Catalyst

An experimental study is made of the time decay of activity of the CO–NO reaction on a Pd/Al₂O₃ looking at the effect on reaction order and apparent activation energy. The optimum kinetics parameters fitting the steady state data at moderate pressures are determined. The time decay curves are analyzed through various catalyst deactivation models.     

β-hydroxyacyl-coa-dehydrogenase (HADH) activity of unfrozen and frozen—thawed frog (Rana esculenta) legs

The β-hydroxyacyl-CoA-dehydrogenase (HADH) activity of unfrozen and thawed frog legs was investigated. The enzyme was extracted by either immersing frog legs in phosphate buffer 0.1 M, pH 6.0 at 25°C for 15 min or pressing them between trichinoscopy glasses. The enzyme activity was assayed using acetoacetyl-CoA as substrate and measured spectrophotometrically at 340 nm. It was possible by both extraction methods to distinguish between thawed and unfrozen samples although when the juice was obtained by pressing the HADH activity of the dilution was ～ 1.5 times higher than that obtained by immersion. The HADH activity was significantly higher (P≤0·001) in frozen-thawed frogs than in unfrozen legs because during freezing there is a release of HADH. No significative differences were found in the HADH activity in samples frozen in the temperature range -10 to -196°C. HADH activity was not affected by the storage time in crushed ice up to 6 days.     

Implicit and hybrid methods for attribute weighting in multi-attribute decision-making: a review study

Artificial Intelligence Review - Attribute weighting is a task of paramount relevance in multi-attribute decision-making (MADM). Over the years, different approaches have been developed to face...     

Word sense disambiguation for spam filtering

Spam has become a major issue in computer security because it is a channel for threats such as computer viruses, worms, and phishing. More than 86% of received e-mails are spam. Historical approaches to combating these messages, including simple techniques such as sender blacklisting or the use of e-mail signatures, are no longer completely reliable. Many current solutions feature machine-learning algorithms trained using statistical representations of the terms that most commonly appear in such e-mails. However, these methods are merely syntactic and are unable to account for the underlying semantics of terms within messages. In this paper, we explore the use of semantics in spam filtering by introducing a pre-processing step of Word Sense Disambiguation (WSD). Based upon this disambiguated representation, we apply several well-known machine-learning models and show that the proposed method can detect the internal semantics of spam messages.     

The Utility of Land-Surface Model Simulations to Provide Drought Information in a Water Management Context Using Global and Local Forcing Datasets

Drought diagnosis and forecasting are fundamental issues regarding hydrological management in Spain, where recurrent water scarcity periods are normal. Land-surface models (LSMs) could provide relevant information for water managers on how drought conditions evolve. Here, we explore the usefulness of LSMs driven by atmospheric analyses with different resolutions and accuracies in simulating drought and its propagation to precipitation, soil moisture and streamflow through the system. We perform simulations for the 1980-2014 period with SASER (5 km resolution) and LEAFHYDRO (2.5 km resolution), which are forced by the Spanish SAFRAN dataset (at 5km and 30km resolutions), and the global eartH2Observe datasets at 0.25 degrees (including the MSWEP precipitation dataset). We produce standardized indices for precipitation (SPI), soil moisture (SSMI) and streamflow (SSI). The results show that the model structure uncertainty remains an important issue in current generation large-scale hydrological simulations based on LSMs. This is true for both the SSMI and SSI. The differences between the simulated SSMI and SSI are large, and the propagation scales for drought regarding both soil moisture and streamflow are overly dependent on the model structure. Forcing datasets have an impact on the uncertainty of the results but, in general, this impact is not as large as the uncertainty due to model formulation. Concerning the global products, the precipitation product that includes satellite observations (MSWEP) represents a large improvement compared with the product that does not.

     

A Robust Controller for A 3‐DOF Flexible Robot with a Time Variant Payload

This article describes a new control scheme designed for a three degree of freedom (3‐DOF) flexible robot. The control scheme consists of two multi variable control loops. The inner loop is the motor's position control system, while the outer loop controls the robot tip's position, thus canceling vibrations which are originated by the structural flexibility of the manipulator during movement. As it will be shown, the outer control loop is robust to payload variations. The outer loop performance is based on a perfect cancelation of the inner loop dynamics. The effects of not achieving such perfect cancelation are also studied, and rules for designing a robust controller in this case are developed. Simulations assuming different payloads have been carried out with successful results for trajectory tracking. Trajectory tracking with a variable payload is also achieved.     

Energy-Harvesting Microresonator Based on the Forces Generated by the Karman Street Around a Rectangular Prism

This paper explores the feasibility of using the unsteady forces generated by the Karman street around a microprism in the laminar flow regime as a means to generate mechanical work. In particular, the study has the objective of assessing whether this physical effect could be used for practical energy-harvesting purposes. The confined flow, either of a liquid or a gas, around a rectangular microprism, of which different aspect ratios have been studied, is considered at Reynolds 200 so as to make sure that the Karman street is developed and that the flow remains 2-D. The microprism is allowed to move freely in the direction perpendicular to the flow. The equation of motion of the prism includes a term that simulates its coupling with a vibration-driven micropower generator. Two different couplings have been considered: a velocity-damped resonant generator and a Coulomb-damped resonant generator. Different configurations have been studied, and comparisons have been carried out between them so as to draw a first set of design guidelines. Finally, it is shown that this type of energy-harvesting microdevice, which is basically 2-D, would yield a reasonable compromise between power output, manufacturing simplicity, and cost.     

Long short-term cognitive networks

Neural Computing and Applications - In this paper, we present a recurrent neural system named long short-term cognitive networks (LSTCNs) as a generalization of the short-term cognitive network...